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Chemistry
UTME / JAMB 2018
Chemical Energetics & Thermochemistry
Solution
3H\(_{2(g)}\)+ N\(_{2(g)}\)⇔ 2NH\(_{3(g)}\) ; H= -ve
In the reaction above, lowering of temperature will
A
have no effect on the equilibrium position
B
increase the rate of both the forward and reverse reactions equally
C
favour the forward reaction
D
favour the reverse reaction
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
N\(_{2(g)}\) + 3H\(_{2(g)}\) ⇔ 2NH\(_{3(g)}\) In the Haber process, the forward reaction is exothermic and the backward reaction is endothermic. If the temperature is decreased, the yield from the exothermic direction is increased i.e. the forward reaction is increased.
Source: Myschool Past Questions Archive (Record #47666)
Chemistry
UTME / JAMB 2018
Chemical Energetics & Thermochemistry
Solution
The situation obtained when a perfect gas expands into a vacuum is
A
ΔH is positive and TΔ S is zero
B
ΔH is positive and T Δ S is negative
C
ΔH is negative and TΔ S is zero
D
ΔH is zero and T Δ S is positive
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The definition of enthalpy change is
\DeltaH = \DeltaU + Pex(\DeltaV)
The enthalpy change is zero because both terms on the right are zero in free expansion of an ideal gas.
There is no external pressure in a free expansion, so P (ex) = 0. And the internal energy change, \DeltaU of free expansion in a closed system is zero since no inter molecular forces have to be overcome. The temperature remains constant and no heat is absorbed or released.
Source: Myschool Past Questions Archive (Record #47667)
Chemistry
UTME / JAMB 2018
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The general formula of alkanones is
A
RCHO
B
R\(_2\)CO
C
RCOOH
D
RCOOR
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Alkanones also known as ketones have the general formula R\(_2\)CO
Source: Myschool Past Questions Archive (Record #47668)
Chemistry
UTME / JAMB 2018
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The alkanoic acid found in human sweat is
A
CH\(_3\)-COOH
B
CH\(_3\)—CH\(_2\)—COOH
C
H-COOH
D
CH\(_3\)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Bacteria of the genus Propionibacterium produce propionic acid (Propanoic Acid) as the end-product of their anaerobic metabolism. This class of bacteria is commonly found in the stomach of ruminants and the sweat glands of humans, and their activity is partially responsible for the odour of both Swiss cheese and sweat.
Source: Myschool Past Questions Archive (Record #47669)
Chemistry
UTME / JAMB 2018
Oxidation, Reduction & Redox Reactions
Solution
In electrovalency, the oxidation number of the participating metal is always
A
decreasing
B
increasing
C
constant
D
neutral
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
In electro-valency the oxidation number of the participating metal increases.
Source: Myschool Past Questions Archive (Record #47660)
Chemistry
UTME / JAMB 2018
Periodic Table & Periodicity
Solution
The ionic radii of metals are usually
A
greater than their atomic radii
B
unaffected by the charge on the ion
C
the same as their atomic radii
D
less than their atomic radii
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
In a neutral atom, the atomic and ionic radius is the same, but many elements exist as anions or cations. If the atom loses its outermost electron (positively charged or cation), the ionic radius is smaller than the atomic radius because the atom loses an electron energy shell.
Yes ionic radius is only less than atomic radius for a metal.
Source: Myschool Past Questions Archive (Record #47661)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Calculate the percentage composition of oxygen in calcium trioxocarbonate(IV) [Ca=40, C=12, O=16]
A
16
B
48
C
40
D
12
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Calcium trioxocarbonate (IV) = CaCO\(_3\)
Percentage of Oxygen = \(\frac{\text{Molar mass of 3O}}{\text{Molar mass of} CaCO_3}\) \times 100%
Percentage of Oxygen = \(\frac{(3 \times 16)}{(40 + 12 + 48)}\) x 100%
Percentage of Oxygen = \(\frac{48}{100}\) x 100%
Percentage of Oxygen = 48%
Source: Myschool Past Questions Archive (Record #47662)
Chemistry
UTME / JAMB 2018
Metals, Transition Elements & Extraction
Solution
Which of these alloys contains copper?
A
solder
B
steel
C
permallory
D
bronze
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Bronze is an alloy consisting primarily of copper, commonly with about 12% tin and often with the addition of other metals (such as aluminium, manganese, nickel or zinc) and sometimes non-metals or metalloids such as arsenic, phosphorus or silicon.
Source: Myschool Past Questions Archive (Record #47663)
Chemistry
UTME / JAMB 2018
Particulate Nature of Matter, Laws & Formulae
Solution
If the molecular mass of tetraoxosulphate (VI) acid is 98, calculate its vapour density.
A
196
B
49
C
106
D
82
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Molecular mass = Vapour Density x 2
Vapour Density = \(\frac{\text{Molecular Mass}}{2}\)
Where Molecular mass = 98g/mol
Vapour Density = \(\frac{98}{2}\)
Vapour Density = 49g/mol
Source: Myschool Past Questions Archive (Record #47664)
Chemistry
UTME / JAMB 2018
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
The elements in the periodic table are listed in order of increasing
A
relative atomic number
B
atomic mass
C
relative isotopic mass
D
nuclear charge
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The periodic number table is arranged in order of atoms increasing atomic number
Source: Myschool Past Questions Archive (Record #47670)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
H\(_2\) S\(_{(g)}\) + Cl\(_{2(g)}\) → 2HCl\(_{(g)}\) + S\(_{(g)}\) In the reaction above, the substance that is reduced is
A
H\(_2\)S
B
S
C
HCl
D
Cl\(_2\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
H \(_2\) S + Cl \(_2\) → 2HCl + S
Please note: substance oxidized or reduced are always the reactants. So, one can easily cross out the two products.
Reduction is
1. Addition of hydrogen
2. Removal of Oxygen
3. Addition of Electron
Oxidation is
1. Removal of hydrogen
2. Addition of hydrogen
3. Removal of Electron
From the question we can see that H was added to Cl in the product, thereby making hydrogen to be removed from S in the reactant hence S is oxidized as a result of the removal of hydrogen and Cl \(_2\) has been reduced due to addition of hydrogen.
Cl \(_2\) is reduced
Source: Myschool Past Questions Archive (Record #47671)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Which of the compounds is composed of Al, Si, O and H?
A
Epson salt
B
Limestone
C
Clay
D
Urea
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Between the five main minerals found in clay, kaolinite is the most common. Kaolinite holds the chemical composition A\(l_2\) S\(i_2\)\(O_5\)(OH)\(_{4}\) and is an aluminum silicate material with a low “shrink-swell” capacity. It is a soft, white mineral but is often colored orange or red by iron oxide found in the soil.
Source: Myschool Past Questions Archive (Record #47672)
Chemistry
UTME / JAMB 2018
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
When large hydrocarbon molecules are heated at high temperature in the presence of a catalyst to give smaller molecules, the process is known as
A
disintegration
B
polymerization
C
cracking
D
degradation
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Cracking is the breakdown of a large alkane into smaller, more useful alkenes. Simply put, hydrocarbon cracking is the process of breaking a long-chain of hydrocarbons into short ones. This process might require high temperatures and high pressure.
Source: Myschool Past Questions Archive (Record #47673)
Chemistry
UTME / JAMB 2018
Water, Solutions & Solubility
Solution
In the removal of water hardness, permutit is regenerated with a strong solution of
A
NaOH
B
Na\(_3\)SO\(_4\)
C
Na\(_3\)CO\(_3\)
D
NaCl
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
permutit water softener can be regenerated by washing the spent resin with brine( saturated sodium chloride solution). The solution ions replace the calcium or magnesium ions present in it.
\(CaR_{2(s)}\) + 2\(NaCl_{aq}\) → \(CaCl_{2(aq)}\) + 2\(NaR_{2(s)}\)
Source: Myschool Past Questions Archive (Record #47674)
Chemistry
WAEC / WASSCE 2018
Oxidation, Reduction & Redox Reactions
Which of the following equations represents a redox reaction?
A
\(HNO_{{3}{(aq)}} + NaOH_{(aq)} \to NaNO_{{3}{(aq)}} + H_{2}O_{(l)}\)
B
\(AgNO_{{3}{(aq)}}+KCl_{(aq)} \to AgCl_{(s)}+KNO_{{3}{(aq)}}\)
C
\(CaCO_{{3}{(s)}} \to CaO_{(s)} + CO_{{2}{(g)}}\)
D
\(2H_{2}S_{(s)} + SO_{{2}{(g)}} \to 2HO_{2} + 3S_{(g)}\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #48961)