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Chemistry
UTME / JAMB 2007
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
If chlorine is bubbled into water and the resulting yellowish-green solution is exposed to bright sunlight for a while, the solution will decompose giving out
A
oxygen and leaving behind aqueous hydrochloric acid
B
chlorine and oxygen
C
oxygen, hydrogen and chlorine
D
oxygen, thereby producing hypochlorous acid
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
When chlorine reacts with water in the presence of sunlight, it produces oxygen gas and hydrochloric acid as the primary products; essentially, the sunlight breaks down the chlorine in water, liberating oxygen gas.
2Cl\(_2\) + 2H\(_2\)O → 4HCl + O\(_2\)
Source: Myschool Past Questions Archive (Record #3791)
Chemistry
UTME / JAMB 2007
Chemical Energetics & Thermochemistry
Solution
H\(_3\)PO\(_4\)(aq) + H\(_2\)O(l) ↔ H\(_2\)PO\(^{4-}\)(aq) + H\(_3\)O\(^+\)(aq) \DeltaH = -13kJ at 298K
In the reaction above, an increase in temperature would
A
slow down the reverse reaction
B
have no effect on the reaction
C
favour the reverse reaction
D
favour the forward reaction
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
In an exothermic reaction, an increase in temperature will favour the reactants (shift the reaction towards the left), meaning the reaction will produce less product as heat is considered a product in an exothermic reaction; according to Le Chatelier's principle, the system will try to counteract the added heat by favouring the reactant side. Thus, the reverse reaction will be favoured.
Source: Myschool Past Questions Archive (Record #3796)
Chemistry
UTME / JAMB 2007
Oxidation, Reduction & Redox Reactions
Solution
The reaction that takes place in Daniell's cell is
A
direct combination
B
redox
C
double decomposition
D
neutralization
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
A Daniell cell undergoes a redox reaction where zinc is oxidized at the anode, releasing electrons that travel through a circuit to the cathode where copper ions are reduced to solid copper, generating an electric current.
Oxidation half-reaction: Zinc metal (Zn) is oxidized to zinc ions (Zn\(^{2+}\)) at the anode, releasing electrons. Zn(s) → Zn\(^{2+}\) + 2e\(^-\)
Reduction half-reaction: Copper ions Cu\(^{2+}\) are reduced to solid copper metal (Cu) at the cathode, accepting electrons. Cu\(^{2+}\) + 2e\(^-\) → Cu
Overall reaction: Zn (s) + Cu\(^{2+}\) (aq) → Zn\(^{2+}\) (aq) + Cu (s).
Source: Myschool Past Questions Archive (Record #3797)
Chemistry
UTME / JAMB 2007
Electrolysis & Electrochemical Cells
What happens when zinc rod is immersed in copper (II) tetraoxosulphate (VI) solution?
A
The blue colour of the solution disappears
B
Electrons flow from copper to zinc
C
The zinc rod remain undissolved
D
The copper generate more copper ions
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option A.
Source: Myschool Past Questions Archive (Record #3805)
Chemistry
UTME / JAMB 2007
Chemical Energetics & Thermochemistry
C\(_2\)H\(_4\)(g) + H\(_2\)(g) → C\(_2\)H\(_6\)(g) \DeltaH = -137kJ mol-1
The reaction represented above is
A
exothermic
B
spontaneous
C
endothermic
D
in equilibrium
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option A.
Source: Myschool Past Questions Archive (Record #3808)
Chemistry
UTME / JAMB 2007
Electrolysis & Electrochemical Cells
How long would it take to deposit 0.08g of copper from CuCl\(_2\) solution by passing a current of 0.5A?
[Cu = 64, 1F = 96500 C mol-1]
A
6 mins
B
8 mins
C
24 mins
D
48 mins
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option B.
Source: Myschool Past Questions Archive (Record #3813)
Chemistry
UTME / JAMB 2007
Metals, Transition Elements & Extraction
Solution
Tartaric acid is used industrially to
A
make baking powder
B
make fruit juices
C
remove rust
D
dry substance
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Tartaric acid is used industrially as an acidulant in food products like carbonated drinks, jellies, and baking powder, as well as in metal cleaning and polishing processes due to its chelating properties; it also finds applications in textile processing and certain photographic development procedures.
The major industrial use of tartaric acid is as an acidulant in the food and beverage industry, primarily used to add a tart flavour to products like carbonated drinks, fruit jellies, candies, and wine, often in combination with other acids to achieve the desired taste profile; it is also used as a leavening agent in baking due to its reaction with baking soda when heated.
Source: Myschool Past Questions Archive (Record #3818)
Chemistry
UTME / JAMB 2007
Chemical Energetics & Thermochemistry
Dissolving some pellets of NaOH in water would result in
A
a decrease in the free energy of the solution
B
a decrease in the entropy of the solution
C
a lowering of the temperature of te solution
D
an increase in the entropy of the solution
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #3822)
Chemistry
UTME / JAMB 2007
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Calculate the number of moles of HCl present in 20cm3 of a 0.75M solution of the acid
A
0.015 mole
B
0.038 mole
C
3.800 moles
D
1.500 moles
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Number of moles = (conc. in mol/dm3*volume in cm3)/1000
(0.75 * 20)/100 = 0.015 mole
Source: Myschool Past Questions Archive (Record #3826)
Chemistry
UTME / JAMB 2007
Oxidation, Reduction & Redox Reactions
Solution
The oxidation state of oxygen in tetraoxosulphate (VI) acid is
A
-4
B
-2
C
+4
D
-8
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
H2SO4
(O.N of hydrogen * 2 ) + O.N of sulphur + O.N of oxygen * 4 = 0
∴ 1 * 2 + 6 + 4x = 0
2 + 6 + 4x = 0
8 + 4x = 0
4x 0 - 8 = -8
4x = -8
x = -8/4 = -2
Source: Myschool Past Questions Archive (Record #3831)
Chemistry
UTME / JAMB 2007
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
MnO\(_2\)(s) + xHCl(aq) → MnCl\(_2\)(aq) + yH\(_2\)O(l) + zCl\(_2\)(g)
In the equation above, what are the values of x, y and z respectively
A
2, 1, 2
B
4, 1, 2
C
4, 2, 1
D
1, 2, 1
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
MnO\(_2\)(s) + xHCl(aq) → MnCl\(_2\)(aq) + yH\(_2\)O(l) + zCl\(_2\)(g)
First, balance the chemical equation, then equate each of the letters with the coefficients.
On balancing, we have : MnO\(_2\)(s) + 4HCl(aq) → MnCl\(_2\)(aq) + 2H\(_2\)O(l) + Cl\(_2\)(g)
Therefore, x = 4,y = 2 and z = 1
Source: Myschool Past Questions Archive (Record #3834)
Chemistry
UTME / JAMB 2007
Kinetic Theory of Matter & Gas Laws
Solution
Calculate the mass of chlorine gas which occupies a volume of 1.12dm3 at s.t.p
[Cl = 35.5, molar volume of gas at s.t.p = 22.4 dm3
A
15.50 g
B
7.10 g
C
3.55 g
D
1.80 g
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
2 * 35.5g of chlorine has a volume of 22.4 dm3 at s.t.p
∴ xg of chlorine will have a volume of 1.12 dm3
x = (1.12 * 35.5 * 2)/22.4 = 3.55g
Source: Myschool Past Questions Archive (Record #3838)
Chemistry
UTME / JAMB 2007
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
Which experiment led to the measurement of the charge on an electron?
A
Mass spectrometric experiment
B
Oil-drop experiment
C
Scattering α - particles
D
Discharge-tube experiment
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
In 1909, Robert Millikan and Harvey Fletcher conducted the oil drop experiment to determine the charge of an electron.
Source: Myschool Past Questions Archive (Record #3841)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
What is the volume of oxygen required to burn complete 45 cm\(^3\) of methane at s.t.p?
A
135.0 cm3
B
180.0 cm3
C
45.0 cm3
D
90.0 cm3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
CH\(_4\)(g) + 2O\(_2\)(g) → 2H\(_2\)O(g) + CO\(_2\)(g)
First, ensure the chemical equation is balanced, stoichiometrically.
i.e CH\(_4\) reacts with 2O\(_2\) in ratio 1 : 2
If 1 mole of CH\(_4\) reacts with 2 moles of O\(_2\)
Then 45 cm\(^3\) CH\(_4\) react with X cm\(^3\) O\(_2\)
i.e 1cm\(^3\) = 2cm\(^3\)
45cm\(^3\)= X cm\(^3\)
X = 45 x 2 = 90 cm\(^3\)
Source: Myschool Past Questions Archive (Record #3844)
Chemistry
UTME / JAMB 2007
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
How many electrons are in the L shell of \(^{31}_{15}\)P?
A
5
B
8
C
18
D
2
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
N.B :
Atomic number = no. of protons = no. of electrons = 15
Orbital configuration of the neutral atom of the element = 2, 8, 5 which represents the shells starting from the first which is K, L, M respectively. i.e
K = 2, L = 8 , M = 5.
Therefore, the L - shell has 8 electrons.
Source: Myschool Past Questions Archive (Record #3845)