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Chemistry
UTME / JAMB 2004
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Oxyacetylene flame is used for iron-welding because it
A
Makes the iron metals solidify very quickly
B
Combines with oxygen to give a pop sound
C
Evolves a lot of heat when burnt
D
Dissociates to produce carbon (IV) oxide and oxygen
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Oxyacetylene flames are used for welding iron because they produce a very high temperature that melts the iron. The flame produced by oxyacetylene is very hot, reaching temperatures of around 3,100^\circC. This is hot enough to melt steel, which has a melting point of over 1,500^\circC.
Source: Myschool Past Questions Archive (Record #2943)
Chemistry
UTME / JAMB 2004
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The alkyl group can be represented by the general formula
A
CnH2n+1
B
CnH2n
C
CnH2n+2
D
CnH2n-2
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The alkyl group is a type of functional group that has a carbon and hydrogen atom present in its structure. The general formula for an alkyl group is C\(_n\)H\(_{2n+1}\), where n represents a number or integer.
Source: Myschool Past Questions Archive (Record #2944)
Chemistry
UTME / JAMB 2004
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
An isomer of C\(_5\)H\(_{12}\) is
A
Butane
B
2 – methylbutane
C
2 – methylpropane
D
2 – ethylbutane
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
There are three isomers of C\(_5\)H\(_{12}\). They include n-pentane , 2 - methyl butane and 2,2-dimethylpropane.
Source: Myschool Past Questions Archive (Record #2945)
Chemistry
UTME / JAMB 2004
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
A characteristic of the alkane family is
A
Addition reaction
B
Elimination reaction
C
Substitution reaction
D
Neutralization reaction
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Substitution reactions are a characteristic reaction of alkanes because they are saturated compounds with only single bonds. This means that hydrogen atoms in an alkane can be easily replaced by other atoms or groups.
Source: Myschool Past Questions Archive (Record #2946)
Chemistry
UTME / JAMB 2004
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of these reagents can confirm the presence of a triple bond?
A
Bromine water
B
Acidified KMnO4
C
Copper (I) chloride
D
Bromine gas
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Copper(I) chloride does not confirm the presence of a triple bond, rather it is ammoniacal cuprous chloride (Cu(NH\(_3\))\(_2\)ClOH)(CuCl) that can be used to distinguish between double and triple bonds in unsaturated hydrocarbons. The test involves reacting the compound with ammoniacal cuprous chloride to see if a red precipitate forms. If a red precipitate forms, the compound is an alkyne and contains at least one triple bond. If no precipitate forms, the compound is an alkene and contains at least one double bond.
To confirm the presence of a triple bond, you can use bromine water (Br₂) or Baeyer's reagent (alkaline potassium permanganate), both of which react with unsaturated bonds (double or triple) by addition reactions, causing the colour of the reagent to disappear.
Source: Myschool Past Questions Archive (Record #2947)
Chemistry
UTME / JAMB 2004
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Vulcanization involves the removal of
A
a monomer
B
the single bond
C
the double bond
D
a polymer
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Vulcanization can cause isomerization of a double bond. This isomerization is a type of stereoisomerism, which is a change in the relative positions of atoms in a molecule. Vulcanization is a process that hardens rubber by forming cross-links between polymer chains.
Source: Myschool Past Questions Archive (Record #2948)
Chemistry
UTME / JAMB 2004
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
CH\(_3\)COOH(g) → CH\(_4\)(g) + CO\(_2\)(g)
The reaction above is
A
Carboxylation
B
Decarboxylation
C
Acidification
D
Esterification
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The decarboxylation reaction of acetic acid (CH\(_3\)COOH) is a process that removes the carboxyl group (−COOH) and replaces it with a hydrogen atom. The reaction produces methane (CH\(_4\)), carbon dioxide (CO\(_2\)).
Source: Myschool Past Questions Archive (Record #2949)
Chemistry
UTME / JAMB 2004
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
C\(_2\)H\(_5\)OH(aq) → Y
If the above reaction takes place in conc. H\(_2\)SO\(_4\) at 180\(^0\)C, Y represents
A
CH4
B
C2H5COOH
C
C2H4
D
CH3OCH3
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Dehydration of ethanol is the process of removing water from ethanol to produce ethene, CH\(_2\)=CH\(_2\). This process can be achieved by heating ethanol with concentrated sulphuric acid H\(_2\)SO\(_4\)
Source: Myschool Past Questions Archive (Record #2950)
Chemistry
UTME / JAMB 2004
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Alkanol + Alkanoic acid ⇌ Ester + Water
The reverse reaction above is known as
A
Hydrolysis
B
Saponification
C
Hydration
D
Fermentation
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The reverse reaction of esterification is hydrolysis.
Esterification: A reaction that produces an ester and water when an alcohol and an alkanoic cid react.
Hydrolysis: A reaction that produces an alcohol and a carboxylic acid when an ester reacts with water and a strong acid.
Source: Myschool Past Questions Archive (Record #2951)
Chemistry
UTME / JAMB 2004
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
In the production of soap, concentrated sodium chloride solution is added to
A
Increase the solubility of soap
B
Decrease the solubility of the soap
C
Saponify the soap
D
Emulsify the soap
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Concentrated Sodium chloride solution, or salt, is commonly added to soap solutions to precipitate out the soap as a solid, making it easier to separate and purify. This process is called "salting out" and it relies on the common ion effect.
Adding salt increases the ionic strength of the solution, reducing the solubility of the soap and causing it to precipitate out of solution.
Source: Myschool Past Questions Archive (Record #2952)
Chemistry
UTME / JAMB 2004
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The IUPAC nomenclature of the compound above is
A
2-ethylpentane
B
3,4-dimethylhexane
C
2,3-dimethylhexane
D
2-ethylhexane
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Firstly, the longest Carbon chain is a straight chain 6 C atoms ⇒ parent name is hexane
Secondly, there are two methyl, CH\(_3\) substituents on C-2 and C-3 ⇒ 2,3 - dimethyl
Finally, merge both the substituent as well as the parent name together ⇒ 2,3 - dimethylhexane
Source: Official Exam / Past Question Archive
Chemistry
UTME / JAMB 2004
Periodic Table & Periodicity
Diagram
Solution
In the experiment above, X is a mixture of nitrogen, carbon (IV) oxide and
Attached Figure / Diagram
A
water
B
impurities
C
inert gas
D
oxygen
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Recall that Air is a mixture of gases. These gases comprises mainly nitrogen, oxygen, carbon(IV) oxide, noble gases, and water vapour.
From the experiment, the alkaline pyrogallol has already absorbed the oxygen, while the anhydrous calcium chloride being a drying agent has also absorbed the moisture content (water vapour) leaving behind Nitrogen, Carbon(IV) oxide and noble or inert gases.
Source: Myschool Past Questions Archive (Record #31617)
Chemistry
UTME / JAMB 2004
Organic Chemistry I: Hydrocarbons & Crude Oil
Diagram
Solution
The IUPAC nomenclature of the compound above is
Attached Figure / Diagram
A
2-ethylpentane
B
3,4-dimethylhexane
C
2,3-dimethylhexane
D
2-ethylhexane
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Firstly, the longest Carbon chain is a straight chain 6 C atoms ⇒ parent name is hexane
Secondly, there are two methyl, CH\(_3\) substituents on C-2 and C-3 ⇒ 2,3 - dimethyl
Finally, merge both the substituent as well as the parent name together ⇒ 2,3 - dimethylhexane
Source: Myschool Past Questions Archive (Record #31618)
English Language
WAEC / WASSCE 2004
Antonyms (Opposite in Meaning)
In each of the following sentences, there is one word underlined and one gap. From the list of words lettered A - D, choose the word that is most nearly opposite in meaning to the underlined word and that will, at the same time, correctly fill the gap in the sentences.
The man refused to accept the offer of a job in the rural area: he preferred one in the ............area.
A
local
B
urban
C
township
D
municipal
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option B.
Source: Myschool Past Questions Archive (Record #25286)
English Language
WAEC / WASSCE 2004
Antonyms (Opposite in Meaning)
In each of the following sentences, there is one word underlined and one gap. From the list of words lettered A - D, choose the word that is most nearly opposite in meaning to the underlined word and that will, at the same time, correctly fill the gap in the sentences.
He is quite an outspoken young man but his father is ..........
A
humorous
B
sober
C
taciturn
D
silent
medium Difficulty
Verified Correct Answer: Option C
Grammar & Contextual Explanation
No expanded working has been attached for this question yet. The verified answer is Option C.
Source: Myschool Past Questions Archive (Record #25287)