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Physics
WAEC / WASSCE 2022
Electrostatics & Capacitors
Diagram
Solution
(a)(i) State Coulomb's law of electrostatics.
(ii) The electron and proton of a hydrogen atom are separated by a mean distance of 5.2 x 10\(^{-11}\)m.
Calculate the magnitude of the electrostatic force between the particles.
[e = 1.6 x 10\(^{-19}\) C, (4\(\pi\) \(\mathcal{E}_{0}\))\(^{-1}\) = 9.0 x 10\(^{9}\) mF\(^{1}\)]
(b) The diagram above shows a potential divider circuit. (see diagram above)
i. Show that V\(_{out}\) = V\(_{in}\) (\(\frac{R_{1}}{R_{1} + R_{2}})\)
ii. If \(\frac{V_{in}}{V_{out}}\) = 2.5 and \(R_2\) = 30\(\Omega\), calculate \(R_1\)
iii. Define the volt.
(c) Explain why wood is not suitable for use as the core of transformers.
(d) State one application for the cathode ray tube.
Attached Figure / Diagram
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a)(i) Coulomb's law of electrostatics
The electrostatic force between two charged bodies is directly proportional to the product of their charges and inversely proportional to the square of the distance between them.
(ii) Calculation of the magnitude of the electrostatic force
F = \(\frac{kq_{1}q_{2}}{d^{2}}\)
F = \(\frac{9.0 \times 10^{9} \times 1.6 \times 10^{-19} \times 1.6 \times 10^{-19}}{(5.2 \times 10^{-11})^{2}}\)
= 8.52 x 10\(^{-8}\) N
(b)(I) Proof of V\(_{out}\)
Let the current through the circuit be I
V\(_{in}\) = I(\(R_1\) + \(R_2\))
OR
I = \(\frac{V_{in}}{R_{1} + R_{2}}\)
V\(_{out}\) = I\(R_2\)
II. Calculation of \(R_1\);
V\(_{out}\) = V\(_{in}\)(\(\frac{R_{1}}{R_{1} + R_{2}}\))
OR
\(\frac{V_{out}}{V_{in}} = \frac{R_{1}}{R_{1} + R_{2}}\)
\(\frac{1}{2.5} = \frac{R_{1}}{R_{1} + R_{30}}\)
\(R_1\) = 20\(\Omega\)
(ii) The Volt The unit of potential difference between two points when one joule of work is done in taking one coulomb of charge between the points,
(c) Why wood is not suitable for use as the Core of transformers Wood is a non-magnetic material and would not provide magnetic coupling between the coils for electromagnetic induction.
(d) Applications of cathode ray tube
i. For studying alternating current waveform
ii. For measuring frequency/voltage/ reactance/power factor and resistance of an electronic device
iii. Used to monitor signals/check FM/AM characteristics
Source: Myschool Past Questions Archive (Record #63534)
Physics
WAEC / WASSCE 2022
Reflection, Refraction & Dispersion of Light
Solution
(a) State one condition each necessary for the characteristics each of the following occurrences:
(i) Constructive interference of waves.
(ii) Total internal reflection.
(iii) Production of beats.
(b) In a resonance tube experiment using a tuning fork of frequency 256 Hz, the first position of resonance was 35 cm, the next position was 100 cm. Calculate the velocity of sound in air from the experiment.
(c)(i) State the three classifications of musical instalments
(ii) Give one example each of the classifications stated in (c)(i).
(d) Calculate the critical angle for light traveling from glass to air. [refractive index of glass = 1.5].
(e) The speed of sound in a medium at a temperature of 102 ^\circC is 240 m s\(^{-1}\). If the speed of sound in the medium is 3 10 m s\(^{-1}\). Calculate its temperature
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a) Conditions necessary for:
Constructive interference of waves
i. lt must involve at least two waves.
ii. Waves must vibrate in phase.
iii. The distance between the sources of the wave must be of the order of the wavelength.
Total internal reflection
i. The waves must travel from a denser medium to a less dense medium.
ii. The angle of incidence (in the denser medium) must be greater than the critical angle.
iii. It must involve two media of different optical densities.
Production of beats
1. The amplitude of the two interfering waves should be the same.
ii. The difference between the frequencies of interfering waves should be small.
iii. The two sources of waves must be sounded together.
(b) Calculation of velocity of sound in air
V = f\(\lambda\)
V = 2f(\(l_2\) - \(l_1\))
= 2 x 256(100 - 35)
= 33280 cm s\(^{-1}\)
= 332.80 m s\(^{-1}\)
(c)(i) Classification of musical instruments
i. Wind
ii. Stringed
iii. Percussion
(ii) Examples of classified instruments saxophone
I. Wind: flute, trumpet, pipe, organ,
iii. Stringed: piano, guitar, violin
iii. Percussion: piano, drum, bell, gong. xylophone
(d) Calculation of critical angle
\(\eta\) = \(\frac{1}{\text {Sin C}}\)
1.5 = \(\frac{1}{\text {Sin C}}\)
Sin C = 0.667
C = 41.80º
(e) Calculation of temperature
\(\frac{V_{1}}{\sqrt T_{1}} = \frac{V_{2}}{\sqrt T_{2}}\)
\(\frac{240} {\sqrt 375} = \frac {310} {\sqrt T_{2}}\)
240 \(\sqrt T_{2}\) = 310 x 19.36
\(\sqrt T_{2}\) = 625 K = 352 ºC
Source: Myschool Past Questions Archive (Record #63664)
Physics
WAEC / WASSCE 2022
Calorimetry, Latent Heat & Change of State
Solution
(a) State two factors that affect the rate of evaporation of a liquid.
(b) Explain the term latent heal.
(c) Explain each of the following phenomena:
(i) On a dry day, water in a clay pot is cooler than water in a rubber container:
(ii) Cooking of food is faster in a pressure cooker than in an ordinary pot.
(d) A 40 V electric heater is used to supply a current of 12 A for 1400 seconds to a body mass of 1.5 kg at its melting point. The body melts and its temperature rises by 60^\circC in an extra 1.2 minutes, Calculate the:
(i) Latent heat of fusion of the body
(ii) Specific heat capacity of the body.
(e) State two differences between evaporation and boiling.
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a) Factors affecting the rate
i. Surface area of the liquid (exposed surface area)
ii. Temperature of the liquid
iii. Wind/ drought.
iv. Humidity/ amount of water vapour
v. Nature of the liquid
vi. Air pressure
(b) Explanation of latent heat;
The energy needed to change the state of a substance without a change in temperature.
(c)(i) Water in a clay pot cooler than in a rubber container;
A clay pot has pores which allows evaporation to occur while a plastic container has no pores.
(ii) Pressure cooker cooks faster than ordinary pot;
Pressure cooker raises the pressure within it, which raises the temperature to/above the boiling point thus cooks faster.
(d)(i) Calculation of latent heat of fusion of the body
Ivt = mL
mL = 12 x 40 x 1400
= 6.72 x 10\^{5}\)j
(ii) Calculation of specific heat capacity of the body
C = \(\frac{Ivt}{m \bigtriangleup \theta}\)
= \(\frac{12 \times 40 \times 72}{1.5 \times 60}\)
= 384 jkg\(^{-1}\) K\(^{-1}\)
(e) difference between evaporation and boiling
Evaporation
Boiling
It takes place at the surface of the liquid
It occurs throughout the entire volume of the liquid
It takes place across all temperatures
It takes place at specific temperatures
It produces a cooling effect
It produces no cooling effect
It is wind aided
It is not wind aided
Source: Myschool Past Questions Archive (Record #63692)
Physics
UTME / JAMB 2022
Reflection, Refraction & Dispersion of Light
Solution
The secondary pigments consist of?
A
blue, green, and violet
B
yellow, green, and magenta
C
magenta, yellow, and cyan
D
red, green, and blue
medium Difficulty
Verified Correct Answer: Option C
Physical Principles & Numerical Solution
The primary colors of pigment are red, blue, and green.
Mixing these primary colors of pigment gives us the three secondary colors:
red+blue=magenta, red+ green = yellow, and blue + green = cyan
Source: Myschool Past Questions Archive (Record #64927)
Physics
UTME / JAMB 2022
Reflection, Refraction & Dispersion of Light
Solution
A person standing waist-deep in a swimming pool appears to have short legs because of light?
A
diffraction
B
refraction
C
reflection
D
interference
medium Difficulty
Verified Correct Answer: Option B
Physical Principles & Numerical Solution
The refractive index of water is greater than that of air.
So, A person legs appear to be short while standing in the tank due to refraction.
Source: Myschool Past Questions Archive (Record #64929)
Physics
WAEC / WASSCE 2022
Atomic, Quantum, Nuclear Physics & Electronics
Solution
(a)(i) What is meant by the term artificial radioactivity?
(ii) Complete the table below
Emission
Nature
Charge
Ionizing
High speed electron
Moderately ionizing
Neutral
Negligible ionizing ability
Alpha particles
Positive
(b) In an x-ray tube, an electron is accelerated from rest towards a metal target by a 30 kV source. Calculate the kinetic energy of the electron. [e=1.6 x 10\(^{-19}\)C]
(c) The table below shows the frequencies of radiations incident on a certain metal and the corresponding kinetic energies of the photoelectrons.
Frequency x 10\(^{14}\)(Hz)
6.8
8.0
9.2
10.0
11.0
Kinetic energy x 10\(^{-19}\)(j)
0.8
1.6
2.4
2.9
3.8
(i) Plot a graph of kinetic energy, K.E, on the vertical axis and frequency, f, on the horizontal axis starting both axes from the origin (0,0).
(ii) From the graph, determine the:
i. Planck's constant;
ii. Threshold frequency of radiations;
iii. Work function of the metal.
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a)() Meaning of artificial radioactivity;
The process by which a stable nucleus is bombarded with a neutron to make it unstable and so disintegrates/decays with the emission of particles/radiation and. energy.
Emission
Nature
Charge
Ionizing
Beta (\(\beta\))
High speed electron
Negative
Moderately ionizing
Gamma (\(\gamma\))
Electro-magnetic radiation
Neutral
Negligible ionizing ability
Alpha particles
Helium nucleus
Positive
Highly ionizing
(b) Calculation of kinetic energy
K.E = eV
= 1.6 x 10\(^{-19}\) x 30 x 10\(^{3}\)
= 4.8 \times 10\(^{-15}\)J
(c)(i) graph of K.E versus f
i. Both axes correctly distinguished
ii. Reasonable scale on both axes
(ii) (I) Planck's constant. h = slope of the graph Slope
i. \(\bigtriangleup\)K.E and \(\bigtriangleup\)f correctly determined
ii. \(\frac{\bigtriangleup K.E}{\bigtriangleup f}\) corectly determined and recorded within range.
(II) Threshold frequency, \(f_0\) .
The intercept on the horizontal or frequency axis.
(III) Threshold frequency, \(W_o\)
Negative intercept on K.E axis.
Source: Myschool Past Questions Archive (Record #63727)
Physics
WAEC / WASSCE 2022
Equilibrium of Forces, Moments & Flotation
Diagram
Solution
You are provided with a metre rule, a weight hanger, slotted masses, M, a piece (if string, a weighing balance and a knife edge. Use the diagram above as a guide to perform the experiment.
(i) Using the weighing balance, determine and record the mass, \(M_o\), of the unloaded metre rule.
(ii) Determine and record the mass, m, of the weight hanger.
(ii) Suspend the metre rule horizontally on the knife edge. Adjust the knife edge to a point G on the metre rule where it balances horizontally.
(iv) Record the distance, d = AG.
(v) Suspend the weight hanger securely at a point, P, on the metre rule such that AP= 5 cm. Keep the hanger at this point throughout the experiment
(vi) Add a mass, M = 20 g to the hanger, adjust the knife edge to a point K on the metre rule such that it balances horizontally as shown in the diagram above.
(vii) Determine and record the distance z = AK.
(vii) Record M and evaluate y - (z - 5), x - (d - z] and v = \(\frac{x}{y}\)
(ix) Repeat the experiment for M = 40 g, 60 g, 80 g and 100 g. In each case, evaluate y, x and v.
(x) Tabulate the results.
(xi) Plot a graph with M on the vertical axis and v on the horizontal axis, sinning both axes from the origin (0,0).
(xii) Determine the slope, s, of the graph.
(xii) Determine the intercept, c, on the vertical axis.
(xiv) State two precautions taken to ensure accurate results.
(b) (i) Under what condition is an object said to be in a stable equilibrium
(ii) Auniform beam of weight 50 N has a body of weight 100 N hung at one end of it. If the beam is 12 m long, determine the distance of a support from a 100 N body for it to balance horizontally.
Attached Figure / Diagram
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a) OBSERVATIONS
(i) Value of \(M_0\) correctly determined and recorded to at least 1 d.p in grammes
(ii) Value of m correctly determined and recorded to at least 1 d.p in grammes
(iii) Value of d correctly read and recorded to at least 1 d.p in cm
(iv) Five values of M correctly recorded in grammes
(v) Five values of Z = AK correctly read and recorded to at least1 d.p in cm and in trend.
Trend: As M increases Z decreases.
(vi) Five values of y = (Z - 5) correctly evaluated and recorded.
(vii) Five values of x = (d - Z) correctly evaluated and recorded
(vii) Five values of v = \(\frac{x}{y}\) correctly evaluated and recorded to at least 3 d.p
(ix) Composite table showing at least M, Z,y, x and v.
(b)(i) Condition for a body to be in stable
- The algebraic sum of all external forces on the object is zero
OR
- The algebraic sum of all external torques from the external forces acting on the object is zero.
OR
- The sum of clockwise moments about a point in the object is equal to the sum of anticlockwise moment about the same point.
OR
- The algebraic sum of all moments about a point on the object is zero.
(ii) If the distance is y,
100y = 50(6 - y)
100y = 300 - 50y
150y = 300
y = 2m
Source: Myschool Past Questions Archive (Record #63747)
Physics
WAEC / WASSCE 2022
Units, Measurements & Dimensional Analysis
Diagram
Solution
You are provided with a loaded boiling tube with a centimeter scale fixed inside it, a transparent vessel filled with water, standard masses 2 g, 5g and 10 g, and a slide vernier caliper. Use the diagram above as a guide to perform the experiment.
(i) Use the slide vernier caliper to measure and record the external diameter, D, of the boiling tube.
(ii) Evaluated A = 0.25\(\pi\)D\(^{2}\), where \(\pi\) = 3.14.
(iii) Place the loaded boiling tube gently in the water in the transparent vessel such that it floats vertically.
(iv) Read and record the depth of immersion, y, from the zero mark of the scale fixed inside, the boiling tube.
(v) Add a mass, m = 2g, to the boiling tube. Read and record the new depth of immersion, y, from the zero mark of the scale.
(vi) Evaluate h = (y - \(y_0\)), log h and log m.
(vii) Repeat the experiment for four other values of m = 5g, 7g, 10 g, and 12g. In each case, record y and evaluate h, log h, and log m.
(viii) Tabulate the results.
(ix) Plot a graph with log m on the vertical axis and log h on the horizontal axis starting both axes from the origin (0,0).
(b)(i) State in full the law on which the experiment in (a) is based.
(ii) A uniform cylindrical rod is 0.63 m long and it has a cross-sectional area of 0.1 m\(^{2}\). Calculate the depth of immersion of the rod if it floats vertically in a liquid of relative density 1.26. [density of rod =720 kg m\(^{-3}\), g = 10 m s\(^{-2}\)].
Attached Figure / Diagram
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a) OBSERVATIONS
(i) Value of D correctly measure and recorded to at least 2 d.p in cm
(ii) Value of A = 0.25\(\pi\)D\(^{2}\) correctly evaluated
(iii) Value of \(y_0\) correctly read and recorded to at least 1 d.p in cm.
(iv) Five values of m correctly recorded in grammes.
(v) Five values of y correctly read and recorded to at least 1 d.p in cm and in trend.
(vi) Five values of h = (y - yo) correctly evaluated.
(vii) Five values of log h correctly evaluated to at least 3 d.p
(viii) Five values of log m correctly evaluated to 3d.
(ix) Composite table showing at least m, y, h, log h and log m.
(b)(i) The Law of Flotation;
A floating body displaces its own weight of fluid in which it floats.
(ii) Weight of rod = 0.63 x 0.1 x 720 x 10 = 453.6
Let y be the depth of immersion
\(\therefore\) Weight of water displaced
= (0.1y) x 1.26 x 1000 x 10
1260y = 453.6 y=453.6=9.36
= 1260y = 453.6
y = \(\frac{453.6}{1260}\) = 9.36
Source: Myschool Past Questions Archive (Record #63754)
Physics
WAEC / WASSCE 2022
Current Electricity & Electric Circuits
Diagram
Solution
You are provided with a battery of e.m.f, E, a standard resistor, R, of resistance 2 \(\Omega\), a key, K, an ammeter, A, a jockey, J, a potentiometer, UV, and some connecting wires.
(i) Measure and record the emf, E, of the battery.
(ii) Set up the circuit as shown in the diagram above with the key open.
(iii) Place the jockey at the point, U, of the potentiometer wire. Close the key and record the reading, i, of the ammeter.
(iv) Place the jockey at a point T on the potentiometer wire UV such that d = UT = 30.0 cm.
(v) Close the circuit, read and record the current, I, on the ammeter,
(vi) Evaluate I\(^{1}\).
(vi) Repeat the experiment for four other values of d = 40.0 cm, 50.0 cm, 60.0 cm and 70.0 cm. In each case, record I and evaluate I\(^{1}\).
(vii) Tabulate the results
(ix) Plot a graph with d on the vertical axis and I on the horizontal axis stalling both axes from the origin (0,0).
(x) Determine the slope, s, of the graph.
(xi) From the graph determine the value \(I_1\), of I when d = 0. (ci) Given that=s, calculate 8.
(xii) State two precautions taken to ensure accurate results.
(xii) Given that \(\frac{E}{\delta}\) = s, calculate \(\delta\).
(b)(i) Write down the equation that connects the resistance, R, of a wire and the factors on which it depends. State the meaning of each of the symbols.
(ii) An electric fan draws a current of0.75 A in a 240 V circuit. Calculate the cost of using, the fan for 10 hours if the utility rate is $ 0.50 per kWh.
Attached Figure / Diagram
medium Difficulty
Verified Correct Answer: Option
Physical Principles & Numerical Solution
(a) OBSERVATIONS
(i) Value of E correctly read and recorded to at least 1 d.p in volts.
(ii) Value of i correctly read and recorded to at least 1 d.pin amperes.
(iii) Five values of d correctly determined and recorded to at least 1 d.p in cm.
(iv) Five values of I correctly read and recorded to at least 1 d.p in amperes and in trend.
Trend; As d increases, I decreases
(v) Five values of I\(^{1}\) correctly evaluated to at least 3 s.f.
(vi) Composite table showing at least d, I, and I\(^{-1}\).
(ii) P = IV
Power P = \(\frac{240 \times 0.75}{100}\)
0.18kw
Energy consumed in 10hr = 0.18 x 10
= 1.8kWh
Cost of energy = 1.8 x 0.5 = $0.9
OR
Cost of energy = \(\frac{\text {P x cost x time}}{100}\)
\(\frac{0.7 \times 240 \times 10}{1000}\)
= $0.9
Source: Myschool Past Questions Archive (Record #63755)
Physics
UTME / JAMB 2022
Current Electricity & Electric Circuits
Solution
Water is not a good thermometric liquid because it?
A
expands unevenly between 0 ºC and 4 ºC
B
maintains fixed density
C
has low freezing point
D
wets glass
medium Difficulty
Verified Correct Answer: Option A
Physical Principles & Numerical Solution
Water is most anomalous at low temperatures, with a remarkable density maximum at 4^\circC.
water is not used as a thermometric liquid because it has low thermal expansivity, high specific capacity, high vapor pressure and wets glass.
Source: Myschool Past Questions Archive (Record #64945)
Physics
WAEC / WASSCE 2022
Current Electricity & Electric Circuits
Solution
You are provided with a battery of e.m.f, E, a standard resistor, R, of resistance 2 \(\Omega\), a key, K, an ammeter, A, a jockey, J, a potentiometer, UV, and some connecting wires.
(i) Measure and record the emf, E, of the battery.
(ii) Set up the circuit as shown in the diagram above with the key open.
(iii) Place the jockey at the point, U, of the potentiometer wire. Close the key and record the reading, i, of the ammeter.
(iv) Place the jockey at a point T on the potentiometer wire UV such that d = UT = 30.0 cm.
(v) Close the circuit, read and record the current, I, on the ammeter,
(vi) Evaluate I\(^{1}\).
(vi) Repeat the experiment for four other values of d = 40.0 cm, 50.0 cm, 60.0 cm and 70.0 cm. In each case, record I and evaluate I\(^{1}\).
(vii) Tabulate the results
(ix) Plot a graph with d on the vertical axis and I on the horizontal axis stalling both axes from the origin (0,0).
(x) Determine the slope, s, of the graph.
(xi) From the graph determine the value \(I_1\), of I when d = 0. (ci) Given that=s, calculate 8.
(xii) State two precautions taken to ensure accurate results.
(xii) Given that \(\frac{E}{\delta}\) = s, calculate \(\delta\).
(b)(i) Write down the equation that connects the resistance, R, of a wire and the factors on which it depends. State the meaning of each of the symbols.
(ii) An electric fan draws a current of0.75 A in a 240 V circuit. Calculate the cost of using, the fan for 10 hours if the utility rate is $ 0.50 per kWh.
A
Operation of a grinding machine
B
Walking
C
Application of brakes
D
Moving piston in a sleeve
medium Difficulty
Verified Correct Answer: Option D
Physical Principles & Numerical Solution
(a) OBSERVATIONS
(i) Value of E correctly read and recorded to at least 1 d.p in volts.
(ii) Value of i correctly read and recorded to at least 1 d.pin amperes.
(iii) Five values of d correctly determined and recorded to at least 1 d.p in cm.
(iv) Five values of I correctly read and recorded to at least 1 d.p in amperes and in trend.
Trend; As d increases, I decreases
(v) Five values of I\(^{1}\) correctly evaluated to at least 3 s.f.
(vi) Composite table showing at least d, I, and I\(^{-1}\).
(ii) P = IV
Power P = \(\frac{240 \times 0.75}{100}\)
0.18kw
Energy consumed in 10hr = 0.18 x 10
= 1.8kWh
Cost of energy = 1.8 x 0.5 = $0.9
OR
Cost of energy = \(\frac{\text {P x cost x time}}{100}\)
\(\frac{0.7 \times 240 \times 10}{1000}\)
= $0.9
Source: Official Exam / Past Question Archive
Physics
UTME / JAMB 2022
Newton's Laws, Momentum & Collisions
Solution
If an object just begins to slide on a surface inclined at 30º to the horizontal,the coefficient of friction is?
A
√3
B
\(\frac{√3}{2}\)
C
\(\frac{1}{√2}\)
D
\(\frac{1}{√3}\)
medium Difficulty
Verified Correct Answer: Option D
Physical Principles & Numerical Solution
A body sliding down a plane inclined at 30o to the horizontal,
Has coefficient of friction = tan 30º or \(\frac{1}{\sqrt3}\)
Source: Official Exam / Past Question Archive
Chemistry
WAEC / WASSCE 2022
Electrolysis & Electrochemical Cells
Solution
(a)(i) Define the first ionization energy of an element
(ii) Consider the following table and use it to answer te question that follows
Element
Li
Be
b
C
N
O
F
Ne
Atomic number
3
4
5
6
7
8
9
10
1st I.E/kj mol\(^{-1}\)
520
900
801
1086
1402
1314
1681
2081
Explain briefly why the first ionization energy of B is less than that of Be despite the fact that the atomic number of B is greater than that of Be.
(b) When Titanium chloride was electrolysed by passing 0.12 A current through the solution for 500 seconds, 0.015 g of titanium was deposited. What is the charge on the titanium ion?
[ IF= 96500 C, Ti= 48.0 ]
(c)(i) Aluminium can be obtained by the application of electrolysis. State the electrolyte which yields aluminium on electrolysis.
(ii) Name two major factors which would favour the siting of an aluminium smelter in a country.
(d)(i) Define the term paramagnetism.
(ii) Consider the following ions: 24\(^{Cr ^{2+}}\), 24\(^{Cr^{6+}}\)
(I) Deduce the number of unpaired electrons in each of the ions.
(II) State which of the ions will have a greater power of paramagnetism
(l) Give a reason for the answer stated in (d)(ii)(II)
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)(i) Is the energy required to remove one mole of an electron from a gaseous atom.
OR
Is the minimum energy required to convert one mole of a gas of atom into one mole of a gaseous plus 1 ions
(ii) \(_{4}\)Be: Is\(^{2}\) 2s\(^{2}\)
\(_{5}\)B :Is\(^{2}\) 2s\(^{2}\) 2p\(^{1}\)
The electron to be removed from Be is in the 2s orbital which is closer to the nucleus, nuclear attraction is greater hence first ionization energy is greater but the electron to be removed from B is in the 2p orbital which is farther away from the nucleus, hence nuclear attraction is weaker hence first ionization energy is smaller.
OR
2p has less energy than 2s
So it is easier to remove an electron from 2p as the nuclear charge is weaker in 2p because 2p is further away from the nucleus. Hence, first ionization energy is small.
(b) Q - It
Q = 0.12 x 500
= 60 C
96500 = 1F
= 60 C liberates 0.015g
\(\therefore\) 96500 will liberate \(\frac{96500}{60}\) x 0.015
= 24 g
n((\(T_1\)) = \(\frac{m}{M}\)
= \(\frac{24}{48}\) = 0.5mol
1F = 0.5mol
2F = 1mol
hence charge = +2
Alternative A
Q = lt
= 0.12 x 500
= 60 C
0.015 g of Ti is deposited by 60 C .
\(\therefore\) 48 g will be deposited by = \(\frac{60}{0.015}\) x 45
= 1920000
96500 C\(\equiv\) i mole of electron
\(\therefore\) 192000 C \(\frac{1}{96500}\) x 192
= 1.989
\(\approx\) 2.0 moles of electron
\(\therefore\) charge on Ti ion is +2
Alternate B
\(\frac{m}{M} = \frac{It}{nF}\)
n = \(\frac{Mlt}{mF}\)
= \(\frac{48 \times 0.12 \times 500}{0.015 \times 96500}\)
= 1.989 \(\equiv\) 2
\(\therefore\) Change on Ti ion is +2
(c)(i) Alumina (A\(l_2\)\(_{3}\)) mixed with molten cryolite (N\(a_3\)AI\(F_6\))
(i) - abundant deposits of bauxite
- cheap source of electricity
(d)(i) Is the ability of a substance to be attracted strongly into a magnetic field.
(ii) I. \(_{24}\)Cr\(^{2+}\) - Is\(^{2}\) 2P\(^{6}\) 3S\(^{2}\) 3P\(^{6}\) 3d\(^{4}\)
unpaired electrons = 4
\(_{24}\)Cr\(^{6}\) - Is\(^{2}\) 2s\(^{2}\) 2p\(^{6}\) 3s\(^{2}\) 3d\(^{6}\)
unpaired electrons = 0
(II) \(_{24}\)Cr\(^{2+}\)
III. The greater the number of unpaired electrons in the 3d - orbital, the| greater-the paramagnetism.
Source: Myschool Past Questions Archive (Record #63758)
Chemistry
WAEC / WASSCE 2022
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
(a) (i) Define the term Avogadro's number.
(ii) If 2.30 g of an oxide of nitrogen, x, contains 3.01 x 10\(^{22}\) molecules, calculate the molar mass of x.
(iii) Deduce the formula of x. N, =6.02 x 10", N =14.0, O = 16.0]
(b)(i) Describe briefly what happens when each of the following substances are added to water:
(I) CC\(I_4\); (II) SiC\(I_4\),
(ii) Explain briefly why the reactions in (a)(i), (b)(i), (I) and (b)(ii) (II) are different Study the diagram below and answer the questions that follow.
(c) Study the diagram below and answer the questions that follow.
(i) What is the set up used for?
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)(i) This can be defined as the number of atoms or molecules in one mole of a substance which is equal to 6.02 x 10\(^{23}\)
(ii) Mass/m.m = no. of molecules / Avogadro's number
(2.30 / m.m) x (3.01x10\(^{22}\) / 6.02 x 10\(^{23}\))
m.m = (2.30 x 6.02 x 10\(^{23}\)) / 3.01 x 10\(^{22}\)
m.m = 46g / mol
\(\therefore\) 14+('16 x 2)
14 + 32 = 46g /mol
\(\therefore\) N\(o_2\)
(b)(i) I. Two layers are formed / no reaction / immiscible
II. there is a reaction / hydrolysis with steamy fumes /white fumes
(ii) The reaction occurs by interaction of the tones pair of electrons of water binding to the central atom (silicon or carbon) / attaching to the central atom In silicon, the 3p - orbital is available to accept the pairs of electrons but in carbon, there is no vacant orbitals for bonding.
OR
Water is polar hence the reaction with SiC\(I_4\). But CC\(I_4\) is non-polar hence there is no reaction
(c) (i) - Purification of metals/ copper
- Electroplating
Source: Myschool Past Questions Archive (Record #63812)
Chemistry
UTME / JAMB 2022
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
An organic compound with fishy smell is likely to have a general formula?
A
RCONHR\(^1\)
B
RCONH\(_2\)
C
RNH\(_2\)
D
RCOR\(^1\)
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Amines possess a characteristic ammonia smell, liquid amines have a distinctive "fishy" and foul smell.
-Amine. R-NH2
Source: Myschool Past Questions Archive (Record #64931)