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Chemistry
WAEC / WASSCE 1990
Kinetic Theory of Matter & Gas Laws
The decomposition of hydrogen peroxide is represented by the equation: 2H2O(l) + O2(g) what mass of hydrogen peroxide would be required to produce 22.4dm3 of oxygen at s.t.p? (H = 1, O = 16, molar volume of a gas at s.t.p. = 22.4dm3)
A
18 g
B
34 g
C
36 g
D
64 g
E
68 g
medium Difficulty
Verified Correct Answer: Option E
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option E.
Source: Myschool Past Questions Archive (Record #36117)
Chemistry
WAEC / WASSCE 1990
Nature of Matter & Separation Techniques
Which of the following compounds crystallizes without water of crystallization?
A
Na2CO3
B
CuSO4
C
MgSO4
D
NaCI
E
FeSO4
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #36118)
Chemistry
WAEC / WASSCE 1990
Stoichiometry, Mole Concept & Volumetric Analysis
The following metals are extracted by the electrolytic method except
A
potassium
B
calcium
C
sodium
D
tin
E
magnesium
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #36119)
Chemistry
WAEC / WASSCE 1990
Nature of Matter & Separation Techniques
Petrol can be obtained from diesel by
A
distillation
B
cracking
C
catalysis
D
polymerization
E
dehydrogenation
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option B.
Source: Myschool Past Questions Archive (Record #36120)
Chemistry
WAEC / WASSCE 1990
Acids, Bases, pH & Salts
Solution
(a)(i) Give one laboratory use of activated charcoal
(ii) A piece of phosphorus and some magnesium ribbon were burnt in two separate jars of oxygen. Water was then added to dissolve the product. State the action of litmus on each of the resulting solutions
(b) Give one chemical test to distinguish between CH\(_3\)CH\(_2\)OH and CH\(_3\)COOH.
(c) Describe how you would dilute accurately a solution containing 0.10 mole of the solute per dm\(^3\) of solution to 0.010M.
A
distillation
B
cracking
C
catalysis
D
polymerization
E
dehydrogenation
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
(a)(i) For removing colouring matter or for absorbing gases.
(ii) Solution of magnesium ash turns red litmus blue. MgO + H\(_2\)O = Mg(OH)\(_2\). Solution of phosphorus fumes turns blue litmus red
(b) Add Na\(_2\)CO\(_{3(aq)}\) or NaHCO\(_{3(aq)}\) separately.
- CH\(_3\)COOH gives a colourless gas that turns lime water milky i.e. CO\(_3\)
- CH\(_3\)CH\(_2\)OH gives no visible reaction. We can also use the acidified KMnO\(_4\) rxn, or iodoform rxn or litmus test to distinguish
(c) A stated volume of the solution is pipetted into a clean 250cm\(^3\) volumetric flask. Distilled water is added and the solution is made up to the mark with more distilled water by means of dropping pipette.
Source: Official Exam / Past Question Archive
Chemistry
UTME / JAMB 1990
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The Avogadro number of 24g of magnesium is the same as that of
A
1g of hydrogen molecules
B
16g of oxygen molecules
C
32g of oxygen molecules
D
35.5g of chlorine molecules
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
24mg = 1 mole of magnesium and
32g of O2 = mole of O2
Source: Myschool Past Questions Archive (Record #44453)
Chemistry
WAEC / WASSCE 1990
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
(a) Write the electronic configuration of an element with atomic number 15, indicating the distribution of electrons in the energy sub-levels
(b) Give the formula and the colour of the complex formed between ammonia and copper (II) ions
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a) 1s\(^2\)2s\(^2\)2p\(^6\)3s\(^2\)3p\(^3\)
(b) Cu\(^2\) + 4NH\(_3\) —> Cu(NH\(_3)^{2+}_4\)
(Deep blue in colour)
Source: Myschool Past Questions Archive (Record #54497)
Chemistry
WAEC / WASSCE 1990
Water, Solutions & Solubility
Solution
(a) Give two reasons why carbon(IV) oxide is used for extinguishing fire
(b) Explain briefly the water softening action of cation exchane resins.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a) The non-flamable nature and the high density of carbon (IV) oxkfe makes it suitable for extinguishing fires.
(b) The cation exchange resin is a complex substance which has its cation part capable of being replaced by the calcium ion (Ca\(^{2+}\)) from the hard water run over the resin. The water running out of the resin column is the softened water
Source: Myschool Past Questions Archive (Record #54498)
Chemistry
WAEC / WASSCE 1990
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
A hydrocarbon X which decolorizes bromine water but has no action on ammoniacal silver trioxonitrate (V) solution was found to have a molar mass of 58 g mol\(^{-1}\)
(a) Deduce the molecular formula of X. (H = 1, C = 12)
(b) Write the structures of two isomers of X.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a) The test carried out shows the hydrocarbon x is an alkene. The smallest number of the family is ethene (C\(_2H_4\))
If (\(C+2H_4)_x = 56\)
i.e. (28)x = 56
x = \(\frac{56}{28}\) = 2
2(\(C_2H_4\)) = C\(_4\)H\(_8\)
(b)
Source: Myschool Past Questions Archive (Record #54499)
Chemistry
WAEC / WASSCE 1990
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
(a) Balance the nuclear equation below and hence identify Y.
\(^{238}_{94}U \to ^{234}_{92}Th + Y\)
(b) In a tabular form, state two of the observations in the cathode ray experiment and the corresponding deductions.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a) \(^{238}_{94}U \to ^{234}_{92}Th + Y\)
From above balanced equation \(^4_2Y = ^4_2He\)
(b) Cathode ray experiment
Observations
Deductions
The cathode rays throw a shadow at the anode.
The rays will turn a light paddle wheel is the tube.
Deductions The rays are negatively charged and hence the attraction to the anode.
The rays therefore have momentum and mass.
Source: Myschool Past Questions Archive (Record #54500)
Chemistry
WAEC / WASSCE 1990
Acids, Bases, pH & Salts
Solution
(a) Give one reason why a collision between reactants may not produce new species.
(b) Explain, illustrating with appropriate equation(s), why an aqueous solution of aluminium chloride is acidic.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
a) A collision between reactants may not produce new species because the reactants may the activation energy.
(b) AlCl\(_{3(g)}\) + H\(_2\)O\(_{(l)}\) \(\to\) Al(OH)\(_{3(aq)}\) + HCl\(_{(aq)}\) of the two products of aluminium chloride HCl is a strong acid which will make the medium acidic.
Source: Myschool Past Questions Archive (Record #54501)
Chemistry
WAEC / WASSCE 1990
Chemical Energetics & Thermochemistry
Solution
(a) Give the formula indicating the relationship between entropy, free energy and enthalpy changes of a system.
(b) For each of the following, state whether entropy change is positive, negative or zero.
(i) H\(_2\)O\(_{(g)}\) -> H\(_2\)O\(_{(g)}\)
(ii) Cl\(_{2(g)}\) ---> 2CI\(_{(g)}\)
(iii) HCI\(_{(g)}\) -> HCl\(_{(g)}\)
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a) \(\Delta\)C = \(\Delta\)H - T\(\Delta\)S
(free energy) (enthalpy) (Temperature x Entropy)
(b)(i) Entropy is positive
(ii) Entropy is positive
(iii) Entropy is negative.
Source: Myschool Past Questions Archive (Record #54504)
Chemistry
WAEC / WASSCE 1990
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Benzene contains six carbon atoms and six hydrogen atoms.
(a)(i) Draw two stable structures of benzene to show how these atoms are arranged.
(ii) What is the concept behind these structures?
(b) Give (i) two uses of benzene. (ii) one industrial source of benzene.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)(i)
(ii) Resonance structure
(b)(i) Benzene can be used to make important chemicals such as disinfectant and perfumes.
(ii) Benzene can be obtained from coal tar, a destructive distillate of coal.
Source: Myschool Past Questions Archive (Record #54505)
Chemistry
WAEC / WASSCE 1990
Periodic Table & Periodicity
Solution
(a) Arrange the first three members of the halogen family in their increasing order of electronegativity. Give the reason for your answer.
(b) State and explain what happens when chlorine reacts with starch iodide paper.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a) Bromine — Chlorine — Fluorine Increasing order of electronegativity. The above order is as a result of their decreasing order of atomic size from bromine to fluorine. The smaller the atom, the more the atom is capable of attracting electron to itself.
(b) Iodine is precipitated as the molecular iodine by chlorine gas because chlorine, the more electronegative halogen than iodine displaces the iodine from its seat of combination in the starch iodine paper.
Source: Myschool Past Questions Archive (Record #54506)
Chemistry
WAEC / WASSCE 1990
Metals, Transition Elements & Extraction
Solution
(a) Name the type of solid structure possessed by:
(i) diamond;
(ii) iodine;
(iii) sodium chloride.
(b) Give:
(i) one alloy of tin:
(ii) a common reducing agent which is a compound of tin.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
(a)(i) Diamond is buckled hexagonal giant molecule
(ii) Iodine is covalent molecule.
(iii) Sodium chloride is face - centred cubic
(b)(i) An alloy of tin is bronze (Cu and Sn)
(ii) Tindichloride (SnCl\(_2\)).
Source: Myschool Past Questions Archive (Record #54507)