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Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
To what volume must 300cm\(^3\) of 0.60M sodium hydroxide solution be diluted to give a 0.40M solution?
A
450cm\(^3\)
B
300cm\(^3\)
C
200cm\(^3\)
D
150cm\(^3\)
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
From the dilution law
C\(_1\)V\(_1\) = C\(_2\)V\(_2\)
C\(_1\) = Initial Concentration of NaOH = 0.6M
V\(_1\) = Initial Volume of NaOH = 300cm3
C\(_2\) = Final Concentration of NaOH = 0.4M
V\(_2\) = Final Volume of NaOH = ?
V\(_2\) = \(\frac{C_1V_1}{C_2}\)
V\(_2\) = \(\frac{0.6 \times 300}{0.4}\)
V\(_2\) = 450 cm\(^3\)
Correct Computation as it follows the equation specified
Source: Myschool Past Questions Archive (Record #47634)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
Diamond is a bad conductor of electricity because its bonding electrons are used in
A
crystal lattice formation
B
covalent bond formation
C
metallic bond formation
D
coordinate bond formation
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Diamond is a covalent macromolecule, and typical of a covalent substance is an insulator. All valence electrons are localized in well-defined covalent bonds and hence are not free to move through the structure
Source: Myschool Past Questions Archive (Record #47635)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
The reaction between an organic acid and an alcohol in the presence of an acid catalyst is known as;
A
saponification
B
dehydration
C
esterification
D
hydrolysis
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Esterification is a chemical reaction that forms at least one ester (= a type of compound produced by reaction between acids and alcohols). Esters are produced when acids are heated with alcohols in a process called esterification. An ester can be made by an esterification reaction of a carboxylic acid and an alcohol.
Source: Myschool Past Questions Archive (Record #47636)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
The constituent common to duralumin and alnico is
A
Co
B
Mn
C
Al
D
Mg
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Constituents of duralumin are: Al, Cu, Mg, Mn.
Constituents of Alnico are: Al, Ni and Co
In 1909, the alloy of duralumin was discovered by Alfred Wilon consisting of 94% Al, 4% Cu, 1% Mg and 1% Mn(Manganese)
Alnico is an acronym referring to a family of iron alloys which in addition to iron are composed primarily of Al, Ni and Co.
Source: Myschool Past Questions Archive (Record #47637)
Chemistry
UTME / JAMB 2018
Kinetics, Energetics and Equilibrium
Solution
The solubility of the solids that dissolves in a given solvent with the liberation of heat will
A
increase with an increase in temperature
B
decrease with an increase in temperature
C
decrease with a decrease in temperature
D
not be affected by changes in temperature
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
increasing temperature in exothermic reaction favors the left/reactant side and decreasing temperature will favor the right/product side.
Source: Myschool Past Questions Archive (Record #47638)
Chemistry
UTME / JAMB 2018
Stoichiometry & Mole Concept
Solution
What mass of Cu would be produced by the cathodic reduction of Cu\(^{2+}\) when 1.60A of current passes through a solution of CuSO\(_4\) for 1 hour. (F=96500Cmol\(^{-1}\) , Cu=64)
A
7.64g
B
3.82g
C
1.91g
D
0.96g
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
M = \(\frac{MmIT}{96500n}\)
Where
M=mass
Mm = Molar mass = 64g/mol
I = current = 1.6A
T= Time =1h r=3600s
N= No of Charge = +2
M = \(\frac{64x \times 1.6 \times 3600}{96500 \times 2}\)
M=1.91g
Source: Myschool Past Questions Archive (Record #47639)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
Calculate the pH of 0.05 moldm\(^{-3}\) H\(_2\)SO\(_4\)
A
1.30
B
1.12
C
1.00
D
0.30
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Recall from pH formula pH = -Log [H+]
H2SO4 → 2H+ + SO42-
2H+ → 2 X0.05 = 0.1
pH= -Log [0.1] = 1
Source: Myschool Past Questions Archive (Record #47640)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
The choice of method for extracting a metal from its ores depends on the
A
strength of the core
B
position of the metal in the electrochemical series
C
source of the core
D
position of the metal in the periodic table
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The method used to extract a metal from its ore depends upon the stability of its compound in the ore, which in turn depends upon the reactivity of the metal:
• The oxides of very reactive metals, such as aluminum, form stable oxides and other compounds. A lot of energy is needed to reduce them to extract the metal.
• The oxides of lesser reactive metals, such as iron, form less stable oxides and other compounds. Relatively little energy is needed to reduce them to extract the metal.
So, the method of extraction of a metal from its ore depends on the metal's position in the reactivity series.
Source: Myschool Past Questions Archive (Record #47641)
Chemistry
UTME / JAMB 2018
Atomic Structure and Periodic Table
Solution
Which of the following produces relatively few ions in solution?
A
NaOH
B
Ca(OH)\(_2\)
C
KOH
D
AI(OH)\(_3\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Aluminium hydroxide is not soluble in water because it is polymeric and it also has high lattice energy and therefore it is hard to break bonds in this compound. So, water cannot dissolve such types of compounds.
Al(OH)\(_3\) is not soluble in water
Source: Myschool Past Questions Archive (Record #47643)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
The end products of burning a candle in the atmosphere are water and
A
carbon (II) oxide
B
sulphur (IV) oxide
C
carbon (IV) oxide
D
sulphur (VI) oxide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When we ignite a candle, the hydrocarbon reacts with oxygen (in excess) to produce carbon dioxide and water. The burning sets an air current which gives dome shape to candle flame and it helps to get complete combustion at the bottom and the outer surface of the flame.
CO\(_2\) is produced
Source: Myschool Past Questions Archive (Record #47650)
Chemistry
UTME / JAMB 2018
Stoichiometry & Mole Concept
Solution
The collision theory explains reaction rates in terms of
A
size of the product
B
frequency of collision of the reactants
C
size of reactant
D
frequency of collision of the products
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Collision theory is the theory used to predict the rates of chemical reactions, particularly for gases. The collision theory is based on the assumption that for a reaction to occur it is necessary for the reacting species (atoms or molecules) to come together or collide with one another.
Source: Myschool Past Questions Archive (Record #47651)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
The presence of ammonia gas in a desiccator can exclusively be removed by
A
phosphorus (V) oxide
B
fused calcium chloride
C
calcium oxide
D
concentrated tetraoxosulphate (VI) acid
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Ammonia gas can be removed from a dessicator by adding a conc. H2SO4 so as to neutralize it since ammonia gas is basic.
Source: Myschool Past Questions Archive (Record #47652)
Chemistry
UTME / JAMB 2018
Acids, Bases, and Salts
Solution
Aluminium does not react with either dilute or concentrated trioxonitrate (V) acid because
A
it is insoluble in either dilute or concentrated trioxonitrate (V) acid
B
it is lower than hydrogen in the electrochemical series
C
the reaction with trioxonitrate (V) acid has a light activation energy
D
an insoluble oxide is formed on its surface which renders it passive
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Aluminium doesn’t react with either dilute or concentrated trioxonitrate (V) acid because an insoluble oxide is formed on its surface which renders it passive. It will depend on the concentration of the nitric acid used…. Although aluminium reacts with dilute nitric acid to produce aluminium nitrate and hydrogen gas, concentrated (>60%) nitric acid is such a powerful oxidising agent that it instantly causes a thin layer of aluminium oxide to coat the surface of the aluminium
Source: Myschool Past Questions Archive (Record #47653)
Chemistry
UTME / JAMB 2018
Electrochemistry and Redox
Diagram
Solution
The figure above shows the electrolysis of molten sodium chloride. Z is the
Attached Figure / Diagram
A
anode where the Cl\(^-\) ions are oxidized
B
cathode where the Cl\(^-\) ions are reduced
C
anode where the Na\(^+\) ions are reduced
D
cathode where the Na\(^+\) ions are oxidized
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
During the electrolysis of brine, the chlorine ions are discharged at the anode and are oxidized. While at the cathode Hydrogen ion is discharged.
Source: Myschool Past Questions Archive (Record #47644)
Chemistry
UTME / JAMB 2018
Matter & Separation Techniques
Solution
The knowledge of half-life can be used to
A
Create an element
B
Detect an element
C
to combine elements
D
Irradiate an element
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Half-life, in radioactivity, the interval of time required for one-half of the atomic nuclei of a radioactive sample to decay (change spontaneously into other nuclear species by emitting particles and energy), or, equivalently, the time interval required for the number of disintegrations per second of a radioactive material to decrease by one-half
Source: Myschool Past Questions Archive (Record #47645)