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Chemistry
WAEC / WASSCE 2022
Electrolysis & Electrochemical Cells
Solution
(a)i. Define an acid according to the Lewis concept
ii. Give one example of a Lewis acid
(b) Explain salting out in soap preparation
(c) State the reagent and condition necessary for the following conversion
H−C≡C−H→Ag−C≡C−Ag
(d) What is the percentage abundance of an isotope?
(e)i. Why does the element with atomic number 18 not have an oxide?
ii. Explain why chlorine(I) oxide has a low melting point
(f). Describe a test to distinguish between concentrated HNO3 and concentrated H2SO4
(g) State two differences between an electrochemical cell and an electrolytic cell
(h) How does the trend in ionization energy affect the reactivity of group 1 elements?
(i).Define the term molecular formula
(j) State which of the gases H2 and NH3 would deviate more from ideal behaviour. Give reasons for the answer stated above
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)i. An acid is any compound which in a chemical reaction is able to attach itself to an unshared pair of electrons in another molecule-a base, to form a new compound
ii. - AlCl3
- BF3
- BeF2
- H+
- K+
(b). It is the addition of NaCl to the reaction mixture in soap production to facilitate the precipitation of soap from the mixture
(c) Reagent -- AgNO3 in NH3(aq) / Ammonical silver trioxonitrate
condition-- heat
(d) - It is the fraction of a given isotope in amixture of isotopes of the same element
- The % of an isotope with a specific atomic mass found in a naturally occuring sample of an element.
(e)i. Because the element is
- Unreactive
- Stable
- A noble gas
- Inert
- Completely filled outermost shell
ii. Because of weak forces between the molecules hence not much heat is needed to break the forces
(f) - (Conc) HNO3 produces brown fumes (of NO2) when copper tunings are added to it/copper (II) salt is added but H2SO4 will not react with the copper tuning/Copper (II) salt
- When Conc. H2SO4 is added to sugar it chars the sugar but Conc. HNO3 will not.
- Add BaCl2 solution to each acid white precipitate indicates H2SO4 no precipitate indicates HNO3
(g)
Electrochemical cell
Electrolytic cell
anode is negative/cathode is positive
anode is positive/cathode is negative
reaction is spontaneous
non-spontaneous
chemical energy is converted to electrical energy
electrical energy is converted to chemical energy
current is generated from within the cell
current is generated from external source/battery
the two half cells are in separate containers and connected by a salt bridge
the two half cells are in the same container
(h) Ionization energy decreases down group 1 elements, the lower the ionization energy, the easier to loose an electron hence the higher the reactive of the elements
(i) Molecular formula shows the actual number of atoms of each element in a molecule
(j) NH3 will deviate more because it has a larger volume and also it has a stronger intermolecular forces
Source: Myschool Past Questions Archive (Record #65777)
Chemistry
WAEC / WASSCE 2022
Non-Metals & Their Compounds
Solution
(a)i. State two conditions used in the Haber process
ii. Explain briefly the effect of increasing the pressure on the rate of reaction in the Haber process.
(b)i. A mixture of nitrogen(IV) oxide and oxygen is bubbled into warm water to produce
trioxonitrate(V) oxide, write a balanced chemical equation for the reaction.
ii. Using a balanced chemical equation only, explain what would happen if nitrogen(IV) oxide is bubbled into warm water.
iii.
Compare the gases evolved when trioxonitrate(V) acid decomposes under each of the following properties:
i. pH
ii. Solubility in water
iii. Reaction with carbon(II) oxide
(c)i. Name two oxides of sulphur
ii. Write a balanced equation for the reaction between each of the named oxides(Sulphur(IV) oxide, Sulphur (VI) oxide) and water
(d)i. Name one calcium compound
a, Used to dry ammonia gas
b. Used in the manufacture of cement
c. That causes hardness in water
d. Name one calcium compound
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)i. Temperature: 350-5000C/high temperature
Pressure: 150-1000 atm/high pressure
Catalyst: (Finely divided) Iron
ii. Rate of the reaction increases as particles are closer together/more particles per unit volume. There are more collisions per seconds/collisions are more often
(b)i. 4NO2 + O2 + 2H2O -----> 4HNO3
ii. 2NO2 + 2H2O -----> HNO3 + HNO2
A misture of two acids will be produced
iii. 4HNO3(aq) → 4NO2 + O2 + 2H2O
i. - Oxygen is neutral while NO2 is acidic
ii. - NO2 is soluble while O2 is sparingly soluble in water
iii. - O2 reacts with CO to form CO2 while NO2 reacts with CO to form a mixture of N2 and CO2
(c)i. Sulphur(IV) oxide
Sulphur (VI) oxide
ii. SO2(g) + H2O(l) ---->H2SO3(aq)
SO3(g) + H2O(l) ---->H2SO4(aq)
(d)i. - calcium oxide
- quick lime
b. - Limestone
- Quick lime
- Calcium trioxocarbonat(IV)
- Calcium oxide
c. - Calcium chloride
- Calcium tetraoxosulphate (VI)
- Calcium hydrogen trioxocarbonate (IV)
d. Calcium tetraoxosulphate (VI) (dihydrate)
Source: Myschool Past Questions Archive (Record #65778)
Chemistry
WAEC / WASSCE 2022
Water, Solutions & Solubility
Solution
(a) Describe the observation that would be made when-----
i. Sulphur is heated from room temperature till 1190C
ii. 50% trioxonitrate(V) acid acts on copper tunings
(b)i. State two gaseous pollutants that can be generated by burning coal.
ii. What gas is responsible for most of the explosions in coal mines?
iii. The mining of coal leads to environmental pollution. State two environmental effects of the mining activity.
iv. Explain briefly why coal burns more easily when it is in pieces than in lump form
v. Name the non-volitile residue after the destructive distillation of coal
(c)i. Describe a chemical test for water
ii.a. State the effect of boiling a temporary hard water
b. State the effect of adding sodium trioxocarbonate(IV) crystals to permanent hard water
iii. Write an equation for the process of boiling a temporary hard water
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)i. Its colour darkens from pale yellow to amber colour while its crystals become needle-like and at 119oC it begins to melt.
ii. The solution turns green, bubbles of colourless gas rise from the bottom of the mixture, but brown fumes of NO2 are produced and the solutions later turns blue.
(b)i - SO2
- CO2
- CO
- NO2
- H2S
ii. Methane
iii. - Contamination of soil
- Soil erosion
- Contamination of ground water
- Loss of biodiversity
- Formation of sink holes
iv. Because of the large surface area and the higher the area the faster the rate of reaction.
v. Coke
(c)i. The sample is added to anhydrous copper (II) tetraoxosulphate (VI) when it turns from white to blue confirms the presence of water/sample is added to anhydrous cobalt chloride/cobalt chloride paper when it turns from blue to pink indicates the presence of water.
ii(a) It softens temporary hard water
(b) To remove permanent hardness/soften hard water
iii. - Ca(HCO3)2 ---heat--->CaCO3 + CO2 + H2O + H2O
or
Mg(HCO3)2 ---heat--->MgCO3 + CO2 + H2O + H2O
Source: Myschool Past Questions Archive (Record #65790)
Chemistry
WAEC / WASSCE 2022
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The by-product of fermentation of sugar is
A
carbon(IV) oxide.
B
ethanoic acid.
C
propanol
D
propan-1, 2, 3- triol.
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Ethanol fermentation, also called alcoholic fermentation, is a biological process which converts sugars such as glucose, fructose, and sucrose into cellular energy, producing ethanol and carbon dioxide as by-products
Source: Myschool Past Questions Archive (Record #65791)
Chemistry
WAEC / WASSCE 2022
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Which of the following sugars is a product of the condensation of monosaccharides?
A
galactose
B
maltose
C
glucose
D
fructose
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Maltose is produced by the enzymatic hydrolysis of starch (a homopolysaccharide) catalyzed by the enzyme amylase.
Source: Myschool Past Questions Archive (Record #65792)
Chemistry
WAEC / WASSCE 2022
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The cleansing effect of soap is low in acidic water because of
A
the formation of unionized fatty acid.
B
increase in the pH of the soap molecules.
C
anti-biodegradable effect of hydrogen ions
D
the hardness of the acidic water.
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Soaps cannot be used in acidic condition because they lose their cleansing effect due to the formation of long chain fatty acids
Source: Myschool Past Questions Archive (Record #65793)
Chemistry
WAEC / WASSCE 2022
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The following compounds are condensation polymers except
A
nylon
B
protein
C
starch
D
polyethene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Condensation polymers are any kind of polymers whose process of polymerization involves a condensation reaction.
Source: Myschool Past Questions Archive (Record #65794)
Chemistry
WAEC / WASSCE 2022
Electrolysis & Electrochemical Cells
Solution
What amount of electricity is required to deposit one mole of aluminium from a solution of AlCl3?
A
One Faraday
B
One ampere
C
Three Faradays
D
Three amperes
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
AlCl3 → Al3+ + 3Cl-
At cathode:
Al3+ + 3e- → Al
3 mole of electrons corresponds 3 F charge
So, required charge =3 F
Source: Myschool Past Questions Archive (Record #65795)
Chemistry
WAEC / WASSCE 2022
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following compounds would react rapidly with bromine?
A
Benzene
B
Hexane
C
Hexene
D
Hexanol
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The addition of bromine to most alkenes is so fast that when bromine is added dropwise to a solution of the alkene the red bromine color disappears almost immediately. In fact, this discharge of color is a useful qualitative test for alkenes.
Source: Myschool Past Questions Archive (Record #65796)
Chemistry
WAEC / WASSCE 2022
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Alkanols can be manufactured from alkenes by the initial reaction of alkenes with
A
bromine in tetrachloromethane
B
concentrated tetraoxosulphate(VI) acid
C
aqueous potassium tetraoxomanganate(VII).
D
sodium hydroxide solution.
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
An alkene reacts with conc. H2SO4 to yield an alkyl hydrogen tetraoxosulphate (VI). The compound formed undergoes hydrolysis when boiled with water to yield an alcohol.
Source: Myschool Past Questions Archive (Record #65797)
Chemistry
WAEC / WASSCE 2022
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Which of the following statements about the standard hydrogen electrode is not correct?
A
The hydrogen gas is at a pressure of 1 atmosphere
B
A solution containing 1 mol dm-3 of H+ (aq) ions is used
C
A platinum electrode is used
D
The temperature is kept at 20 °C
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The standard hydrogen electrode consists of hydrogen gas at 25oC
Source: Myschool Past Questions Archive (Record #65798)
Chemistry
WAEC / WASSCE 2022
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
If 60 g of M combines with 24 g of oxygen, what would the empirical formula of the oxide be?
( molar mass of M = 120, O = 16)
A
MO
B
M\(O_2\)
C
M\(O_3\)
D
M\(O_4\)
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Data obtained from the question
M = 60 g
O = 24 g
Empirical formula =?
How to determine the empirical formula
Divide by their molar mass
M = 60\div120 = 0.5
O = 24 \div16 = 1.5
Divide by the smallest
M = 0.5\div0.5 = 1
O = 1.5 \div0.5 = 3
Thus, the empirical formula of the oxide is MO₃
Source: Myschool Past Questions Archive (Record #65799)
Chemistry
WAEC / WASSCE 2022
Electrolysis & Electrochemical Cells
Solution
The products of the electrolysis of dilute sodium chloride using carbon electrodes are
Anode Cathode
A
chlorine and sodium.
B
oxygen and hydrogen.
C
chlorine and hydrogen.
D
hydrogen and oxygen.
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Oxygen is produced at the anode and hydrogen is produced at the cathode in dilute NaCl
Source: Myschool Past Questions Archive (Record #65800)
Chemistry
WAEC / WASSCE 2022
Electrolysis & Electrochemical Cells
Solution
Determine the quantity of electricity used when a current of 0.20 amperes is passed through an electrolytic cell for 60 minutes.
A
12C
B
120C
C
360C
D
720C
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Q =It
t = 60 * 60=3600
I = 0.20
Q=0.20 * 3600
Q= 720C
Source: Myschool Past Questions Archive (Record #65801)
Chemistry
WAEC / WASSCE 2022
Acids, Bases, pH & Salts
Solution
Oxochlorate(I) acid is used as a bleaching agent because it is
A
a weak acid
B
a reducing agent.
C
an oxidizing agent
D
a strong acid.
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
HOCl is unstable and decomposes to release oxygen which oxidizes the dye to form a colourless compound.
Source: Myschool Past Questions Archive (Record #65802)