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Chemistry
WAEC / WASSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Which of the following substances increases in mass when heated in air?
A
Sodium chloride
B
lodine crystals
C
magnesium ribbon
D
copper (ll) oxide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The mass of magnesium ribbon increases when heated in air because it combines with oxygen to form magnesium oxide, a white powder:
The chemical equation for this reaction is:
2Mg + O2 → 2MgO
Source: Myschool Past Questions Archive (Record #36909)
Chemistry
WAEC / WASSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Calculate the mass of sodium hydroxide in 5.00 dm3 of a 0.125 mol dm-3 solution [NaOH = 40 g mol]
A
0.0156 g
B
0.625 g
C
1.00 g
D
25. 0 g
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
1 mole of NaOH per dm3 has a mass of 40g mass of NaOH in 0.125 mole = 0.125 x 40 = 5g mass in 5.00 dm3 of the solution = 5 x 5 = 25.0g
Source: Myschool Past Questions Archive (Record #36910)
Chemistry
WAEC / WASSCE 2001
Acids, Bases, pH & Salts
Solution
Which of the following salt solutions will have a pH greater than 7?
A
NaCl(aq)
B
Na2CO3(aq)
C
Na2SO4(aq)
D
NaHSO4(aq)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The pH of a solution of sodium carbonate is greater than 7 because it's a basic salt. When Na2CO3 is dissolved in water, it undergoes hydrolysis, which produces OH- ions, making the solution pH greater than 7.
Source: Myschool Past Questions Archive (Record #36911)
Chemistry
WAEC / WASSCE 2001
Reaction Rates & Chemical Equilibrium
Solution
What will happen if more heat is applied to the following system at equilibrium? X2(g) + 3Y 2(g) ⇌ 2XY3(g); ∆H =-kJmol -1
A
the yield of XY 3 will decompose
B
more of XY3 will decompose
C
More of X2 will react
D
the forward reaction will go to completion
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
If more heat is applied to an exothermic reaction in equilibrium, it means temperature is increased, this will however, cause the equilibrium shift to the left. This means the product will decompose to produce more of the reactants on the LHS. i.e XY\(_3\) will decompose.
Source: Myschool Past Questions Archive (Record #36912)
Chemistry
WAEC / WASSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Equal amounts of marble chips are reacted separately with 100cm3 of hydrochloric acid of different concentrations . if all the marble chips reacted, which of the following remained the same in each case?
A
Average rate of evolution of gas
B
Total mass of gas evolved during the reaction
C
Time taken for the reaction to reach completion
D
lnitial reaction rates
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When marble chips (calcium carbonate) react with hydrochloric acid, they produce carbon dioxide gas, water, and calcium chloride. The chemical reaction is represented by the equation CaCO3 + 2HCl → CaCl2 + H2O + CO2.
The rate of the reaction is proportional to the number of collisions between reactant molecules. Increasing the concentration of hydrochloric acid increases the number of acid particles in the same volume of liquid, which increases the frequency of collisions. If equal amounts of marble chips react separately with different concentrations of hydrochloric acid, the amount of carbon dioxide gas produced remained the same in each case
Source: Myschool Past Questions Archive (Record #36913)
Chemistry
WAEC / WASSCE 2001
Nature of Matter & Separation Techniques
Solution
CuSO4 5H2O can be obtained from an aqueous solution of copper (ll) tetraoxosulphate (VI) by
A
evaporation to dryness
B
using chromatography
C
precipitation
D
crystallization
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Crystallization is the process by which solids form when atoms or molecules are organized into a crystal structure. The resulting crystal's attributes depend on factors like temperature, air pressure, cooling rate, and time of fluid evaporation. copper (II) sulphate pentahydrate (CuSO4⋅5H2O) can be obtained from an aqueous solution of copper (II) tetraoxosulphate (VI) by crystallization.
Source: Myschool Past Questions Archive (Record #36914)
Chemistry
WAEC / WASSCE 2001
Nature of Matter & Separation Techniques
Solution
Which of the compounds will leave a metal residue when heated?
A
Cu(NO 3 )2
B
AgNO3
C
K2CO3
D
CaCO3
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
AgNO3 is also known as lunar caustic because it: Creates a burning sensation and Leaves a black stain similar to the moon. Silver nitrate (AgNO3) will leave a metal residue when heated strongly.
Source: Myschool Past Questions Archive (Record #36915)
Chemistry
WAEC / WASSCE 2001
Electrolysis & Electrochemical Cells
Solution
A visible change is observed when a strip of iron is placed in an aqueous solution of
A
FeSO4
B
ZnSO4
C
CuSO4
D
MgSO4
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The blue color of the copper sulfate solution fades and eventually turns a pale green or greenish blue color. This is because the iron displaces the copper from the copper sulfate solution, forming ferrous sulfate (FeSO4). A visible change is observed when a strip of iron is placed in an aqueous solution of copper sulfate (CuSO4)
Source: Myschool Past Questions Archive (Record #36916)
Chemistry
NECO SSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
20 cm\(^3\) of 0.09 mol dm\(^{-3}\) solution of tetraoxosuiphate (Vi) acid requires 30cm\(^3\) of sodium hydroxide solution for complete neutralization. The molar concentration of sodium hydroxide is [H = 1; S = 32; 0 = 16; Na = 23]
A
0.03 mol dm3
B
0.12 mol dm3
C
0.27 mol dm3
D
0.45 mol dm3
E
0.90 mol dm3
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
First, write a balanced chemical equation for the neutralization reaction.
H\(_2\)SO\(_4\) + 2 NaOH → Na\(_2\)SO\(_4\) + 2H\(_2\)O
From the balanced equation, N\(_A\) = 1, N\(_B\) = 2
V\(_A\) = 20 cm\(^3\) ; C\(_A\) = 0.09 moldm\(^{-3}\) ; V\(_B\) = 30 cm\(^3\) ; C\(_B\) = ?
Using the formula, \(\frac{C_A V_A}{C_B V_B}\) = \(\frac{N_A}{N_B}\)
C\(_B\) = \(\frac{C_A V_A N_B}{V_B N_A}\)
= \(\frac{0.09 X 20 X 2}{30 X 1}\)
= 0.12 moldm\(^{-3}\)
Source: Myschool Past Questions Archive (Record #43317)
Chemistry
NECO SSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
The decreasing order of the oxidising power of the halogens is
A
Br>I>Cl>F
B
F>I>Cl>Br
C
F>Cl>Br>l
D
I>Br>Cl>F
E
Cl>Br>F>I
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option C.
Source: Myschool Past Questions Archive (Record #43318)
Chemistry
NECO SSCE 2001
Oxidation, Reduction & Redox Reactions
Solution
Which statement BEST describes the process of oxidation?
A
addition of hydrogen
B
loss of oxygen
C
decrease in oxidation number
D
loss of electrons
E
gain of elections.
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
In terms of loss or gain of electron(s), the statement that best describes oxidation is the loss of electrons. Always use the acronym: OIL / RIG.
O- Oxidation
I - Is
L - Loss of electrons
R - Reduction
I - Is
G - Gain of electron
Source: Myschool Past Questions Archive (Record #43319)
Chemistry
NECO SSCE 2001
Nature of Matter & Separation Techniques
Solution
Animal charcoal differs from wood charcoal in that it
A
has a dark colour
B
has a high carbon content
C
is a good absorbent
D
is crystalline.
E
is rich in phosphate content
medium Difficulty
Verified Correct Answer: Option E
Chemical Principles & Mechanism
Animal charcoal or bone black is the carbonaceous residue obtained by the dry distillation of bones. It contains only about 10% carbon, the remaining being calcium and magnesium phosphates (80%) and other inorganic material originally present in the bones.
Source: Myschool Past Questions Archive (Record #43321)
Chemistry
NECO SSCE 2001
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
The atomic number of iron is 56. The number of unpaired electrons in the Fe3+ ion is
A
1
B
2
C
3
D
4
E
5
medium Difficulty
Verified Correct Answer: Option E
Chemical Principles & Mechanism
-There are 4 unpaired electrons in Fe
-However; 5 unpaired electrons are present in Fe3+
Source: Myschool Past Questions Archive (Record #43322)
Chemistry
NECO SSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The use of sulphur to vulcanize rubber is made to make it
A
blacker.
B
cheaper. .
C
more elastic
D
tougher
E
softer.
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The use of sulfur to vulcanize rubber is made to enhance its properties, making it more durable, elastic, and heat-resistant.
Source: Myschool Past Questions Archive (Record #43324)
Chemistry
NECO SSCE 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Which element contains the greatest number of moles?
A
8 g of Helium
B
48 g of Carbon
C
78 g of Potassium
D
130g of Zinc
E
216g of Sliver
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
To find the number of moles, we use the formula n = \(\frac{mass}{Molar Mass}\)
N.B: [ He = 4, C = 12, K =39, Zn = 65, Ag = 108]
A. 8 g of Helium, n = \(\frac{8}{4}\) = 2 moles
B. 48 g of Carbon, n = \(\frac{48}{12}\) = 4 moles
C. 78 g of Potassium, n = \(\frac{78}{39}\) = 2 moles
D. 130g of Zinc, n = \(\frac{130}{65}\) = 2 moles
E. 216g of Sliver, n = \(\frac{216}{108}\) = 2moles
Comparing the results, the element with the greatest number of moles is B. 48 g of Carbon, containing 4 moles.
Source: Myschool Past Questions Archive (Record #43326)