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Chemistry
WAEC / WASSCE 2005
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Credit will be given for strict adherence to instructions, for observations precisely recorded, and for accurate inferences. All tests, observations, and inferences must be clearly entered in your answer book, in ink, at the time they are made.
C Is an inorganic salt. D is an organic compound. Carry out the following exercises on C and D. Record your observations and identify any gases evolved. State the conclusion you draw from the result of each test.
(a) (i) Put C in a test tube and add about 10 cm\(^3\) of distilled water. Stir well.
(ii) Divide the resulting solution into two portions. To the first portion add sodium hydroxide solution in drops and then in excess.
(iii) To the second portion add dilute trioxonitrate (V) acid. Then add silver trioxonitrate (V) solution followed by aqueous ammonia in excess. tube and odd about 2- 5 cm\(^3\) of 'Xn'.
(ii) Identify the functional group present in D.
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
Test
Observation
Inference
(i) C + 10cm\(^3\) of water
Dissolves forming a solution
C is soluble in water
(ii) Solution C + NaOH\(_{(aq)}\) in drops and excess
White precipitate which is insoluble in excess
Ca\(^{2+}\) is present
iii) Solution C + HNO\(_{3(aq)}\) + AgNO\(_{3(aq)}\) + NH\(_{3(aq)}\)
in excess
No visible reaction. A white precipitate formed. The precipitate is soluble
Cl\(^{-1}\) present
Cl\(^{-}\) confirmed
(iv) D + NaHCO\(_3\)
Effervescence occurs, colourless gas evolved which turns lime water milky
D is an organic acid or an alkanoic acid
Source: Myschool Past Questions Archive (Record #60064)
Chemistry
WAEC / WASSCE 2005
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
All your burette readings (initial and final), as well as the size of your pipette, must be recorded but no account of experimental procedure is required. All calculations must be done in your answer book.
A is a solution of H\(_2\)SO\(_4\) containing 4.9 gdm-3, B is a solution containing X g dm\(^{-3}\) of Na\(_2\)CO\(_3\).
(a) Put A into the burette and titrate it against 20.0 cm\(^3\) or 25.0 cm\(^3\) portions of B using methyl orange as an indicator. Record the volume of your pipette. Tabulate your burette readings and calculate the average volume of A used. The equation for the reaction involved in the titration is; H\(_2\)SO\(_{4(aq)}\) + Na\(_2\)CO\(_{3(aq)}\) \(\to\) N\(a_2\)SO\(_{4(aq)}\) + H\(_2\)O\(_{(l)}\) + CO\(_{2(g)}\)
(b) From your results and information provided above, calculate the:
(i) Concentration of A In mol dm\(^{-3}\)
(ii) concentration of B in mol dm\(^{-3}\)
(iii) mass of salt formed when 500 cm\(^3\) of B is Completely neutralized by A.
(v) volume of carbon (IV) oxide liberated in (b) (ii) above at s.t.p. [O = 16, Na = 23, S = 32, 1 mole or a gas occupies 22.4 dm\(^3\) at s.t.p.]
medium Difficulty
Verified Correct Answer: Option
Chemical Principles & Mechanism
Titration/Burette Reading
Rough(cm\(^3\))
1st Titre (cm\(^3\))
2nd Titre (cm\(^3\)
3rd Titre (cm\(^3\))
Final Reading
22.80
22.70
32.70
22.70
Initial Reading
0.00
0.00
10.00
0.00
Volume of acid used
22.00
22.70
22.70
22.70
Volume of pipette used = 25.00 cm\(^3\)
Average volume of acid = \(\frac{22.70 + 22.70 +22.70}{3}\)
= \(\frac{68.10}{3}\)
= 22.70 cm\(^3\)
(b)(i) Concentration of A in mol/dm\(^3\) = \(\frac{\text{conc. of A in g/dm}^3}{\text{Molar mass of A}}\)
Molar mass of H\(_2\)SO\(_{4(aq)}\) = 1 x 2 + 32 x 16 x 4 = 98 g/mol
Conc. of A in mol/dm\(^3\) = \(\frac{4.9}{98}\) = 0.05 mol/dm\(^3\)
(ii) H\(_2\)SO\(_4\) + Na\(_2\)CO\(_{3(aq)}\) \(\to\) Na\(_2\)SO\(_{4(aq)}\) + H\(_2\)O\(_{(l)}\) + CO\(_{2(g)}\)
\(\frac{C_AV_A}{C_BV_B} = \frac{\text{Mole ratio of acid}}{\text{Molar ration of base}}\)
\(\frac{0.05 \times 22.7}{C_B \times 25} = \frac{1}{1}\)
C\(_B\) = \(\frac{0.05 \times 22.7 \times 1}{25 \times 1}\)
= 0.0454
C\(_B\) = 0.05 3 S.F
C\(_B\) = 0.05 mol/dm\(^3\)
(iii) Moles of B = \(\frac{ \text{conc. of B in mol/dm}^3 \times Volume of B}{1000}\)
\(\frac{0.05 \times 500}{1000}\) = 0.025 moles
Molar mass of Na\(_2\)SO\(_4\) = 2 x 23 + 32 + 16 x 4 = 142 g/mol
1 mole of B formed 142g of Na\(_2\)SO\(_4\)
0.025 moles of B will form \(\frac{0.025 \times 142}{1}\) = 3.55 g
(iv) 1 mole of B produces 22.4 dm\(^3\) of CO\(_2\) at s.t.p.
0.025 mole of B will produce 0.025 x 22.4 = 0.56 dm\(^3\) of CO\(_2\) at s.t.p. C is CaCl\(_2\), D is CH\(_3\)COOH or Benzoic acid
Source: Myschool Past Questions Archive (Record #60066)
Chemistry
UTME / JAMB 2005
Organic Chemistry I: Hydrocarbons & Crude Oil
Diagram
Solution
The IUPAC nomenclature for the hydrocarbon above is
Attached Figure / Diagram
A
1,2 - dimethylprop-2-ene
B
1,1- dimethylprop-2-ene
C
2-methylbut-3-ene
D
3-methylbut-1-ene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The IUPAC nomenclature for the hydrocarbon is 3-methylbut-1-ene.
First, identify the longest C- chain. The longest 4 Carbon atoms → But-1-ene (because of the double bond on C-1 which depicts an ethene)
Secondly, the substituent functional group methyl CH\(_3\) → 3-methyl (because the methyl is on C-3 with reference from where the double bond counts from)
Lastly, add up step 2 and 1 → 3-methyl but-1-ene.
Source: Myschool Past Questions Archive (Record #72272)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
No wonder Sikemi later became a detective; she has been very observant.
A
curious
B
perceptive
C
inductive
D
inquisitive
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
"Perceptive" refers to the ability to perceive or understand things quickly and accurately, often through observation or insight. In the context of the sentence, Sikemi's observant nature suggests that she is perceptive, noticing details and understanding situations well.
Source: Myschool Past Questions Archive (Record #40452)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
Nigeria has been playing a vital role in the political and economic development of Africa.
A
creditable
B
crucial
C
respectable
D
laudable
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
"Crucial" means extremely important or essential. It is similar to the idea of playing a vital role in the development of Africa.
Source: Myschool Past Questions Archive (Record #40453)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
Emeka's painting was so realistic that it could almost have been a photograph.
A
picturesque
B
concrete
C
lively
D
authentic
medium Difficulty
Verified Correct Answer: Option D
Grammar & Contextual Explanation
"Authentic" in this context implies genuine or true to life, similar to being realistic. It suggests that Emeka's painting closely resembles reality and is not artificial or exaggerated.
Source: Myschool Past Questions Archive (Record #40454)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
Courteously, Ade stood back to let his teacher go first through the door
A
calmly
B
politely
C
carefully
D
patiently
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
The word "courteously" means in a polite, considerate, or mannerly way. In the context of the sentence, Ade is showing courtesy by standing back and letting his teacher go through the door first. Therefore, the word "polite" in option B is the closest in meaning to "courteously." Both words convey the idea of behaving with good manners and showing respect.
Source: Myschool Past Questions Archive (Record #40455)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
Many people used to live in poverty.
A
instability
B
want
C
difficulty
D
the slums
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
The word "poverty" refers to the state of being extremely poor, lacking basic necessities or financial resources. Option B, "want," is the option nearest in meaning. "Want" can be used as a synonym for poverty, indicating a state of lacking material possessions or financial means.
Options A, C, and D do not accurately capture the meaning of living in poverty. Option A, "instability," generally refers to a lack of stability, option C, "difficulty," is more about challenges in general, and option D, "the slums," refers specifically to impoverished areas rather than the state of poverty itself.
Source: Myschool Past Questions Archive (Record #40456)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
Accountability is certainly a desirable quality in a politician.
A
respectability
B
courage
C
responsibility
D
diligence
medium Difficulty
Verified Correct Answer: Option C
Grammar & Contextual Explanation
"Accountability" and "responsibility" are closely related concepts that both involve being answerable for one's actions or duties. In the context of the sentence, accountability is described as a desirable quality, indicating the importance of being responsible and accountable for one's decisions and actions, especially for a politician.
Source: Myschool Past Questions Archive (Record #40457)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
The common practice among some media practitioners is to be sensational in their reporting.
A
prevalent
B
rampant
C
ordinary
D
cogent
medium Difficulty
Verified Correct Answer: Option A
Grammar & Contextual Explanation
"Prevalent" means widespread or commonly occurring.
Source: Myschool Past Questions Archive (Record #40458)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
That fateful decision changed the company's outlook in many ways.
A
wonderful
B
disastrous
C
uncontrollable
D
unsuccessful
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
fateful
adjective fate·ful \ˈfāt-fəl\
Simple Definition of fateful : having important results : producing a serious and usually bad result
Synonyms = calamitous, cataclysmal (or cataclysmic), catastrophic, damning, destructive, disastrous, fatal, ruinous, unfortunate
Source: Myschool Past Questions Archive (Record #40459)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
The accident victim received a superficial wound from the crash
A
a serious
B
a painless
C
an internal
D
an external
medium Difficulty
Verified Correct Answer: Option D
Grammar & Contextual Explanation
"Superficial" typically refers to something that is on the surface or not deep, so an "external" wound, which is on the outside of the body is the nearest in meaning.
Source: Myschool Past Questions Archive (Record #40461)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
The boxer fizzled out just in the sixth round
A
knocked out his opponent
B
showed off his talents
C
became tired but fought on spiritedly
D
surrendered rather disappointingly
medium Difficulty
Verified Correct Answer: Option D
Grammar & Contextual Explanation
To fizzle out means to gradually end, often in a disappointing or weak way. It’s like a firework that starts with a promising spark but then fades away without much impact. For instance, if someone’s enthusiasm for a project or reform wanes after an initial burst of energy, we can say it fizzled out. "Fizzled out" can also imply a disappointing or unsatisfactory end, such as giving up or surrendering in a disappointing manner.
Source: Myschool Past Questions Archive (Record #40462)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
The manager described Mfon as a man of vehement character.
A
weak and interesting
B
strong and insistent
C
troublesome and noisy
D
clever and helpful
medium Difficulty
Verified Correct Answer: Option B
Grammar & Contextual Explanation
"Vehement" means showing strong feelings or passion, often characterised by intensity or insistence. Therefore, describing Mfon as a man of vehement character implies that he is strong-willed, determined, and insistent in his actions or beliefs.
Source: Myschool Past Questions Archive (Record #40463)
English Language
UTME / JAMB 2005
Synonyms (Nearest in Meaning)
Solution
Choose the option nearest in meaning to the word or phrase underlined.
Obi's dog is old but still lively
A
attractive
B
howling
C
barking
D
frisky
medium Difficulty
Verified Correct Answer: Option D
Grammar & Contextual Explanation
"Lively" typically describes someone or something full of energy, active or spirited. Similarly, "frisky" suggests liveliness, playfulness or being full of vigour.
Source: Myschool Past Questions Archive (Record #40464)