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Chemistry
UTME / JAMB 2022
Reactions Rates and Chemical Equilibria
Solution
The reactions below represent neutralization reaction, in which of them is the value of ΔH highest?
A
CH\(_3\)CH\(_2\)COOH + KOH → CH\(_3\)CH\(_2\)COOK + H\(_2\)O
B
NH\(_4\)OH + HCL → NH\(_4\) + H\(_2\)O
C
NaOH + HCL → NaCL + H\(_2\)O
D
CH\(_3\)COOH + NaOH → CH\(_3\)COONa + H\(_2\)O
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The enthalpy change of neutralisation involving weak acids are smaller in magnitude compared to that between strong acids and strong bases. This is because weak acids/bases are partially dissociated, which means not all hydrogen ions are free to react with hydroxide ions.
For strong acids and bases, the enthalpy of neutralisation values are always closely similar with the values -57 and -58 KJ/mol. We know that strong acids completely ionize in water. In case of weak acids, only partial dissociation of its ions occurs.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64973)
Chemistry
UTME / JAMB 2022
Reactions Rates and Chemical Equilibria
Solution
When heat is absorbed during a chemical reaction, the reaction is said to be
A
thermodynamic
B
exothermic
C
isothermal
D
endothermic
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
An endothermic reaction is any chemical reaction that absorbs heat from its environment.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64988)
Chemistry
UTME / JAMB 2022
Hydrogen Hydrides
Solution
In which of the following will hydrogen form ionic compound?
A
HCL
B
NaH
C
NH\(_3\)
D
CH\(_4\)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
NaH is a saline (salt-like) hydride, composed of Na+ and H− ions.
NaH (sodium hydride) is considered an ionic compound because it is composed of a metal (sodium) and a non-metal (hydrogen), where sodium readily loses an electron to form a positive ion (Na+) and hydrogen gains an electron to form a negative ion (H-) creating an ionic bond between them.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64962)
Chemistry
UTME / JAMB 2022
Oxygen Oxides Ozone
Solution
The following non-metal form acidic oxides with oxygen except?
A
phosphorus
B
sulphur
C
carbon
D
chlorine
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The oxides which neither react with acids nor react with bases are known as neutral oxides.
Carbon monoxide neither reacts with acids nor reacts with bases.
Thus, carbon monoxide is a neutral oxide, produced when combustion reactions are not fully completed, either through lack of oxygen or due to low mixing
Source: WAEC / JAMB / NECO Classroom Archive (Record #64904)
Chemistry
UTME / JAMB 2022
Carbon Carbon Compounds
Solution
A colored gas that is known to be poisonous and can readily damage the mucous lining of the lungs is?
A
hydrogen sulphide
B
carbon(ii)oxide
C
chlorine
D
sulphur(iv)oxide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Chlorine is a yellow-green gas at room temperature. Chlorine has a pungent, irritating odor similar to bleach that is detectable at low concentrations.
Exposure to low concentrations of chlorine (1 to 10 ppm) may cause eye and nasal irritation, sore throat, and coughing. Inhalation of higher concentrations of chlorine gas (>15 ppm) can rapidly lead to respiratory distress with airway constriction and accumulation of fluid in the lungs (pulmonary edema).
Source: WAEC / JAMB / NECO Classroom Archive (Record #64944)
Chemistry
UTME / JAMB 2022
Carbon Carbon Compounds
Solution
The pollutant usually presents in a city which generates its electricity from coal?
A
fog
B
carbon(ii)oxide
C
smog
D
sulphur(iv)oxide
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
In the majority of power plants, sulfur appears due to coal burning which is used to generate electricity.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64978)
Chemistry
UTME / JAMB 2022
Carbon Carbon Compounds
Solution
How many bonding pair are present in carbon(iv)oxide?
A
4
B
3
C
2
D
1
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
There are 4 bond pairs in CO₂ and no lone pairs are there.
Source: WAEC / JAMB / NECO Classroom Archive (Record #65005)
Chemistry
UTME / JAMB 2022
Sulphur Sulphur Compounds
Solution
SO\(_2\) + O\(_2\) → 2SO\(_3\)
In the reaction above, the most suitable catalyst is?
A
chromium(vi)oxide
B
iron(iii)oxide
C
copper(i)oxide
D
vanadium(v)oxide
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
During the Contact Process for manufacturing sulfuric acid, sulfur dioxide has to be converted into sulfur trioxide, which is done by passing sulfur dioxide and oxygen over a solid vanadium(V) oxide catalyst.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64902)
Chemistry
UTME / JAMB 2022
Sulphur Sulphur Compounds
Solution
The sulphide that is commonly used in coating electric fluorescent tubes is?
A
iron(ii)Sulphide
B
tin(ii)sulphide
C
Zinc Sulphide
D
lead(iv) Sulphide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
ZnS (Zinc Sulfide) screen was used because it emits a flash of light when struck by an alpha particle.
This is a phenomenon called Radio luminescence in which a flash of light is observed on the screen when acted upon by a radioactive substance.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64907)
Chemistry
UTME / JAMB 2022
Transition Metals and Their Compounds
Solution
Using the metal activity series, the metal that can liberate hydrogen gas from steam is?
A
iron
B
copper
C
tin
D
lead
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Iron reacts with steam to form iron oxide and hydrogen gas.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64926)
Chemistry
UTME / JAMB 2022
Transition Metals and Their Compounds
Solution
Zn + 2HCL → ZnCl\(_2\) + H\(_2\)
What happens to zinc in the above reaction?
A
oxidized
B
a reactant
C
reduced
D
a metal
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
-Zn is a reducing agent, HCl is an oxidizing agent.
-the zinc is oxidized
Source: WAEC / JAMB / NECO Classroom Archive (Record #64938)
Chemistry
UTME / JAMB 2022
Transition Metals and Their Compounds
Solution
Wrought iron is obtained by heating cast iron in a furnace with?
A
magnetite
B
haematite
C
carbon(ii)oxide
D
calcium trioxosilicate(iv)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Cast iron + haematite = wrought iron
Source: WAEC / JAMB / NECO Classroom Archive (Record #65002)
Chemistry
UTME / JAMB 2022
Transition Metals and Their Compounds
Solution
In the extraction of iron, hot air is introduced into the blast furnace through?
A
valves
B
open-hearths
C
arcs
D
tuyeres
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Pre-heated air at about 600ºC is blown into the furnaces from the bottom through the tuyeres.
Source: WAEC / JAMB / NECO Classroom Archive (Record #65003)
Chemistry
UTME / JAMB 2022
Organic Chemistry
Solution
An organic compound which liberate carbon(iv)oxide from trioxocarbonate(iv) solution is likely to be?
A
C\(_2\)H\(_5\)OH
B
C\(_3\)H\(_4\)
C
C\(_6\)H\(_6\)
D
CH\(_3\)COOH
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Carboxylic acids and enols react with sodium bicarbonate to liberate carbon dioxide.
E,g CH\(_3\)COOH
Source: WAEC / JAMB / NECO Classroom Archive (Record #64909)
Chemistry
UTME / JAMB 2022
Organic Chemistry
Solution
The dehydration of CH\(_3\)CH\(_2\)CH\(_2\)CH\(_2\)OH will give?
A
HC≡CCH\(_2\)CH\(_3\)
B
CH\(_2\)≡CH\(_2\)CH\(_3\)
C
CH\(_3\)C≡CCH\(_3\)
D
CH\(_3\)CH=CHCH\(_3\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
An alkene is produced when dehydration of alcohol is performed. Alcohol dehydration is an example of an elimination reaction which is quite the opposite of substitution reaction and addition reaction.
The products of the dehydration of a primary alkanol are water and an alk-1-ene (1-alkene).
Butanol gives a mixture of but-1-ene and but-2-ene when dehydrated.
Source: WAEC / JAMB / NECO Classroom Archive (Record #64985)