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Chemistry
UTME / JAMB 2018
Particulate Nature of Matter, Laws & Formulae
A balanced chemical equation obeys the law of
A
conservation of mass
B
definite proportions
C
multiple proportions
D
conservation of energy
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option A.
Source: Myschool Past Questions Archive (Record #47344)
Chemistry
UTME / JAMB 2018
Air & Environmental Chemistry
Solution
When air which contains the gases Oxygen, nitrogen, carbondioxide, water vapour and the rare gases, is passed through alkaline pyrogallol and then over quicklime, the only gases left are;
A
nitrogen and carbondioxide
B
the rare gases
C
nitrogen and oxygen
D
nitrogen and the rare gases
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The quick-lime is a drying agent that can dry most gases except ammonia. Hence it removes the water vapour. Quick-lime which is calcium oxide reacts with the carbon dioxide forming calcium carbonate. Hence carbon dioxide and monoxide is eliminated leaving nitrogen, and the rare gases
Source: Myschool Past Questions Archive (Record #47628)
Chemistry
UTME / JAMB 2018
Non-Metals & Their Compounds
Solution
In the laboratory preparation of oxygen, the gas cannot be collected by downward displacement of air because
A
the density of oxygen is greater than that of air
B
the density of air is nearly the same as that of oxygen
C
oxygen is a component of air
D
air is an impure substance
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Oxygen is collected in downward displacement of water because:-
Oxygen is only slightly soluble in water. Therefore, it can be collected over water without the fear of excessive dilution.
Oxygen is slightly heavier than air, so it cannot be collected over air.
Source: Myschool Past Questions Archive (Record #47629)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
2KClO\(_3\)(s) → 2KCl(s) + 3O\(_2\)(g)
The importance of the catalyst in the reaction above is that
A
heating may not be required before the reaction takes place
B
the reaction is controllable even at a high temperature
C
the reaction produces large quantity of oxygen
D
the reaction takes place more rapidly at a lower temperature
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
A catalyst is a substance that enables a chemical reaction to proceed at a usually faster rate or under different conditions (as at a lower temperature) than otherwise possible.
Source: Myschool Past Questions Archive (Record #47630)
Chemistry
UTME / JAMB 2018
Non-Metals & Their Compounds
Solution
Which of the following is used to power steam engines?
A
lubricating oil
B
coal
C
bitumen
D
diesel oil
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When we burn coal on a fire, the bonds break apart and the energy is released in the form of heat. Coal contains about half as much energy per kilogram as cleaner fossil fuels such as gasoline, diesel, and kerosene—and that's one reason why steam engines have to burn so much of it.
Coal is the fuel used to power steam engines.
Source: Myschool Past Questions Archive (Record #47631)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
In the reaction between sodium hydroxide and sulphuric acid solutions, what volume of 0.5 molar sodium hydroxide would exactly neutralise 10cm3 of 1.25 molar sulphuric acid?
A
5cm\(^3\)
B
10cm\(^3\)
C
20cm\(^3\)
D
50cm\(^3\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
2NaOH + H\(_2\) SO\(_4\)↔Na\(_2\)SO\(_4\) + 2H\(_2\)O
V x 0.5M = 2(10 x 1.25)
0.5V = 2 x 12.5
0.5V = 25
V = 250.5 = 50cm\(^2\)
Correct computation as it follows the equation specified.
Source: Myschool Past Questions Archive (Record #47633)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
To what volume must 300cm\(^3\) of 0.60M sodium hydroxide solution be diluted to give a 0.40M solution?
A
450cm\(^3\)
B
300cm\(^3\)
C
200cm\(^3\)
D
150cm\(^3\)
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
From the dilution law
C\(_1\)V\(_1\) = C\(_2\)V\(_2\)
C\(_1\) = Initial Concentration of NaOH = 0.6M
V\(_1\) = Initial Volume of NaOH = 300cm3
C\(_2\) = Final Concentration of NaOH = 0.4M
V\(_2\) = Final Volume of NaOH = ?
V\(_2\) = \(\frac{C_1V_1}{C_2}\)
V\(_2\) = \(\frac{0.6 \times 300}{0.4}\)
V\(_2\) = 450 cm\(^3\)
Correct Computation as it follows the equation specified
Source: Myschool Past Questions Archive (Record #47634)
Chemistry
UTME / JAMB 2018
Chemical Bonding & Intermolecular Forces
Solution
Diamond is a bad conductor of electricity because its bonding electrons are used in
A
crystal lattice formation
B
covalent bond formation
C
metallic bond formation
D
coordinate bond formation
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Diamond is a covalent macromolecule, and typical of a covalent substance is an insulator. All valence electrons are localized in well-defined covalent bonds and hence are not free to move through the structure
Source: Myschool Past Questions Archive (Record #47635)
Chemistry
UTME / JAMB 2018
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The reaction between an organic acid and an alcohol in the presence of an acid catalyst is known as;
A
saponification
B
dehydration
C
esterification
D
hydrolysis
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Esterification is a chemical reaction that forms at least one ester (= a type of compound produced by reaction between acids and alcohols). Esters are produced when acids are heated with alcohols in a process called esterification. An ester can be made by an esterification reaction of a carboxylic acid and an alcohol.
Source: Myschool Past Questions Archive (Record #47636)
Chemistry
UTME / JAMB 2018
Metals, Transition Elements & Extraction
Solution
The constituent common to duralumin and alnico is
A
Co
B
Mn
C
Al
D
Mg
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Constituents of duralumin are: Al, Cu, Mg, Mn.
Constituents of Alnico are: Al, Ni and Co
In 1909, the alloy of duralumin was discovered by Alfred Wilon consisting of 94% Al, 4% Cu, 1% Mg and 1% Mn(Manganese)
Alnico is an acronym referring to a family of iron alloys which in addition to iron are composed primarily of Al, Ni and Co.
Source: Myschool Past Questions Archive (Record #47637)
Chemistry
UTME / JAMB 2018
Water, Solutions & Solubility
Solution
The solubility of the solids that dissolves in a given solvent with the liberation of heat will
A
increase with an increase in temperature
B
decrease with an increase in temperature
C
decrease with a decrease in temperature
D
not be affected by changes in temperature
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
increasing temperature in exothermic reaction favors the left/reactant side and decreasing temperature will favor the right/product side.
Source: Myschool Past Questions Archive (Record #47638)
Chemistry
UTME / JAMB 2018
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
What mass of Cu would be produced by the cathodic reduction of Cu\(^{2+}\) when 1.60A of current passes through a solution of CuSO\(_4\) for 1 hour. (F=96500Cmol\(^{-1}\) , Cu=64)
A
7.64g
B
3.82g
C
1.91g
D
0.96g
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
M = \(\frac{MmIT}{96500n}\)
Where
M=mass
Mm = Molar mass = 64g/mol
I = current = 1.6A
T= Time =1h r=3600s
N= No of Charge = +2
M = \(\frac{64x \times 1.6 \times 3600}{96500 \times 2}\)
M=1.91g
Source: Myschool Past Questions Archive (Record #47639)
Chemistry
UTME / JAMB 2018
Acids, Bases, pH & Salts
Solution
Calculate the pH of 0.05 moldm\(^{-3}\) H\(_2\)SO\(_4\)
A
1.30
B
1.12
C
1.00
D
0.30
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Recall from pH formula pH = -Log [H+]
H2SO4 → 2H+ + SO42-
2H+ → 2 X0.05 = 0.1
pH= -Log [0.1] = 1
Source: Myschool Past Questions Archive (Record #47640)
Chemistry
UTME / JAMB 2018
Periodic Table & Periodicity
Solution
The choice of method for extracting a metal from its ores depends on the
A
strength of the core
B
position of the metal in the electrochemical series
C
source of the core
D
position of the metal in the periodic table
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The method used to extract a metal from its ore depends upon the stability of its compound in the ore, which in turn depends upon the reactivity of the metal:
• The oxides of very reactive metals, such as aluminum, form stable oxides and other compounds. A lot of energy is needed to reduce them to extract the metal.
• The oxides of lesser reactive metals, such as iron, form less stable oxides and other compounds. Relatively little energy is needed to reduce them to extract the metal.
So, the method of extraction of a metal from its ore depends on the metal's position in the reactivity series.
Source: Myschool Past Questions Archive (Record #47641)
Chemistry
UTME / JAMB 2018
Chemical Energetics & Thermochemistry
Solution
Which of the following produces relatively few ions in solution?
A
NaOH
B
Ca(OH)\(_2\)
C
KOH
D
AI(OH)\(_3\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Aluminium hydroxide is not soluble in water because it is polymeric and it also has high lattice energy and therefore it is hard to break bonds in this compound. So, water cannot dissolve such types of compounds.
Al(OH)\(_3\) is not soluble in water
Source: Myschool Past Questions Archive (Record #47643)