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Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Ethanol can easily be produced by
A
fermentation of starch
B
distillation of starch solution
C
catalytic oxidation of methane
D
destructive distillation of wood
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Ethanol may be produced by either synthetic chemical method or by fermentation of carbohydrate (Starch).
Source: Myschool Past Questions Archive (Record #2132)
Chemistry
UTME / JAMB 2002
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Which of the following gives a precipitate when treated with NaOH solution?
A
AlCl3
B
NH4CL
C
CH3COONa
D
Na2CO3
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The reaction of aluminum chloride, AlCl\(_3\) and sodium hydroxide (NaOH) produces a white precipitate of aluminum hydroxide Al(OH)\(_3\).
Source: Myschool Past Questions Archive (Record #2133)
Chemistry
UTME / JAMB 2002
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
An example of element that can catenate is
A
bromine
B
nitrogen
C
chlorine
D
carbon
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Catenation is the ability of an atom to form chains and rings by sharing electrons with other atoms of the same element. Carbon has a high tendency to catenate because of the strength of its C–C bonds. Carbon's least diffuse valence shell p orbital allows it to form longer p-p sigma bonded chains of atoms than heavier elements.
Source: Myschool Past Questions Archive (Record #2134)
Chemistry
UTME / JAMB 2002
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The reaction of an alkene with hydrogen in the presence of catalyst is
A
a substitution reaction
B
an oxidation reaction
C
a nucleophilic reaction
D
an addition reaction
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
When an alkene reacts with hydrogen in the presence of a catalyst, the reaction is called hydrogenation.
Hydrogenation is an addition reaction that occurs when hydrogen gas is added to an alkene's double bond in the presence of a metal catalyst. The reaction results in the formation of an alkane, which is a saturated compound.
The reaction is also known as catalytic hydrogenation because a catalyst is required for it to occur. The catalyst lowers the activation energy of the reactants, which increases the reaction rate.
Source: Myschool Past Questions Archive (Record #2135)
Chemistry
UTME / JAMB 2002
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The number of isomers formed by C\(_6\)H\(_{14}\) is
A
4
B
5
C
2
D
3
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The five structural isomers of C\(_6\)H\(_{14}\), also known as hexane, are:
n-hexane: Has only primary and secondary carbon atoms
2-methylpentane: Has a single tertiary carbon atom
3-methylpentane: Has a tertiary carbon atom
2,2-dimethylbutane: Has two tertiary carbon atoms
2,3-dimethylbutane: Has two tertiary carbon atoms.
Source: Myschool Past Questions Archive (Record #2136)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Which of these pairs are synthetic and natural macromolecules respectively?
A
Haemoglobin and nylon, creatine and polyethylene
B
Nylon and polyethlene, creatine and Haemoglobin
C
Nylon and creatine, polyethylene and haemoglobin
D
Creatine and Polyethylene, nylon and haemoglobin
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A macromolecule is a very large molecule, usually with a diameter of 100 to 10,000 angstroms (10−5 to 10−3 mm).
Nylon is a synthetic macromolecule that's made up of repeating subunits called monomers. It's created through a condensation polymerization reaction between adipic acid and hexamethylene diamine.
Polyethylene is a synthetic polymer, which means it's made by scientists and engineers from petroleum oil.
Creatine is a non-protein compound that is derived from amino acids, and is produced in the body by the liver, kidneys, and pancreas. It is also found in protein-rich foods like meat, fish, and milk.
Hemoglobin is a natural organic(natural) macromolecule.
Source: Myschool Past Questions Archive (Record #2137)
Chemistry
UTME / JAMB 2002
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Ordinary glass is manufactured from silica, CaCO3 and
A
Na2CO3
B
K2CO3
C
K2SO4
D
NaHCO3
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Ordinary glass is made from sand(silica), limestone(CaCO\(_3\) and soda ash, Na\(_2\)CO\(_3\).
Source: Myschool Past Questions Archive (Record #2138)
Chemistry
UTME / JAMB 2002
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
A red precipitate of copper (I) carbide is formed when ammonium solution of copper (I) chloride is introduced into
A
CH3CH2CH2CH3
B
CH2 = CH - CH2CH3
C
HC≡CH
D
CH3 - C = C - CH3
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When ethyne is passed through an ammoniacal solution of copper(I) chloride, a red-brown precipitate of copper(I) acetylide is produced. Terminal alkynes also react to form a red-brown precipitate
Source: Myschool Past Questions Archive (Record #2139)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The boiling of fat and aqueous caustic soda is referred to as
A
hydrolysis
B
esterification
C
acidification
D
saponification
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Saponification is a process that involves the conversion of fat, oil, or lipid, into soap and alcohol by the action of aqueous alkali.
Source: Myschool Past Questions Archive (Record #2140)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The most important use of hydrogen is in the
A
manufacture of ammonia
B
manufacture of methyl alcohol
C
manufacture of ethyl alcohol
D
hydrogenation of oils
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The most important use of hydrogen is the ammonia synthesis or manufacture of ammonia(Haber process). The use of hydrogen is extending quickly in fuel refinement, like the breaking down by hydrogen (hydrocracking), and in sulphur elimination.
Source: Myschool Past Questions Archive (Record #2141)
Chemistry
UTME / JAMB 2002
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
which of the following polymers is suitable for packaging and electrical insulation?
A
polyamide
B
polyethene
C
polycarbonate
D
polystyrene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Polyvinyl Chloride (PVC) and polyethylene (PE) are polymers that are used for both packaging and electrical insulation.
Polyethylene or polyethene (PE) is a popular plastic used for insulating cables, wires, bushings, and transformer components. PE has excellent insulation properties and high dielectric strength. However, Polyethylene is a good choice for packaging because it's non-toxic, food safe, and can be customized into many shapes and sizes. It's also resistant to chemicals, UV light, and moisture, and can be reused while polystyrene is a good choice for electrical insulation because it has low thermal conductivity and prevents the flow of electrical current. Since polystyrene can serve both purposes, it's a better answer compared to polyethene.
Source: Myschool Past Questions Archive (Record #2142)
Chemistry
UTME / JAMB 2002
Periodic Table & Periodicity
Solution
Hydrogen is readily released when dilute hydrochloric acid reacts with
A
Cu
B
Na
C
Au
D
Ag
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When alkali metals react with Hydrochloric acids. hydrogen gas is usually produced. Hence, Sodium belongs to the group of Alkali metals.
Na + HCl → NaCl + H\(_2\)
Source: Myschool Past Questions Archive (Record #2143)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The intermediate product formed when ethanol is progressively oxidized to ethanoic acid with potassium heptaoxodichromate (IV) is
A
butanal
B
ethanal
C
methanal
D
propanal
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The complete oxidation of ethanol to ethanoic acid is a stepwise process that involves the following steps:
Ethanol is oxidized to ethanal
Water adds an oxygen atom to ethanal
Ethanoic acid is formed.
Source: Myschool Past Questions Archive (Record #2144)
Chemistry
UTME / JAMB 2002
Oxidation, Reduction & Redox Reactions
Solution
A rock sample was added to cold dilute HNO3. The gas evolved was passed into a solution of acidified K2Cr2O7 and the solution turned green. The sample contains
A
Cl-
B
NO3-
C
SO32-
D
SO42-
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sulphur dioxide reacts with potassium dichromate and sulphuric acid to produce potassium sulphqqqqqqqqqqqqqqqate, chromium(III) sulfate and water and the solution turns from orange to green.
Source: Myschool Past Questions Archive (Record #2145)
Chemistry
UTME / JAMB 2002
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
Which of the following statement is true of a proton?
A
The mass of a proton is 1840 times the mass of electron
B
the total mass of the protons in a particular nucleus is always half the nuclear size
C
The mass of a proton is one - twelfth the molar mass of carbon
D
The mass of a proton is 1.0008g
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The mass of a proton is 1.6726\times10−24 g, while the mass of a proton = 1.00727 a . m. u. so OPTION A is correct because the mass of an electron is \(\frac{1}{1840}\) of that of a proton, which is the same as say the mass of a proton is 1840 times the mass of an electron.
Source: Myschool Past Questions Archive (Record #2146)