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Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
Nickel is used in the hydrogenation of alkenes because it
A
Increases the yield of the product
B
lowers the activation energy of the reaction
C
makes the reaction more exothermic
D
prevents a reverse reaction from occuring
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Nickel acts as a catalyst in the hydrogenation of alkenes. Catalysts function by providing an alternative reaction pathway with a lower activation energy. By lowering the energy barrier, a larger fraction of reactant molecules have sufficient energy to react at a given temperature, which significantly increases the reaction rate. In this specific reaction, nickel adsorbs hydrogen onto its surface, weakening the H-H bonds and facilitating their addition to the alkene.
Source: Myschool Past Questions Archive (Record #76997)
Chemistry
WAEC / WASSCE 2025
Electrochemistry and Redox
Solution
Aluminum is extracted by
A
electrolysis of the purified ore
B
froth floatation of the smelted ore
C
reduction of the ore with coke in a furnace
D
roasting the ore in excess supply of air
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Aluminum is a highly reactive metal, placing it high on the reactivity series. Because it forms very stable oxides, it cannot be extracted from its ore (bauxite) using standard chemical reducing agents like carbon or coke. Instead, the industrial extraction process is by electrolysis of the purified ore.
Source: Myschool Past Questions Archive (Record #76998)
Chemistry
WAEC / WASSCE 2025
Matter & Separation Techniques
Solution
Which of the following gases is used in fire extinguishers?
A
Carbon(IV)oxide
B
Nitrogen(IV)oxide
C
Carbon(II)oxide
D
Sulphur(IV)oxide
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Carbon(IV)oxide, commonly known as carbon dioxide (CO\(_2\)), is the primary gas used in fire extinguishers because it is non-combustible and denser than air. When released, it displaces the oxygen surrounding the fire, effectively "suffocating" the flames by removing one of the three essential components (fuel, heat, and oxygen) needed for combustion.
Source: Myschool Past Questions Archive (Record #77016)
Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
Both Na\(^+\) and K\(^+\) have
A
tendency to give electrons
B
positive reduction potential
C
tendency to accept electrons
D
negative oxidation potential
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sodium (Na\(^+\)) and potassium (K\(^+\)) are cations, meaning they have already lost an electron to achieve a stable noble gas configuration. Because they are positively charged, they have a tendency to accept electrons to return to their neutral elemental state (Na or K), a process called reduction.
Conversely, option A, which is the tendency to give electrons describes the neutral atoms (Na and K) which are strong reducing agents that readily lose their single valence electron. Once they become Na\(^+\) and K\(^+\) ions, they have a stable octet and do not tend to lose further electrons.
The correct answer is option C.
Source: Myschool Past Questions Archive (Record #77017)
Chemistry
WAEC / WASSCE 2025
Matter & Separation Techniques
Solution
If a gas occupies a volume of 400cm\(^3\) at a temperature of 400K and a pressure of 1 atm, at what temperature and pressure would its volume be 200cm\(^3\)?
A
800 K and 1 atm
B
800 k and 0.5 atm
C
200 k and 1 atm
D
200 k and 0.5 atm
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
To determine the correct conditions, we use the Combined Gas Law, which relates the pressure, volume, and temperature of a fixed amount of gas:
\(\frac{P\(_1\)V\(_1\)}{T\(_1\)}\) = \(\frac{P\(_2\)V\(_2\)}{T\(_2\)}\)
Given:
V\(_1\) = 400 cm\(^3\) , T\(_1\) = 400 K , P\(_1\) = 1 atm
V\(_2\) = 200 cm\(^3\) , T\(_2\) = ? , P\(_2\) = ?
We need to find which pair of pressure and temperature satisfies the equality
P\(_1\)V\(_1\)/T\(_1\) = P\(_2\)V\(_2\)/T\(_2\)
First, calculate the initial constant:
\(\frac{1 atm . 400cm{^3}}{400K}\) = 1
Now, test Option C:
P\(_2\) = 1 atm
V\(_2\) = 200cm\(^3\)
T\(_2\) = 200 K
\(\frac{1 atm . 200cm{^3}}{200K}\) = 1
Options A, B and D will not give you 1.
Source: Myschool Past Questions Archive (Record #77018)
Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
The nucleus of a hydrogen atom consists of
A
one proton only
B
one proton and one neutron
C
one neutron only
D
one electron only
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The nucleus of an ordinary hydrogen atom (specifically the most abundant isotope, protium) consists of a single proton.
Atomic Number: Hydrogen has an atomic number of 1, meaning it contains exactly one proton.
Source: Myschool Past Questions Archive (Record #77020)
Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
If acidified K\(_2\)Cr\(_2\)O\(_7\) acts as an oxidizing agent, the colour changes from
A
orange to red
B
yellow to green
C
orange to green
D
yellow to red
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Acidified potassium dichromate (K\(_2\)Cr\(_2\)O\(_7\)) is a strong oxidizing agent that undergoes a distinct colour change during redox reactions. In an acidic medium, the chromium is present in the dichromate ion (Cr\(_2\)O\(_7\)\(^{2-}\)), where it has an oxidation state of +6. This ion gives the solution its characteristic orange colour.
When it acts as an oxidizing agent, it accepts electrons and is reduced to chromium(III) ions (Cr\(^{3+}\)), where the oxidation state is +3. The formation of Cr\(^{3+}\) ions (often as chromium(III) sulfate in sulphuric acid solutions) turns the solution green.
Source: Myschool Past Questions Archive (Record #77021)
Chemistry
WAEC / WASSCE 2025
Matter & Separation Techniques
Solution
Which of the following elements is a metalloid?
A
Aluminium
B
Selenium
C
Phosphorus
D
Sodium
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
While standard chemical definitions usually limit metalloids to a list of six elements (Boron, Silicon, Germanium, Arsenic, Antimony, and Tellurium), Selenium is frequently classified as a metalloid in various educational contexts and standardized tests because it exhibits intermediate properties between metals and nonmetals. Though more strictly defined as a nonmetal in some academic circles, it is the only viable answer among the choices provided that displays "metalloid-like" or semiconducting behavior.
Source: Myschool Past Questions Archive (Record #77022)
Chemistry
WAEC / WASSCE 2025
Matter & Separation Techniques
Solution
Iodine could be separated from the mixture of iodine and Calcium chloride by
A
Evaporation
B
Sublimation
C
fractional distillation
D
fractional crystallization
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Iodine can be separated from calcium chloride using sublimation because of the distinct physical properties of the two substances:
1. Iodine is a sublimable solid, meaning it transitions directly from a solid state to a gaseous state upon heating without passing through a liquid phase.
2. Calcium chloride is a non-sublimable ionic salt with a very high melting point, so it remains in the solid state while the iodine vapourizes.
Source: Myschool Past Questions Archive (Record #77024)
Chemistry
WAEC / WASSCE 2025
Matter & Separation Techniques
Solution
Sodium chloride is used in the following processes except
A
treatment of water
B
manufacturing of chloride
C
preservation of food
D
separation of soap glycerol
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Sodium chloride (common salt) is a versatile chemical used in various industrial and domestic processes. While it has many applications, it is not typically used for the primary treatment of water (such as purification or filtration of polluted water).
Source: Myschool Past Questions Archive (Record #77025)
Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
Which of the following bonds is not an intermolecular force?
A
Hydrogen bond
B
Van der waal's
C
dipole-dipole
D
metallic bond
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
A metallic bond is an intramolecular (chemical) bond rather than an intermolecular force. It involves a lattice of metal cations surrounded by a "sea" of delocalized valence electrons. Because this bond exists within a substance to hold its atoms together rather than between discrete molecules, it does not qualify as an intermolecular force.
Source: Myschool Past Questions Archive (Record #77026)
Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
All the following compounds are ionic except
A
AgCl
B
KNO\(_3\)
C
NO\(_2\)
D
(NH\(_4\))\(_2\)CO\(_3\)
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
NO\(_2\) (nitrogen dioxide) is a covalent compound, not an ionic one. It is formed by the sharing of electrons between two non-metals: nitrogen and oxygen. Unlike ionic compounds, which typically involve the transfer of electrons from a metal to a non-metal, NO\(_2\) consists solely of non-metallic elements that form molecular bonds.
Source: Myschool Past Questions Archive (Record #77028)
Chemistry
WAEC / WASSCE 2025
Atomic Structure and Periodic Table
Solution
The metal carbonate that would not decompose when heated strongly is
A
Al\(_2\)CO\(_3\)
B
CaCO\(_3\)
C
MgCO\(_3\)
D
Na\(_2\)CO\(_3\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Sodium carbonate (Na\(_2\)CO\(_3\)) is an alkali metal carbonate that is extremely stable and does not decompose when heated strongly, even at Bunsen burner temperatures. This stability is due to the large size and low charge density of the sodium cation (Na\(^+\)), which has low polarizing power and cannot easily distort the carbonate ion (CO\(_3\)\(^{2-}\)) to break its carbon-oxygen bonds. Most group 1 carbonates (except lithium carbonate) exhibit this high thermal stability.
Source: Myschool Past Questions Archive (Record #77029)
Chemistry
WAEC / WASSCE 2025
Acids, Bases, and Salts
Solution
In the use of a universal indicator, red colour is an indication that the substance is a
A
concentrated acid
B
concentrated alkali
C
dilute acid
D
dilute base
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
A universal indicator changes colour to represent the pH level of a substance. For instance, a red colour indicates a very low pH (typically 0 to 3), which corresponds to a strong or concentrated acid; for pH 0: Specifically produces a strong red or dark red colour, representing the highest acidity and for indicator Spectrum: the colour moves from red (strong acid) to orange/yellow (weak/dilute acid), green (neutral), and finally blue/purple (bases).
Source: Myschool Past Questions Archive (Record #77030)
Chemistry
WAEC / WASSCE 2025
Acids, Bases, and Salts
Solution
Which of the following oxides would form two different types of acids when dissolved in water?
A
CO\(_2\)
B
NO\(_2\)
C
SO\(_2\)
D
SO\(_3\)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Nitrogen dioxide (NO\(_2\)) is unique because it undergoes a disproportionation reaction when dissolved in water. In this reaction, the nitrogen atom (which has an oxidation state of +4 in NO\(_2\) ) is both oxidized and reduced simultaneously, resulting in the formation of two distinct acids;
2NO\(_2\) + H\(_2\)O → HNO\(_2\) + HNO\(_3\)
Source: Myschool Past Questions Archive (Record #77031)