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Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The conversion of open chain alkanes into cycloalkanes and aromatic compounds is called
A
cracking
B
reforming
C
isomerization
D
polymerization
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The correct answer is B. Reforming.
Reforming is a process in petroleum refining where low-octane, straight-chain alkanes are converted into higher-octane, branched-chain alkanes, cycloalkanes, and aromatic compounds. This process involves the use of catalysts and high temperatures to break and reform the molecular bonds. Reforming is an important process in the production of high-octane gasoline and other petroleum products.
Source: Myschool Past Questions Archive (Record #3981)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following alkanes has the highest boiling point?
A
Pentane
B
Ethane
C
Propane
D
Methane
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The correct answer is A. Pentane.
Boiling point increases with molecular weight and size in alkanes, due to increased London dispersion forces (also known as van der Waals forces).The order of boiling points for the given options is:
Methane (boiling point: -161.5^\circC) < Ethane (boiling point: -88.5^\circC) < Propane (boiling point: -42.2^\circC) < Pentane (boiling point: 36.1^\circC). Therefore, Pentane has the highest boiling point among the given options.
Source: Myschool Past Questions Archive (Record #3982)
Chemistry
UTME / JAMB 2007
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Certain useful waxes are composed mainly of
A
amino acids
B
glycerols
C
alkanols
D
alkanoates
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Waxes are esters of higher fatty acids with long chain of monohydric alcohols. It is a simple lipid that is an ester of a long-chain alcohol and a fatty acid. The alcohol may contain around 12-32 carbon atoms. Waxes are found in nature as coatings on leaves and stems. The wax prevents the plant from losing excessive amounts of water.
Source: Myschool Past Questions Archive (Record #3983)
Chemistry
UTME / JAMB 2007
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The IUPAC nomenclature of compound CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) is
A
propyl ethanoate
B
ethyl butanoate
C
ethyl propanoate
D
methyl butanoate
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
While trying to name the compound CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) , we must realize that this ester or alkanoate was derived from two reactants; alkanol and alkanoic acid. Therefore, we'll try to split the compound into two for easier naming.
CH\(_3\)CH\(_2\)COO - CH\(_2\)CH\(_3\).
Secondly, start the naming from the right hand side i.e CH\(_2\)CH\(_3\), which is ethyl
Thirdly, name the compound from the left hand side i.e CH\(_3\)CH\(_2\)COO,which is propanoate (because there are 3 carbon atoms and the functional group RCOO-).
Finally, join the two names together i.e ethyl propanoate.
Source: Myschool Past Questions Archive (Record #3985)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
When temporary hard water is boiled for sometime in a kettle, the inner surface of the kettle becomes coated with a deposit of
A
calcium tetraoxosulphate(VI)
B
calcium trioxocarbonate (IV)
C
calcium hydrogentrioxocarbonate (IV)
D
aluminium trioxocarbonate (IV)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When temporary hard water is boiled for some time in a kettle, the inner surface of the kettle becomes coated with a deposit of Calcium trioxocarbonate(IV), CaCO\(_3\), which originated from Calcium hydrogen trioxocarbonate(IV), Ca(HCO\(_3\))\(_2\).
Ca(HCO\(_3\))\(_2\) → CaCO\(_3\) + H\(_2\)O + CO\(_2\)
Source: Myschool Past Questions Archive (Record #3987)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
A supersaturated solution is said to contain
A
more solute than it can dissolve at that temperature in the presence of undissolved solute
B
as much solute as it can dissolve at that temperature in the presence of undissolved solute
C
as much solute as it can dissolve at that temperature
D
more solute than it can dissolve at that temperature
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The correct answer is D. More solute than it can dissolve at that temperature.
A supersaturated solution is a solution that contains more dissolved solute than it can hold at equilibrium at a given temperature. This means that the solution is unstable and can precipitate out the excess solute at any moment.
In contrast, a saturated solution (option C) contains as much dissolved solute as it can hold at equilibrium at a given temperature, while an unsaturated solution contains less dissolved solute than it can hold.
Source: Myschool Past Questions Archive (Record #3991)
Chemistry
UTME / JAMB 2007
Periodic Table & Periodicity
Solution
The presence of nitrogen in air is to slow down
A
respiration and combustion
B
combustion and corrosion
C
corrosion and respiration
D
respiration and transpiration
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Nitrogen in the air slows down the burning process of materials, essentially acting as a fire suppressant by diluting the oxygen concentration needed for combustion to occur rapidly; making up the majority of air, it prevents flames from spreading too quickly.
Also,nitrogen in the air does slow down corrosion because it is an inert gas, meaning it doesn't readily react with metals, while the primary contributor to corrosion, oxygen, is displaced by the presence of nitrogen in the atmosphere; essentially, by taking up space, nitrogen limits the amount of oxygen that can come into contact with a metal surface, thus slowing down the corrosion process.
Conversely, nitrogen in the air does not slow down respiration because it is not used in respiration, just as the nitrogen in the soil can affect transpiration rates, but the relationship depends on soil moisture and other factors.
Source: Myschool Past Questions Archive (Record #3994)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
A good drying agent should be
A
deliquescent
B
effervescent
C
hygroscopic
D
efflorescent
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A good drying agent should be hygroscopic because this property means it readily absorbs moisture from the surrounding environment, making it effective at drying substances; while efflorescence is the opposite, where a substance releases water, making it unsuitable for drying purposes. Examples of hygroscopic drying agents: Silica gel, calcium oxide, concentrated sulphuric acid.
Source: Myschool Past Questions Archive (Record #3997)
Chemistry
UTME / JAMB 2007
Air & Environmental Chemistry
Solution
Smog usually occurs over cities which
A
burn a lot of fossil fuels
B
have very few plants
C
are surrounded by water
D
are overpopulated
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The correct answer is A. Burn a lot of fossil fuels.
Smog, a type of air pollution, is often associated with urban areas that burn large amounts of fossil fuels, such as coal, oil, and gasoline. These fuels release pollutants like nitrogen oxides, sulphur dioxide, and particulate matter into the atmosphere, which can react with sunlight and other chemicals to form ground-level ozone and smog.
While options B, C, and D may be related to urban areas, they are not the primary cause of smog. Burning fossil fuels is the main culprit!
Source: Myschool Past Questions Archive (Record #4000)
Chemistry
UTME / JAMB 2007
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
What weight of NaCl is needed to make 2.0 dm3 of a 1.5M solution?
[Na = 23, Cl = 35.5]
A
116 g
B
175 g
C
87 g
D
58 g
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Molar mass of Nacl = 23 + 35.5 = 58.5 g/mol
Number of moles of Nacl = conc. in mol/dm3
x vol. in dm3
= 1.5 * 2.0 = 3.0 moles
1 mole of NaCl has a weight of 58.5 * 3
= 175.5g
Source: Myschool Past Questions Archive (Record #4002)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Use the diagram above to answer the question below:
The alternative raw material labelled M is
A
carbon
B
steam
C
oxygen
D
natural gas
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The alternative raw material labelled M is steam
Source: Official Exam / Past Question Archive
Chemistry
WAEC / WASSCE 2007
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
When sodium atom form the ion Na+,
A
it gains one proton
B
it achieves a noble gas configuration
C
its atomic number increases
D
it gains one electron
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When the sodium atom forms an ion, Na+ it loses one electron, i.e. it achieves a noble gas electronic configuration. It will lose one of its 11 electrons to have 10 electrons like neon.
\(Na - e^- → Na^+\)
Na → \(Na^+ + e^-\)
Source: Myschool Past Questions Archive (Record #37132)
Chemistry
WAEC / WASSCE 2007
Chemical Bonding & Intermolecular Forces
Which of the following statements about rare gases are correct?
A
Their outermost shells are fully filled
B
They are generally unreactive
C
Their outermost shells are partially filled
D
They have lone pair of
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option A.
Source: Myschool Past Questions Archive (Record #37133)
Chemistry
WAEC / WASSCE 2007
Stoichiometry, Mole Concept & Volumetric Analysis
Which of the following properties is characteristic of the halogens?
A
Ability to accept electrons readily
B
Ability to donate electrons readily
C
Ability to from basic oxides
D
Formation of coloured compounds
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option A.
Source: Myschool Past Questions Archive (Record #37134)
Chemistry
WAEC / WASSCE 2007
Periodic Table & Periodicity
In which of the following atoms is the ionic radius larger than the atomic radius? [11 Na, 12Mg,13AI,17CI]
A
Aluminium
B
Chlorine
C
Magnesium
D
Sodium
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option B.
Source: Myschool Past Questions Archive (Record #37135)