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Chemistry
UTME / JAMB 2018
Stoichiometry & Mole Concept
Solution
An element X forms the following compounds with chlorine; XCl\(_4\), XCl\(_3\), XCl\(_2\). This illustrates the
A
law of multiple proportions
B
law of chemical proportions
C
law of simple proportions
D
law of conservation of mass
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The law of multiple proportion states that when element A and B combine to form more than one chemical compound then the various masses of sample A react with a fixed mass of sample B are in a simple multiple ratio.
Source: Myschool Past Questions Archive (Record #47646)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
The hydrogen ion concentration of a sample of orange juice is 2.0 X 10\(^{-11}\)moldm\(^{-3}\). What is its p\(^{OH}\)? [log102 = 0.3010]
A
3.30
B
13.00
C
10.70
D
11.30
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
PH+POH=14
p\(^{H}\) = Log [H\(^+\)]
p[H\(^+\) ] = 2.0 X 10\(^{-11}\)moldm\(^{-3}\)
p\(^{H}\) = Log [2.0 X 10\(^{-11}\)]
p\(^{H}\) = 10.70
10.70+ p\(^{OH}\) =14
p\(^{OH}\) = 14 -10.70
= 3.30
Source: Myschool Past Questions Archive (Record #47647)
Chemistry
UTME / JAMB 2018
Kinetics, Energetics and Equilibrium
Solution
2SO\(_2\) \(_{(g) }\)+ O\(_2\) \(_{(g) }\) ↔ 2SO\(_3\)\(_{(g) }\) \DeltaH = -395.7kJmol\(^{-1}\)
In the equation, an increase in temperature will shift the equilibrium position to the
A
left and equilibrium constant decreases
B
left and equilibrium constant increases
C
right and equilibrium constant increases
D
right and equilibrium constant decreases
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
This is typical of what happens with any equilibrium where the forward reaction is exothermic. Increasing the temperature decreases the value of the equilibrium constant. Where the forward reaction is endothermic, increasing the temperature increases the value of the equilibrium constant. Endothermic reaction has a Positive Enthalpy change. Exothermic reaction has a negative enthalpy change.
Source: Myschool Past Questions Archive (Record #47649)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
The conductivity of an acid solution depends on the
A
amount of ions present and their mobilities
B
mobilities of the ions present
C
amount of ions present
D
temperature of the solution
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The conductivity of a solution depends on the number of charge carriers (the concentrations of the ions), the mobility of the charge carriers and their charge. Theoretically, conductivity should increase in direct proportion to concentration.
Source: Myschool Past Questions Archive (Record #47655)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
Which of the following metals cannot replace hydrogen from water or steam?
A
Sodium
B
Magnesium
C
Iron
D
Copper
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Metals above hydrogen in the activity series can displace or replace hydrogen present in water (H\(_2\)O) example of such metals are Ca, K, Na etc. But the metals below hydrogen in the activity series cannot replace hydrogen in the activity series example of such metals are Cu, Hg.
Source: Myschool Past Questions Archive (Record #47656)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
Elements P, Q, R, S have 6, 11, 15, 17 electrons respectively, therefore,
A
P will form an electrovalent bond with R
B
Q will form a covalent bond with S
C
R will form an electrovalent bond with S
D
Q will form an electrovalent bond with S
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
P 6 = 2, 4
Q 11 = 2, 8, 1
R 15 = 2, 8, 5
S 17 = 2, 8, 7
Given the above is the electronic arrangement of PQRS elements, Q will form an electrovalent bond with S. Without argument, D is the answer because electrovalency involves the transfer of electron. Already, Q is 11 with electronic configuration of 2, 8, 1, i.e. having 1 valence electron which is ready to be lost by the atom of element Q, also, S is 17, with electronic configuration of 2, 8, 7. There the 7 valence electron of S attracts that only 1 electron to attain a stable octet structure.
Source: Myschool Past Questions Archive (Record #47657)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
During the electrolysis of copper II sulphate between platinum electrodes, if litmus solution is added to the anode compartment
A
the litmus turns blue but no gas is evolved
B
the litmus turns blue and oxygen is evolved
C
the litmus turns blue and hydrogen is evolved
D
the litmus turns red and oxygen is evolved
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
During the electrolysis of copper using platinum electrode, Cu and H migrate to the cathode while,SO\(_4\) and OH migrate to the anode.CU is then discharged preferentially at the cathode, acquiring two electrons and is deposited as metallic copper, while OH is discharged preferentially at the anode and deposited as gaseous oxygen, then the SO\(_4\) and H still in the solution react, thereby making d solution acidic and then changing the litmus paper red which is the test for acids.
Source: Myschool Past Questions Archive (Record #47658)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
The derivative of benzene that can be used in making explosives is
A
aniline
B
xylene
C
phenol
D
toluene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Yes, Toluene is used in making explosives, based on information from the textbook "New School Chemistry", pg 541.
Phenol is used as a starting material to makes explosive materials such as picric acid. Picric acid is one of the most acidic phenol. Like other strongly nitrated organic compounds, picric acid is an explosive. Toluene, however, is used to produce a stronger explosive material called TriNitroToluene (TNT).
Therefore Toluene is the most appropriate answer for this question but in situations where you don't find Toluene in the options provided, then Phenol makes a viable answer.
Source: Myschool Past Questions Archive (Record #47659)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
Sieving is a technique used to separate mixtures containing solid particles of
A
small sizes
B
large sizes
C
different sizes
D
the same size
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sieving is a simple and convenient technique of separating particles of different sizes.
Source: Myschool Past Questions Archive (Record #47665)
Chemistry
UTME / JAMB 2018
Kinetics, Energetics and Equilibrium
Solution
3H\(_{2(g)}\)+ N\(_{2(g)}\)⇔ 2NH\(_{3(g)}\) ; H= -ve
In the reaction above, lowering of temperature will
A
have no effect on the equilibrium position
B
increase the rate of both the forward and reverse reactions equally
C
favour the forward reaction
D
favour the reverse reaction
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
N\(_{2(g)}\) + 3H\(_{2(g)}\) ⇔ 2NH\(_{3(g)}\) In the Haber process, the forward reaction is exothermic and the backward reaction is endothermic. If the temperature is decreased, the yield from the exothermic direction is increased i.e. the forward reaction is increased.
Source: Myschool Past Questions Archive (Record #47666)
Chemistry
UTME / JAMB 2018
Stoichiometry & Mole Concept
Solution
The situation obtained when a perfect gas expands into a vacuum is
A
ΔH is positive and TΔ S is zero
B
ΔH is positive and T Δ S is negative
C
ΔH is negative and TΔ S is zero
D
ΔH is zero and T Δ S is positive
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The definition of enthalpy change is
\DeltaH = \DeltaU + Pex(\DeltaV)
The enthalpy change is zero because both terms on the right are zero in free expansion of an ideal gas.
There is no external pressure in a free expansion, so P (ex) = 0. And the internal energy change, \DeltaU of free expansion in a closed system is zero since no inter molecular forces have to be overcome. The temperature remains constant and no heat is absorbed or released.
Source: Myschool Past Questions Archive (Record #47667)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
The general formula of alkanones is
A
RCHO
B
R\(_2\)CO
C
RCOOH
D
RCOOR
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Alkanones also known as ketones have the general formula R\(_2\)CO
Source: Myschool Past Questions Archive (Record #47668)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
The alkanoic acid found in human sweat is
A
CH\(_3\)-COOH
B
CH\(_3\)—CH\(_2\)—COOH
C
H-COOH
D
CH\(_3\)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Bacteria of the genus Propionibacterium produce propionic acid (Propanoic Acid) as the end-product of their anaerobic metabolism. This class of bacteria is commonly found in the stomach of ruminants and the sweat glands of humans, and their activity is partially responsible for the odour of both Swiss cheese and sweat.
Source: Myschool Past Questions Archive (Record #47669)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
In electrovalency, the oxidation number of the participating metal is always
A
decreasing
B
increasing
C
constant
D
neutral
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
In electro-valency the oxidation number of the participating metal increases.
Source: Myschool Past Questions Archive (Record #47660)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
The ionic radii of metals are usually
A
greater than their atomic radii
B
unaffected by the charge on the ion
C
the same as their atomic radii
D
less than their atomic radii
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
In a neutral atom, the atomic and ionic radius is the same, but many elements exist as anions or cations. If the atom loses its outermost electron (positively charged or cation), the ionic radius is smaller than the atomic radius because the atom loses an electron energy shell.
Yes ionic radius is only less than atomic radius for a metal.
Source: Myschool Past Questions Archive (Record #47661)