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Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The end products of burning a candle in the atmosphere are water and
A
carbon (II) oxide
B
sulphur (IV) oxide
C
carbon (IV) oxide
D
sulphur (VI) oxide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When we ignite a candle, the hydrocarbon reacts with oxygen (in excess) to produce carbon dioxide and water. The burning sets an air current which gives dome shape to candle flame and it helps to get complete combustion at the bottom and the outer surface of the flame.
CO\(_2\) is produced
Source: Myschool Past Questions Archive (Record #47650)
Chemistry
UTME / JAMB 2018
Reaction Rates & Chemical Equilibrium
Solution
The collision theory explains reaction rates in terms of
A
size of the product
B
frequency of collision of the reactants
C
size of reactant
D
frequency of collision of the products
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Collision theory is the theory used to predict the rates of chemical reactions, particularly for gases. The collision theory is based on the assumption that for a reaction to occur it is necessary for the reacting species (atoms or molecules) to come together or collide with one another.
Source: Myschool Past Questions Archive (Record #47651)
Chemistry
UTME / JAMB 2018
Water, Solutions & Solubility
Solution
The presence of ammonia gas in a desiccator can exclusively be removed by
A
phosphorus (V) oxide
B
fused calcium chloride
C
calcium oxide
D
concentrated tetraoxosulphate (VI) acid
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Ammonia gas can be removed from a dessicator by adding a conc. H2SO4 so as to neutralize it since ammonia gas is basic.
Source: Myschool Past Questions Archive (Record #47652)
Chemistry
UTME / JAMB 2018
Electrolysis & Electrochemical Cells
Solution
Aluminium does not react with either dilute or concentrated trioxonitrate (V) acid because
A
it is insoluble in either dilute or concentrated trioxonitrate (V) acid
B
it is lower than hydrogen in the electrochemical series
C
the reaction with trioxonitrate (V) acid has a light activation energy
D
an insoluble oxide is formed on its surface which renders it passive
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Aluminium doesn’t react with either dilute or concentrated trioxonitrate (V) acid because an insoluble oxide is formed on its surface which renders it passive. It will depend on the concentration of the nitric acid used…. Although aluminium reacts with dilute nitric acid to produce aluminium nitrate and hydrogen gas, concentrated (>60%) nitric acid is such a powerful oxidising agent that it instantly causes a thin layer of aluminium oxide to coat the surface of the aluminium
Source: Myschool Past Questions Archive (Record #47653)
Chemistry
UTME / JAMB 2018
Electrolysis & Electrochemical Cells
Diagram
Solution
The figure above shows the electrolysis of molten sodium chloride. Z is the
Attached Figure / Diagram
A
anode where the Cl\(^-\) ions are oxidized
B
cathode where the Cl\(^-\) ions are reduced
C
anode where the Na\(^+\) ions are reduced
D
cathode where the Na\(^+\) ions are oxidized
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
During the electrolysis of brine, the chlorine ions are discharged at the anode and are oxidized. While at the cathode Hydrogen ion is discharged.
Source: Myschool Past Questions Archive (Record #47644)
Chemistry
UTME / JAMB 2018
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
The knowledge of half-life can be used to
A
Create an element
B
Detect an element
C
to combine elements
D
Irradiate an element
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Half-life, in radioactivity, the interval of time required for one-half of the atomic nuclei of a radioactive sample to decay (change spontaneously into other nuclear species by emitting particles and energy), or, equivalently, the time interval required for the number of disintegrations per second of a radioactive material to decrease by one-half
Source: Myschool Past Questions Archive (Record #47645)
Chemistry
UTME / JAMB 2018
Particulate Nature of Matter, Laws & Formulae
Solution
An element X forms the following compounds with chlorine; XCl\(_4\), XCl\(_3\), XCl\(_2\). This illustrates the
A
law of multiple proportions
B
law of chemical proportions
C
law of simple proportions
D
law of conservation of mass
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The law of multiple proportion states that when element A and B combine to form more than one chemical compound then the various masses of sample A react with a fixed mass of sample B are in a simple multiple ratio.
Source: Myschool Past Questions Archive (Record #47646)
Chemistry
UTME / JAMB 2018
Acids, Bases, pH & Salts
Solution
The hydrogen ion concentration of a sample of orange juice is 2.0 X 10\(^{-11}\)moldm\(^{-3}\). What is its p\(^{OH}\)? [log102 = 0.3010]
A
3.30
B
13.00
C
10.70
D
11.30
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
PH+POH=14
p\(^{H}\) = Log [H\(^+\)]
p[H\(^+\) ] = 2.0 X 10\(^{-11}\)moldm\(^{-3}\)
p\(^{H}\) = Log [2.0 X 10\(^{-11}\)]
p\(^{H}\) = 10.70
10.70+ p\(^{OH}\) =14
p\(^{OH}\) = 14 -10.70
= 3.30
Source: Myschool Past Questions Archive (Record #47647)
Chemistry
UTME / JAMB 2018
Reaction Rates & Chemical Equilibrium
Solution
2SO\(_2\) \(_{(g) }\)+ O\(_2\) \(_{(g) }\) ↔ 2SO\(_3\)\(_{(g) }\) \DeltaH = -395.7kJmol\(^{-1}\)
In the equation, an increase in temperature will shift the equilibrium position to the
A
left and equilibrium constant decreases
B
left and equilibrium constant increases
C
right and equilibrium constant increases
D
right and equilibrium constant decreases
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
This is typical of what happens with any equilibrium where the forward reaction is exothermic. Increasing the temperature decreases the value of the equilibrium constant. Where the forward reaction is endothermic, increasing the temperature increases the value of the equilibrium constant. Endothermic reaction has a Positive Enthalpy change. Exothermic reaction has a negative enthalpy change.
Source: Myschool Past Questions Archive (Record #47649)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The conductivity of an acid solution depends on the
A
amount of ions present and their mobilities
B
mobilities of the ions present
C
amount of ions present
D
temperature of the solution
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The conductivity of a solution depends on the number of charge carriers (the concentrations of the ions), the mobility of the charge carriers and their charge. Theoretically, conductivity should increase in direct proportion to concentration.
Source: Myschool Past Questions Archive (Record #47655)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Which of the following metals cannot replace hydrogen from water or steam?
A
Sodium
B
Magnesium
C
Iron
D
Copper
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Metals above hydrogen in the activity series can displace or replace hydrogen present in water (H\(_2\)O) example of such metals are Ca, K, Na etc. But the metals below hydrogen in the activity series cannot replace hydrogen in the activity series example of such metals are Cu, Hg.
Source: Myschool Past Questions Archive (Record #47656)
Chemistry
UTME / JAMB 2018
Chemical Bonding & Intermolecular Forces
Solution
Elements P, Q, R, S have 6, 11, 15, 17 electrons respectively, therefore,
A
P will form an electrovalent bond with R
B
Q will form a covalent bond with S
C
R will form an electrovalent bond with S
D
Q will form an electrovalent bond with S
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
P 6 = 2, 4
Q 11 = 2, 8, 1
R 15 = 2, 8, 5
S 17 = 2, 8, 7
Given the above is the electronic arrangement of PQRS elements, Q will form an electrovalent bond with S. Without argument, D is the answer because electrovalency involves the transfer of electron. Already, Q is 11 with electronic configuration of 2, 8, 1, i.e. having 1 valence electron which is ready to be lost by the atom of element Q, also, S is 17, with electronic configuration of 2, 8, 7. There the 7 valence electron of S attracts that only 1 electron to attain a stable octet structure.
Source: Myschool Past Questions Archive (Record #47657)
Chemistry
UTME / JAMB 2018
Electrolysis & Electrochemical Cells
Solution
During the electrolysis of copper II sulphate between platinum electrodes, if litmus solution is added to the anode compartment
A
the litmus turns blue but no gas is evolved
B
the litmus turns blue and oxygen is evolved
C
the litmus turns blue and hydrogen is evolved
D
the litmus turns red and oxygen is evolved
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
During the electrolysis of copper using platinum electrode, Cu and H migrate to the cathode while,SO\(_4\) and OH migrate to the anode.CU is then discharged preferentially at the cathode, acquiring two electrons and is deposited as metallic copper, while OH is discharged preferentially at the anode and deposited as gaseous oxygen, then the SO\(_4\) and H still in the solution react, thereby making d solution acidic and then changing the litmus paper red which is the test for acids.
Source: Myschool Past Questions Archive (Record #47658)
Chemistry
UTME / JAMB 2018
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The derivative of benzene that can be used in making explosives is
A
aniline
B
xylene
C
phenol
D
toluene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Yes, Toluene is used in making explosives, based on information from the textbook "New School Chemistry", pg 541.
Phenol is used as a starting material to makes explosive materials such as picric acid. Picric acid is one of the most acidic phenol. Like other strongly nitrated organic compounds, picric acid is an explosive. Toluene, however, is used to produce a stronger explosive material called TriNitroToluene (TNT).
Therefore Toluene is the most appropriate answer for this question but in situations where you don't find Toluene in the options provided, then Phenol makes a viable answer.
Source: Myschool Past Questions Archive (Record #47659)
Chemistry
UTME / JAMB 2018
Nature of Matter & Separation Techniques
Solution
Sieving is a technique used to separate mixtures containing solid particles of
A
small sizes
B
large sizes
C
different sizes
D
the same size
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sieving is a simple and convenient technique of separating particles of different sizes.
Source: Myschool Past Questions Archive (Record #47665)