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Chemistry
WAEC / WASSCE 2008
Water, Solutions & Solubility
Solution
(a)(i) Define hard water
(ii) Name two substances responsible for hardness in water
(iii) Give two methods for the removal of hardness in water.
(b)(i) What are the raw materials require for the manufacture of tetraoxosulphate (VI) acid by the contact process?
(ii) Write an equation for tr reaction that requires a catalyst in the contact process (iii) State the catalyst used in (b)(ii).
(c)(i) Give two uses of sodium tetraoxosulphate (VI) Consider the reaction represented by the following equation:
Na\(_2\)SO\(_4\).10H\(_2\)O\(_{(s)}\) \(\to\) Na\(_2\)SO\(_4\).H\(_2\)O + 9H\(_2\)O\(_{(g)}\)
(ii) What name is given to this type of reaction?
(iii) Calculate the solubility of Na\(_2\)CO\(_3\) at 25^\circC. if 30.0 cm\(^3\) of its saturated solution at that temperature gave 1.80 g of the anhydrous salt. [C = 12, 0 = 16, Na = 23]
(d)(i) Define the term activated complex
(ii) State one reason why a collision may not produce a chemical reaction
(iii) The formation of water gas is represented by the following equation:
C\(_{(s)}\) + H\(_2\)O\(_{(g)}\) \(\to\) CO\(_{(g)}\) + H\(_{2(0)}\) \(\Delta\)H= + 131 kJmol\(^{-1}\)
Draw an energy profile diagram for the reaction showing the I. activated complex, II. enthalpy of reactants.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)(i) Hard water is water which will not readily form lather with soap.
(ii) 1. Calcium tetraoxosulphate (IV) 2. Calcium hydrogen trioxocarbonate (IV) 3. Magnesium tetraoxosulphate (VI) 4. Magnesium hydrogen trioxocarbonate (IV).
(iii)(a) Heating the water to boiling/distillation (b) Addition of calculated amount of calcium hydroxide [Ca(OH)\(_2\)] (c) Addition of washing soda crystals to the water [Na\(_2\)CO\(_3\)] (d) Ion exchange resin/permutit method.
(b)(i) Sulphur air or oxygen
(ii) 2SO\(_{2(g)}\) +O\(_{2(g)}\) \(\rightleftharpoons\) 2SO\(_{3(g)}\)
(iii) V\(_2\)O\(_5\) / Vanadium (V) oxide.
(c)(i) Use of Na\(_2\)SO\(_4\)
(a) Water softener (b) In glass or paper manufacturing (c) As analytical reagent (d) As purgative (e) In the manufacture of detergents .
(ii) Mass of salt per 30 cm\(^3\) of saturated solution = 1.80g.
1000 cm\(^3\) of saturated solution contains = \(\frac{1000 \times 1.80}{30}\)
= 60g.
Molar mass of Na\(_2\)CO\(_3\) = 23 x 2 + 12 x 1 + 16 x 3 = 106g.
Solubility of Na\(_2\)CO\(_3\) = \(\frac{60}{106}\) = 0.566 mole dm\(^3\).
(d)(i) Activated complex is the intermediate (complex) that reactants must attain in order to form a product or it is a temporary species formed by reactant molecules as a result of collision before the products are formed.
(ii) A collision may fail to produce a chemical reaction if the energy of the colliding particles is less than activation energy / if the reactant are not properly aligned.
Source: Myschool Past Questions Archive (Record #52202)
English Language
WAEC / WASSCE 2008
Lexis, Structure & Register (Cloze & Vocabulary)
In question numbered 99 above, choose the best option from letters A - D that best completes the gap.
A
struggled
B
grumbled
C
suffered
D
toiled
medium Difficulty
Verified Correct Answer: Option D
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #25834)
English Language
WAEC / WASSCE 2008
Lexis, Structure & Register (Cloze & Vocabulary)
In question numbered 100 above, choose the best option from letters A - D that best completes the gap.
A
roof
B
structure
C
wall
D
apartment
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option B.
Source: Myschool Past Questions Archive (Record #25835)
Chemistry
NECO SSCE 2008
Reaction Rates & Chemical Equilibrium
Solution
In which of the following equations can Le-chartelier’s principle be applied?
A
H2(g)+S(g) → H2(g)
B
2H2S(g) + O2 (g) → 2H2O(l) + 2SO2(g)
C
N2(g) +3H2(g)
⇌ 2NH3(g)
D
NaOH(aq) +CO2(g) → Na2CO3(aq) + H2O(l)
E
S(s) + 02(g) → SO2(g)
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
According to Le Chatelier's Principle, this will be favored if you lower the temperature. The system will respond by moving the position of equilibrium to counteract this - in other words by producing more heat. To get as much ammonia as possible in the equilibrium mixture, you need as low a temperature as possible
Source: Official Exam / Past Question Archive
Chemistry
WAEC / WASSCE 2008
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
(a) In the laboratory preparation of crystals of CuSO\(_4\), a green powder Q was added to dilute H\(_2\)SO\(_4\), and stirred. Effervescence occurred and a gas R was given off which turned lime water milky. Excess Q was removed from the mixture. The solution of Cu\(_2\)SO\(_4\) was concentrated to half its original volume and allowed to stand.
(i) What is substance Q?
(ii) Name gas R
(ii) Why was excess Q used?
(iv) How would you know that the reaction is complete?
(v) What method was used to remove excess Q? (vi) Why was the solution of CusO\(_4\) not heated to dryness?
(b) Name the reagent(s) used for testing each of the following substances in the laboratory: (i) Water; (i) Primary alkanol.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)(i) Q is copper (II) trioxocarbonate (IV)
(ii) R is carbon (IV) oxide
(iii) Excess Q was used to ensure that all the acid reacted
(iv) When there is no more effervescence.
(v) Filtration.
(b)(i) White anhydrous copper (II) teraoxosulphate (VI).
(ii) Alkaline iodine solution, or acidified potassium tetraoxomanganate (VIl).
Source: Myschool Past Questions Archive (Record #60031)
Chemistry
WAEC / WASSCE 2008
Nature of Matter & Separation Techniques
Solution
Credit will be given for strict adherence to the instructions, for observations precisely recorded, and for accurate inferences. All tests, observations, and inferences must be clearly centered in your answer book, at the time they are made.
C is a mixture of two salts. Carry outline following exercises on C. Record your observations and identify any gas(es) evolved. State the conclusion you draw from the result of each test.
(a) Put C into a beaker and add about 10 cm\(^3\) of distilled water, stir the mixture, and filter. Test the filtrate with litmus paper. Keep the residue and the filtrate.
(b)(i) To about 2 cm\(^3\) of the filtrate, add few drops of aqueous HNO\(_3\) followed by AgNO\(_{3(aq)}\)
(ii) Add excess NH\(_3\) solution to the resulting mixture.
(c) To about half of the residue from (a) above, add about 5cm\(^3\) of dilute HNO\(_3\) in drops. Divide the resulting solution into two equal portions.
(d)(i) To the first portion add ammonia solution in drops and then in excess.
(ii) To the second portion add dilute hydrochloric acid.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
Test
Observation
Inference
(a) C + water
Mixture
filtered
Filtrate 1 litmus
Partly dissolves
Colourless filtrate
white residue
No effect on litmus
C contains solution and
insoluble salts
Filtrate is neutral
(b)(i) Filtrate + dil. H\(_2\)SO\(_4\) + AgNO\(_{3(aq)}\)
(ii) Mixture in (b)(i)
+ excess NH\(_3\) soln
No reaction
white ppt
ppt dissolves
Cl\(^-\) present
Cl\(^-\) confirmed
(c) Residue + dil. HNO\(_3\)
Effervescence occurs, gas turns lime water milky
CO\(_2\)
CO\(_3^{2-}\) present
(d)(i) First portion + dil. NH\(_3\) in drops
then in excess
(ii) Second portion + dil. HCl
White ppt
ppt insoluble
White chalky ppt
Pb\(^{2+}\) may be present
Pb\(^{2+}\) present
Pb\(^{2+}\) confirmed
Source: Myschool Past Questions Archive (Record #60032)
Chemistry
WAEC / WASSCE 2008
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Burette readings(initial and final) must be given to two decimal places. Volume of pipette user must also be recorded but on account of experimental procedure is required. All calculations must be done in your answer book. A is O.050 mol dm\(^{-3}\) of acid HX. Bis a solution of NaOH containing 0.025 moles per 250 solutions.
(a) Put A into the burette and titrate it against 20.00 cm\(^3\) or 25.00 cm\(^3\) portions B using phenolphthalein as indicator. Tabulate your readings and calculate the average volume or A used.
(b) your results and the information provided above, calculate the;
(i) amount of acid in the average
(ii) amount of base in 20.00 cm\(^3\) or 25.00 cm\(^3\);
(iii) mole ratio of acid to base
(c) Write a balanced chemical equation for the reaction between the acid H\(_y\)X and the base NaOH
(d) State the basicity of the acid H\(_y\)X.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
Table of Result
Indicator used: Phenolphthalein
Volume of pipette = 25 cm\(^3\)
Burette Reading
Rough
1st
2nd
3rd
Final (cm\(^3\))
22.60
22.40
22.30
22.30
Initial (cm\(^3\))
0.00
0.00
0.00
0.00
Volume of acid used (cm\(^3\))
22.00
22.40
22.30
22.30
Average volume of acid used, V\(_A\) = \(\frac{22.40 + 22.30 + 22.30}{3}\)
= \(\frac{67.00}{3}\)
Average titre value = 22.30 cm\(^3\), V\(_A\)
(b)(i) Amount of acid in the average titre, V\(_A\)
1000 cm\(^3\) contains 0.05 moles
V\(_A\) will contain = \(\frac{0.05 \times 22.30}{1000}\)
= 0.0011 moles
(ii) Concentration of NaOH in B
\(\frac{0.025}{0.25}\) = 0.199 mol dm\(^{-3}\)
To calculate the amount of base in 25 cm\(^3\)
\(\frac{25 cm^3}{1000}\) x 0.100 mol dm\(^{-3}\) = 0.0025 moles
(iii) Mole ratio of acid (H\(_y\)X) to base (NaOH)
\(\frac{0.0011}{0.0025}\) = \(\frac{1}{2}\)
(c) Equation for the reaction
2NaOH + H\(_y\)X \(\to\) Na\(_2\)X + H\(_2\)O
(d) Basicity of acid H\(_y\)X = 2, (two)
Source: Myschool Past Questions Archive (Record #60033)
English Language
UTME / JAMB 2008
Lexis, Structure & Register (Cloze & Vocabulary)
In question number 25 above choose the best option from letters A- D that best complete the gap
A
rational
B
reactional
C
proactive
D
radical
medium Difficulty
Verified Correct Answer: Option A
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option A.
Source: Official Exam / Past Question Archive
English Language
NECO SSCE 2008
Oral English: Vowel & Consonant Sounds
Solution
Choose from the options lettered A - E the one that contains the sound segment represented by the given phonetic symbol
/\theta/
A
tank
B
teethe
C
thank
D
they
E
this
medium Difficulty
Verified Correct Answer: Option C
Grammar & Contextual Explanation
tank - /tæŋk/
teethe - /tiːð/
thank - /\thetaæŋk/
they - /ðeɪ/
this - /ðɪs/
Source: Myschool Past Questions Archive (Record #43892)
English Language
NECO SSCE 2008
Oral English: Vowel & Consonant Sounds
Solution
Choose from the options lettered A - E the one that has the same vowel sound as the one represented by the underlined Letter(s).
gear
A
badge
B
bridge
C
jeer
D
large
E
leg
medium Difficulty
Verified Correct Answer: Option C
Grammar & Contextual Explanation
gear - /gɪə/
A. badge – /bæʤ/
B. bridge – /brɪʤ/
C. jeer – /ʤɪə/
D. large – /lɑːʤ/ → ends with /ʤ/ as well
E. leg – /leg/
Source: Myschool Past Questions Archive (Record #43893)
English Language
NECO SSCE 2008
Oral English: Vowel & Consonant Sounds
Choose from the options lettered A - E the one that has the same vowel sound as the one represented by the underlined letter(s)
may
A
car
B
man
C
mark
D
mean
E
shake
medium Difficulty
Verified Correct Answer: Option E
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option E.
Source: Myschool Past Questions Archive (Record #43894)
English Language
NECO SSCE 2008
Synonyms (Nearest in Meaning)
Choose from the options lettered A - E the one that is nearest in meaning to the word underlined.
My principal gives his candid opinion on every issue brought before him.
A
complete
B
fatherly
C
frank
D
honest
E
vague
medium Difficulty
Verified Correct Answer: Option C
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option C.
Source: Myschool Past Questions Archive (Record #43895)
English Language
NECO SSCE 2008
Oral English: Stress, Rhymes & Intonation
Solution
Choose from the options lettered A - E the one that has the same stress with the word given. In each word, only one syllable has the main/primary and the syllable is written in capital letters
desegregate
A
DE-seg-re-gate
B
de-SEG-re-gate
C
de-seg-RE-gate
D
de-seg-re-GATE
E
DE-seg-re-GATE
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
Words that end with "ate" are usually stressed on the third syllable from the last.
Source: Myschool Past Questions Archive (Record #43896)
English Language
NECO SSCE 2008
Lexis, Structure & Register (Cloze & Vocabulary)
Solution
Choose from the options lettered A - E the one that most appropriately completes each sentence
Olu has returned the pencil he________him.
A
handed
B
borrowed
C
dashed
D
lent
E
given
medium Difficulty
Verified Correct Answer: Option D
Grammar & Contextual Explanation
The pronoun "he" refers to the person who originally gave the pencil to Olu, i.e., the lender. Thus, the complete sentence would read:
"Olu has returned the pencil he lent him."
Source: Myschool Past Questions Archive (Record #43897)
English Language
NECO SSCE 2008
Oral English: Vowel & Consonant Sounds
Solution
Choose from the options lettered A - E the one that has the same consonant sound as the one represented by the underlined Letter(s).
thin
A
bathe
B
day
C
there
D
they
E
tooth
medium Difficulty
Verified Correct Answer: Option E
Grammar & Contextual Explanation
thin - /\thetaɪn/
bathe - /beɪð/
day - /deɪ/
there - /ðeə/
they - /ðeɪ/
tooth - /tuː\theta/
Source: Myschool Past Questions Archive (Record #43898)