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Chemistry
UTME / JAMB 2007
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
If the electron configuration of an element is 1S\(^2\) 2S\(^2\)2P\(^5\), how many unpaired electron are there?
A
2
B
8
C
1
D
4
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When the electrons are drawn out in the orbitals, following the Hund's rule, the diagram above is what will be obtained.
Source: Myschool Past Questions Archive (Record #3849)
Chemistry
UTME / JAMB 2007
Periodic Table & Periodicity
Solution
Which of the following decrease when a given mass of gas is compressed to half its initial volume?
A
Atomic radius of each
B
Average intermolecular distance
C
Frequency of collisions
D
Number of molecules presents
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When a gas is compressed to half its volume, the average intermolecular distance decreases because the same number of gas molecules are now confined to a smaller space, forcing them closer together, resulting in a smaller average distance between each molecule.
Conversely, when the volume of a gas is reduced, the frequency of collisions between molecules increases; this is because the molecules have less space to move around, leading to more frequent interactions with each other and the container walls.
Source: Myschool Past Questions Archive (Record #3853)
Chemistry
UTME / JAMB 2007
Metals, Transition Elements & Extraction
Solution
A metal X forms two bromides with the formulae XBr2 and XBr3. What type of bonding exists between X and bromine in the bromide?
A
Ionic bonding
B
Metallic bonding
C
Dative bonding
D
Covalent bonding
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
If the metal X forms two bromides with the formulae XBr\(_2\) and XBr\(_3\), it simply means it has variable oxidation number or states which is one of the characteristics of transition metals. This implies X is a metal. However, whenever a metal combines with a non-metal, there is usually a transfer of electrons from the metals to the non-metals, and the type of bond formed is the ionic or electrovalent bond.
Source: Myschool Past Questions Archive (Record #3859)
Chemistry
UTME / JAMB 2007
Nature of Matter & Separation Techniques
Solution
A mixture of petrol and water can be separated through
A
centrifugation
B
distillation
C
the use of separating funnel
D
the use of filter paper
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Petrol and water are immiscible liquids, so the best method of separation of petrol and water is by a separating funnel.
Source: Myschool Past Questions Archive (Record #3860)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following represents an aromatic compound?
A
C6H5OH
B
C6H12
C
C6H9OH
D
C6H8
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Aromatic compounds are chemical compounds that consist of conjugated planar ring systems accompanied by delocalized pi-electron clouds in place of individual alternating double and single bonds. In a simpler term, aromatic compounds are compounds of Benzene and its derivatives.e.g Benzene, Phenol, Toluene, xylene, anthracene, Naphthalene etc all cyclically conjugated.
The compound in option A is called phenol - a benzene ring with an hydroxyl group (OH) attached to C-1.
Source: Myschool Past Questions Archive (Record #3861)
Chemistry
UTME / JAMB 2007
Acids, Bases, pH & Salts
Solution
CH\(_3\)CH\(_2\)Cl + KCN → CH\(_3\)CH\(_2\)CN + KCl
In the reaction above, the cyanide is
A
hydrophobic
B
hydrophilic
C
nucleophilic
D
electrophilic
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A nucleophile is considered an electron donating species, meaning it readily donates an electron pair to form a bond with another molecule, typically an electrophile, in a chemical reaction; essentially acting as a Lewis base.
CN\(^-\) (cyanide ion) is considered a nucleophile. This is because it has a negative charge and a lone pair of electrons that it can donate to form a bond with a positively charged species, making it an electron-rich species characteristic of nucleophile.
Conversely, an electrophile is a chemical species that forms bonds with nucleophiles by accepting an electron pair. Because electrophiles accept electrons, they are Lewis acids.
Source: Myschool Past Questions Archive (Record #3866)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following compounds is the best possible anti-knock agent for petrol?
A
(CH3)2CH - CH(CH3)CH2CH3
B
CH3CH2(CH3)CHCH2CH2CH3
C
CH3CH2(CH3)CHCH2CH2CH3
D
(CH3)3C - CH2CH2CH3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
An "anti-knock agent" for petrol (or gasoline) is a chemical additive that is added to fuel to prevent engine knocking, which is a knocking sound produced by premature ignition in the combustion chamber, and essentially increases the fuel's octane rating by delaying ignition.
Option A - 2,3- dimethylpentane
Option B - 3-methylhexane
Option C - 3-methylhexane
Option D - 2,2-dimethylpentane
Both 2,3-dimethylpentane and 2,2-dimethylpentane are branched-chain structures. However, 2,2-dimethylpentane has a more compact, highly branched structure, which is generally associated with higher octane ratings and better anti-knock properties.
In contrast, 2,3-dimethylpentane has a slightly less branched structure, which may result in slightly lower octane ratings. So, while both compounds are branched, the degree of branching and the resulting octane rating can differ.
Source: Myschool Past Questions Archive (Record #3869)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The hydrocarbon used in the production of styrene is
A
ethyne
B
propyne
C
ethane
D
ethene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Styrene is produced from the monomer ethylbenzene through a process called dehydrogenation, where hydrogen is removed from ethylbenzene to create styrene; dehydrogenation of ethylbenzene, a compound obtained by reacting ethylene and benzene. However, ethylene is also known as ethene.
Source: Myschool Past Questions Archive (Record #3870)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
How many structural isomers of chlorobutane are possible?
A
4
B
3
C
2
D
1
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The structural isomers of chlorobutane are: 1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane, and 2-chloro-2-methylpropane; in total, there are four structural isomers of chlorobutane.
Explanation:
1-chlorobutane: Chlorine is attached to the first carbon of a straight carbon chain.
2-chlorobutane: Chlorine is attached to the second carbon of a straight carbon chain.
1-chloro-2-methylpropane: A methyl group is attached to the second carbon of a propane chain, with chlorine on the first carbon.
2-chloro-2-methylpropane: Chlorine is attached to a carbon that is also connected to two methyl groups.
Source: Myschool Past Questions Archive (Record #3980)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The conversion of open chain alkanes into cycloalkanes and aromatic compounds is called
A
cracking
B
reforming
C
isomerization
D
polymerization
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The correct answer is B. Reforming.
Reforming is a process in petroleum refining where low-octane, straight-chain alkanes are converted into higher-octane, branched-chain alkanes, cycloalkanes, and aromatic compounds. This process involves the use of catalysts and high temperatures to break and reform the molecular bonds. Reforming is an important process in the production of high-octane gasoline and other petroleum products.
Source: Myschool Past Questions Archive (Record #3981)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following alkanes has the highest boiling point?
A
Pentane
B
Ethane
C
Propane
D
Methane
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The correct answer is A. Pentane.
Boiling point increases with molecular weight and size in alkanes, due to increased London dispersion forces (also known as van der Waals forces).The order of boiling points for the given options is:
Methane (boiling point: -161.5^\circC) < Ethane (boiling point: -88.5^\circC) < Propane (boiling point: -42.2^\circC) < Pentane (boiling point: 36.1^\circC). Therefore, Pentane has the highest boiling point among the given options.
Source: Myschool Past Questions Archive (Record #3982)
Chemistry
UTME / JAMB 2007
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Certain useful waxes are composed mainly of
A
amino acids
B
glycerols
C
alkanols
D
alkanoates
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Waxes are esters of higher fatty acids with long chain of monohydric alcohols. It is a simple lipid that is an ester of a long-chain alcohol and a fatty acid. The alcohol may contain around 12-32 carbon atoms. Waxes are found in nature as coatings on leaves and stems. The wax prevents the plant from losing excessive amounts of water.
Source: Myschool Past Questions Archive (Record #3983)
Chemistry
UTME / JAMB 2007
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The IUPAC nomenclature of compound CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) is
A
propyl ethanoate
B
ethyl butanoate
C
ethyl propanoate
D
methyl butanoate
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
While trying to name the compound CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) , we must realize that this ester or alkanoate was derived from two reactants; alkanol and alkanoic acid. Therefore, we'll try to split the compound into two for easier naming.
CH\(_3\)CH\(_2\)COO - CH\(_2\)CH\(_3\).
Secondly, start the naming from the right hand side i.e CH\(_2\)CH\(_3\), which is ethyl
Thirdly, name the compound from the left hand side i.e CH\(_3\)CH\(_2\)COO,which is propanoate (because there are 3 carbon atoms and the functional group RCOO-).
Finally, join the two names together i.e ethyl propanoate.
Source: Myschool Past Questions Archive (Record #3985)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
When temporary hard water is boiled for sometime in a kettle, the inner surface of the kettle becomes coated with a deposit of
A
calcium tetraoxosulphate(VI)
B
calcium trioxocarbonate (IV)
C
calcium hydrogentrioxocarbonate (IV)
D
aluminium trioxocarbonate (IV)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When temporary hard water is boiled for some time in a kettle, the inner surface of the kettle becomes coated with a deposit of Calcium trioxocarbonate(IV), CaCO\(_3\), which originated from Calcium hydrogen trioxocarbonate(IV), Ca(HCO\(_3\))\(_2\).
Ca(HCO\(_3\))\(_2\) → CaCO\(_3\) + H\(_2\)O + CO\(_2\)
Source: Myschool Past Questions Archive (Record #3987)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
A supersaturated solution is said to contain
A
more solute than it can dissolve at that temperature in the presence of undissolved solute
B
as much solute as it can dissolve at that temperature in the presence of undissolved solute
C
as much solute as it can dissolve at that temperature
D
more solute than it can dissolve at that temperature
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The correct answer is D. More solute than it can dissolve at that temperature.
A supersaturated solution is a solution that contains more dissolved solute than it can hold at equilibrium at a given temperature. This means that the solution is unstable and can precipitate out the excess solute at any moment.
In contrast, a saturated solution (option C) contains as much dissolved solute as it can hold at equilibrium at a given temperature, while an unsaturated solution contains less dissolved solute than it can hold.
Source: Myschool Past Questions Archive (Record #3991)