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Chemistry
UTME / JAMB 2003
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
Metals of the first transition series have special properties which are different from those of groups I and II elements because they have partially filled
A
s orbitals
B
p orbitals
C
d orbitals
D
f orbitals
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Transition elements (also known as transition metals) are elements that have partially filled d orbitals.
Source: Myschool Past Questions Archive (Record #2515)
Chemistry
UTME / JAMB 2003
Acids, Bases, pH & Salts
Solution
Which of the following statements is true of sulphur (IV) oxide?
A
It forms tetraoxosulphate (VI) acid with water
B
It is an odourless gas
C
It is an acid anhydride
D
It forms white precipitate with acidified barium chloride
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sulphur(iv) oxide(SO\(_2\)) is an acid anhydride, meaning it's a non-metal oxide that reacts with water to form an acidic solution. It's also known as sulphurous anhydride. sulphur dioxide (SO\(_2\)) is an acid anhydride, meaning it's a non-metal oxide that reacts with water to form an acidic solution.
Source: Myschool Past Questions Archive (Record #2517)
Chemistry
UTME / JAMB 2003
Water, Solutions & Solubility
Solution
The salt that will form a precipitate soluble in excess ammonia solution is
A
Ca(NO3)2
B
Cu(NO3)2
C
Mg(NO3)2
D
Al(NO3)3
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When ammonia is added to a copper(II) nitrate solution, a pale blue precipitate of copper(II) hydroxide (Cu(OH)2) forms. The balanced equation for this reaction is
Cu(NO\(_3\))\(_2\) + 2NH\(_4\)OH→Cu(OH)2↓ + 2NH\(_4\)NO\(_3\)
Excess ammonia: When more ammonia is added, the precipitate dissolves and forms a deep blue solution of tetraammine copper(II) nitrate. The balanced equation for this reaction is Cu(OH)2(s)+4NH3(aq)−⇀↽−[Cu(NH3)4]+2(aq)+2OH−(aq)
This happens because the addition of more ammonia causes the formation of a coordination complex cation of copper(II) bonded to four ammonia molecules. This shifts the solubility equilibrium of copper(II) hydroxide to the right, causing the precipitate to dissolve.
Source: Myschool Past Questions Archive (Record #2518)
Chemistry
UTME / JAMB 2003
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The metal that liberates hydrogen from cold water in bubbles only is?
A
Na
B
K
C
Ca
D
Al
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
After a second or so, the calcium metal begins to bubble vigorously as it reacts with the water, producing hydrogen gas, and a cloudy white precipitate of calcium hydroxide.
Source: Myschool Past Questions Archive (Record #2519)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Chlorine gas turns a damp starch-iodide paper
A
pink
B
colourless
C
red
D
dark blue
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Chlorine gas turns damp starch-iodide paper blue-black.
The chlorine oxidizes the iodide ions on the paper into iodine, which then reacts with the starch to produce a blue-black compound.
Chemical reaction: The chemical reaction is:
Cl\(_2\)(aq) + 2I\(^−\)(aq) → I\(_2\)(aq) + 2Cl\(^−\)(aq)
Source: Myschool Past Questions Archive (Record #2520)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The modern process of manufacturing steel for iron is by
A
treatment with acids
B
oxidation
C
blast reduction
D
treatment with alkanal
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Modern steelmaking involves two primary steps that transform iron ore into the final product. While the initial stage of extracting iron from its ore in a blast furnace is a reduction process (using carbon monoxide to remove oxygen from the iron oxide), the actual conversion of that iron into steel is an oxidation process.
Source: Myschool Past Questions Archive (Record #2521)
Chemistry
UTME / JAMB 2003
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Ethene reacts with hydrogen bromide to give
A
CH2Br2
B
CH3CH2Br
C
C2H2Br2
D
CHBr2
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When ethene, C\(_2\)H\(_4\) reacts with hydrogen bromide (HBr), the product is bromoethane (C\(_2\)H\(_5\)Br):
C\(_2\)H\(_4\) + HBr → C\(_2\)H\(_5\)Br
This reaction is an addition reaction where HBr adds across the double bond of ethene:
The double bond breaks
A hydrogen atom attaches to one of the carbons
A bromine atom attaches to the other
Source: Myschool Past Questions Archive (Record #2522)
Chemistry
UTME / JAMB 2003
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
How many isomers does pentane have?
A
6
B
5
C
4
D
3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Isomers are chemical compounds with the same Molecular formula but different structural formula or arrangements of atoms in the molecule.
Pentane, an organic compound with the chemical formula C\(_5\)H\(_{12}\), has three structural isomers:
n-pentane: A straight chain of five carbon atoms
2-methylbutane: A four-carbon chain with a methyl group branching off the second carbon atom
2,2-dimethylpropane: A three-carbon chain with two methyl groups branching off the middle carbon atom
Source: Myschool Past Questions Archive (Record #2523)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The leachate of a certain plant ash is used in local soap making because it contains
A
sodium chloride and potassium hydroxide
B
sodium hydroxide
C
potassium hydroxide
D
soluble carbonates and hydrogen carbonates
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The leachate of certain plant ash, especially from hardwoods, is used in local soap making because it contains potassium hydroxide (KOH), which is a type of lye. KOH is an alkaline substance that reacts with fats to produce soap through a process called saponification. While sodium hydroxide (NaOH) is also used in soap making, KOH-based soaps are known to be softer and are often used in liquid soap formulations.
Source: Myschool Past Questions Archive (Record #2524)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The formula for ethyl butanoate is
A
C3H7COOC2H5
B
C2H5COOC3H7
C
C4H9COOC2H5
D
C2H5COOC4H9
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Ethyl butyrate, also known as ethyl butanoate, or butyric ether, is an ester with the chemical formula CH₃CH₂CH₂COOCH₂CH₃.
Source: Myschool Past Questions Archive (Record #2525)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Ethanol reacts with excess acidified K\(_2\)Cr\(_2\)O\(_7\) to produce
A
ethanedioic acid
B
ethanal
C
ethylethanoate
D
ethanoic acid
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
When ethanol reacts with excess acidified potassium dichromate, it produces ethanoic. This reaction occurs in two steps:
Ethanol to ethanal: Ethanol is oxidized to ethanal.
Ethanal to ethanoic acid: Ethanal is oxidized to ethanoic acid.Potassium dichromate is a strong oxidizing agent. During the reaction, the color changes from orange to green.
Source: Myschool Past Questions Archive (Record #2527)
Chemistry
UTME / JAMB 2003
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
A compound contains 40.0% carbon 6.7% hydrogen and 53.3% oxygen. If the molar mass of the compound is 180, find the molecular formula.
[H = 1, C = 12, O = 16]
A
CH2O
B
C3H6O3
C
C6H12O6
D
C6H12O3
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
C - 40% ; 40/12 = 3.33
H - 6.7% ; 6.7/1 = 6.7
O - 53.3% ; 53.3/16 = 3.33
C = 3.33/3.33 = 1
H = 6.7/3.33 = 2
O = 3.33/3.33 = 1
CH2O
(CH2O)n = 180
(12 + 2 + 16)~n = 180
30n = 180
n = 6
= C6H12O6
Source: Myschool Past Questions Archive (Record #2528)
Chemistry
UTME / JAMB 2003
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The process by which atoms are rearranged into different molecular structure in the petroleum refining process is referred to as
A
catalytic cracking
B
hydrocracking
C
polymerization
D
reforming
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Reforming is a chemical process that changes the molecular structure of hydrocarbons to improve their properties. It's often used to improve the combustion characteristics of low-quality gasoline stocks. Reforming can be done using thermal or catalytic methods.
Source: Myschool Past Questions Archive (Record #2529)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Which of the following is found in cotton
A
Starch
B
Cellulose
C
Fat
D
Oil
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Cotton fibers are the dried-out remains of long and thick cell walls. The secondary cell wall of a cotton fiber is made of pure cellulose, while the non-cellulosic components are located in the outer layers or inside the lumens of the fibre.
Source: Myschool Past Questions Archive (Record #2530)
Chemistry
UTME / JAMB 2003
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The principal constituent of natural gas is
A
methane
B
ethane
C
propane
D
butane
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Natural gas is mostly methane, with small amounts of other alkanes like ethane, propane, butane, and pentane. It may also contain trace amounts of contaminants like water vapour, carbon(iv)oxide, nitrogen, and hydrogen sulphide. The main constituent of natural gas is methane, CH\(_4\), a simple hydrocarbon compound.
Source: Myschool Past Questions Archive (Record #2531)