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Chemistry
UTME / JAMB 2006
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The element with the electron configuration 1S\(^2\)2S\(^2\)2P\(^3\) is
A
calcium
B
chlorine
C
oxygen
D
nitrogen
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The element with the electron configuration 1S\(^2\)2S\(^2\)2P\(^3\) is Nitrogen.
Source: Myschool Past Questions Archive (Record #3303)
Chemistry
UTME / JAMB 2006
Periodic Table & Periodicity
Solution
A decrease in atomic size and an increase in nuclear charge across a period lead to
A
an increase in the tendency to lose electron
B
an increase in chemical reactivity
C
a decrease in electropositivity
D
a decrease in covalency in bond formation
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The correct answer is C. A decrease in electropositivity.
As you move across a period in the periodic table:
- Atomic size decreases due to the increase in effective nuclear charge.
- Nuclear charge increases due to the addition of protons.
This results in:
- A stronger attraction between the nucleus and electrons, making it more difficult for the atom to lose electrons.
- A decrease in electropositivity (the tendency of an atom to lose electrons and form a positive ion).
The other options are incorrect:
A. The tendency to lose electrons actually decreases across a period.
B. Chemical reactivity can increase or decrease across a period, depending on the specific elements and their electron configurations.
D. The decrease in atomic size and increase in nuclear charge can actually lead to an increase in the covalent character of bonds, as the atom becomes more electronegative.
Source: Myschool Past Questions Archive (Record #3728)
Chemistry
UTME / JAMB 2006
Nature of Matter & Separation Techniques
Solution
The order in which a mixture of sand, ammonium chloride and sodium chloride can be separated is
A
dissolution → dryness → filtration → evaporation
B
filtration → sublimation → evaporation → dryness
C
sublimation → dissolution → filtration → evaporation
D
dissolution → filtration → sublimation → evaporation
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
To separate sand, NH₄Cl, and NaCl, you can use sublimation to isolate NH₄Cl, followed by dissolving the remaining mixture in water, filtering out the sand, and then evaporating the solution to recover NaCl.
Sublimation of NH₄Cl
Heat the mixture of sand, NH₄Cl, and NaCl in a china dish covered with a funnel (plugged with cotton).
NH₄Cl will sublime (transform directly from solid to gas) and condense on the cooler surface of the funnel, leaving behind a mixture of sand and NaCl.
Collect the NH₄Cl from the funnel walls.
Dissolving and Filtering:
Add water to the remaining mixture of sand and NaCl.
NaCl will dissolve in water, while sand will remain undissolved.
Filter the mixture to separate the sand from the NaCl solution.
3. Evaporating the NaCl Solution:
Evaporate the water from the NaCl solution, leaving behind solid NaCl crystals.
Source: Myschool Past Questions Archive (Record #3729)
Chemistry
UTME / JAMB 2006
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
The idea of planetary electron was that of
A
Rutherford
B
Thompson
C
Bohr
D
Dalton
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Ernest Rutherford proposed the idea of the planetary model of the atom, where electrons orbit a central nucleus, in 1911.
The idea of a "planetary electron," where electrons orbit the nucleus like planets around the sun, is attributed to Ernest Rutherford; his model is often called the "planetary model" of the atom. While Bohr later refined this model by proposing fixed energy levels for electrons, the initial concept of electrons orbiting a central nucleus like planets was put forward by Rutherford. The idea of a "planetary" model of the atom, where electrons orbit the nucleus like planets around the sun, was later proposed by Niels Bohr in 1913.
Source: Myschool Past Questions Archive (Record #3730)
Chemistry
UTME / JAMB 2006
Kinetic Theory of Matter & Gas Laws
Solution
If 30cm\(^3\) of gas at 50\(^0\)C is warmed to 80\(^0\)C at a fixed pressure, the fractional increase in volume is
A
0.009
B
0.093
C
0.910
D
1.090
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Given:
V\(_1\) = 30cm\(^3\)
T\(_1\) = 50\(^0\)C + 273 = 323K
V\(_2\) = ?
T\(_2\) = 80\(^0\)C + 273 = 353K
According to Charles' law: \(\frac{V_1}{T_1}\) = \(\frac{V_2}{T_2}\)
V\(_2\) = \(\frac{{353}\times{30}}{323}\)
V\(_2\) = 32.79 cm\(^3\)
Increase in volume = V\(_2\) - V\(_1\) = 32.79 - 30 = 2.79 cm\(^3\)
Fractional increase in volume = \(\frac{{V_2} - {V_1}}{V_1}\)
= \(\frac{{32.79} - {30}}{30}\)
= 0.09287
= 0.093
Source: Myschool Past Questions Archive (Record #3731)
Chemistry
UTME / JAMB 2006
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
2C\(_2\)H\(_2\)(g) + 5O\(_2\)(g) → 4CO\(_2\)(g) + 2H\(_2\)O(g)
In the reaction above, the mass of carbon(IV)oxide produced on burning 78 g of ethyne is
[C =12, O = 16, H = 1]
A
264 g
B
39 g
C
352 g
D
156 g
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
2C\(_2\)H\(_2\)(g) + 5O\(_2\)(g) → 4CO\(_2\)(g) + 2H\(_2\)O(g)
2 moles : 4 moles
n = \(\frac{mass}{molar mass}\) = \(\frac{78}{26}\)
If 3 moles : 6 moles
n = \(\frac{m}{M}\)
m = n x M
m = 6 x 44
m = 264g
Source: Myschool Past Questions Archive (Record #3732)
Chemistry
UTME / JAMB 2006
Oxidation, Reduction & Redox Reactions
Solution
The ion that can be used as an oxidizing agent is
A
Au3+
B
Fe3+
C
ClO-
D
Ca2+
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
All the other options given, in their atom state can be good oxidizing agents but the ions are reducing agents.
Source: Myschool Past Questions Archive (Record #3733)
Chemistry
UTME / JAMB 2006
Electrolysis & Electrochemical Cells
Solution
Zinc and carbon rods are used as anode and cathode respectively in a
A
Leclanche cell
B
lead accumulator
C
Daniel cell
D
voltaic cell
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
In a Leclanche cell, the anode and the cathode are a zinc rod and a carbon rod respectively. The electrolyte is an ammonium chloride solution or paste (wet or dry cell).
Source: Myschool Past Questions Archive (Record #3736)
Chemistry
UTME / JAMB 2006
Oxidation, Reduction & Redox Reactions
Solution
In which of the following is the oxidation number of sulphur equal to - 2?
A
SO3
B
S8
C
H2S
D
SO2
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
H\(_2\)S = 0
Bearing in mind that the oxidation state of H = + 1
H\(_2\) + S = 0
2(+1) + S = 0
+ 2 + S = 0
S = 0 - 2
S = - 2
Source: Myschool Past Questions Archive (Record #3738)
Chemistry
UTME / JAMB 2006
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Na\(_2\)CO\(_3\)(g) + 2HCl(aq) → 2NaCl(aq) + H\(_2\)O(l) + CO\(_2\)(g)
How many moles of sodium trioxocarbonate (IV) are there in a 25 cm\(^3\) solution which required 10cm\(^3\) of 0.05 mol dm\(^3\) hydrochloric acid solution to neutralize it?
A
1.000 mole
B
0.100 mole
C
0.010 mole`
D
0.111 mole
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
\(\frac{C_A V_A}{C_BV_B} = \frac{a}{b}\)
\(\frac{0.05 \times 10}{C_B \times 25} = \frac{2}{1}\)
50C\(_B\) = 0.5
C\(_B\) = \(\frac{0.5}{50} = \frac{1}{100}\)
= 0.01
Source: Myschool Past Questions Archive (Record #3740)
Chemistry
UTME / JAMB 2006
Chemical Energetics & Thermochemistry
Solution
If the heat of combustion of hydrogen is -285.8kJ,
What is the heat of formation of water?
A
+571.6 kJ
B
-571.6 kJ
C
-285.8 kJ
D
+285.8 kJ
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Heat of combustion (\DeltaH^\circc) is the energy released when a substance is burnt in oxygen.
The heat of formation (\DeltaH^\circf) is the energy released or absorbed when a substance is formed from its constituent elements.
The chemical equation is H\(_2\) + 1/2 O\(_2\) → H\(_2\)O
Since the heat of formation of H\(_2\) is zero (\DeltaHf(H\(_2\) ) = 0 kJ/mol), and the heat of combustion of H\(_2\) is -285.8 kJ/mol, we can use the following relationship:
\DeltaHc(H\(_2\) ) = \DeltaHf( H\(_2\)O) - \DeltaHf(H\(_2\) )
Rearrange to solve for \DeltaHf( H\(_2\)O):
\DeltaHf( H\(_2\)O) = \DeltaHc(H\(_2\) ) + \DeltaHf(H\(_2\) )
= -285.8 kJ/mol + 0 kJ/mol
= -285.8 kJ/mol
Source: Myschool Past Questions Archive (Record #3741)
Chemistry
UTME / JAMB 2006
Oxidation, Reduction & Redox Reactions
Solution
5SO\(_2\)(g) + 2KMnO\(_4\)(aq) + 2H\(_2\)O(l) → K\(_2\)SO\(_4\) + 2MnSO\(_4\)(aq) + 2H\(_2\)SO\(_4\)(aq)
In the reaction above, the products give a
A
purple solution
B
purple precipitate
C
colourless precipitate
D
colourless solution
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
When sulphur dioxide (SO₂) reacts with an acidified solution of potassium permanganate (KMnO₄), the initially purple solution turns colourless. The reason is because the reaction between SO₂ and KMnO₄ is a redox (reduction-oxidation) reaction. SO₂ acts as a reducing agent, meaning it causes the reduction of another substance (KMnO₄), While the permanganate ion (MnO₄⁻) in KMnO₄ is reduced to manganese(II) ions (Mn²⁺), which are colourless.
SO₂ is oxidized to sulphate ions (SO₄²⁻), which are also colourless. So, the purple colour of KMnO₄ is due to the permanganate ion, and when this ion is reduced, the solution becomes colourless.
Source: Myschool Past Questions Archive (Record #3742)
Chemistry
UTME / JAMB 2006
Reaction Rates & Chemical Equilibrium
Solution
In the diagram above, the respective activation energies for the catalyzed and uncatalyzed reactions in kJ are
A
45 and 50
B
50 and 45
C
30 and 35
D
40 and 45
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The activation energy, Ea is the energy of the transition state, (T.E) minus the reactant energy (R.E).
For Catalyzed reaction, Ea = T.E - R.E = 45 - 15 = 30
For Uncatalyzed reaction, Ea = T.E - R.E = 50 - 15 = 35
Source: Official Exam / Past Question Archive
Chemistry
UTME / JAMB 2006
Reaction Rates & Chemical Equilibrium
Diagram
Solution
In the diagram above, gas X is
Attached Figure / Diagram
A
hydrogen
B
chlorine
C
oxygen
D
hydrogen chloride
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When chlorine water (a solution of chlorine gas in water) is exposed to sunlight, chlorine reacts with water molecules to form hypochlorous acid (HClO), which then decomposes into hydrochloric acid (HCl) and oxygen gas (O\(_2\)).
Initial Reaction: Cl₂ + H₂O ⇌ HClO + HCl
Decomposition of Hypochlorous Acid: HClO → HCl + [O] (nascent oxygen)
Formation of Oxygen Gas: [O] + [O] → O₂
Overall Reaction: 2Cl₂ + 2H₂O → 4HCl + O₂
N.B: Nascent oxygen refers to the atomic form of oxygen (represented as [O]) that is highly reactive and unstable.
Source: Myschool Past Questions Archive (Record #31622)
Chemistry
UTME / JAMB 2006
Acids, Bases, pH & Salts
Diagram
Solution
In the diagram above, mixture Y is
Attached Figure / Diagram
A
NH4NO3(s) + CaSO4(s),/sub>
B
NH4Cl(s) + NaNO2(s)
C
NH4NO2(s) + Na2SO4(s)
D
NH4Cl(s) + Ca(OH)2(s)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
2NH₄Cl + Ca(OH)₂ → CaCl₂ + 2NH₃ + 2H₂O
The reaction between ammonium chloride and calcium hydroxide is a double displacement reaction. However, in the reaction between ammonium chloride (NH₄Cl) and calcium hydroxide (Ca(OH)₂), quicklime (CaO) is used to dry the ammonia gas (NH₃) produced by absorbing water, preventing the formation of ammonium sulphate when sulphuric acid is used to dry the gas.
Source: Myschool Past Questions Archive (Record #31624)