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Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
Biuret test is a chemical test used for detecting the presence of
A
carbohydrates
B
proteins
C
amines
D
alkanoates
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The biuret test uses copper sulphate in a basic solution to create a purple complex with substances that contain two or more peptide bonds. If protein is present, the biuret reagent will turn purple, and if no protein is present, it will remain blue.
The biuret test is a chemical test that detects the presence of proteins in a sample.
Source: Myschool Past Questions Archive (Record #70235)
Chemistry
UTME / JAMB 2024
Matter & Separation Techniques
Solution
A gas when mixed with oxygen, it produces a very hot and early controllable flame. What is the name of the flame and where is it used?
A
Acetylene flame; miners' lamb
B
Oxy-ethylene ; hunters' torch
C
Oxy-ethylene flame; miners' lamb
D
Oxy-ethylene flame ; cutting and welding metals
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
When Oxygen reacts with acetylene, an oxy-acetylene or oxy-ethylene flame is obtained. This flame produces a very high temperature flame which is able to weld or join two or more metals together.
The combustion of acetylene and oxygen produces a flame that can reach temperatures over 3,000^\circC, making it hot enough to melt steel. Oxy-acetylene equipment can be used for welding, cutting, brazing, heating, and more.
Source: Myschool Past Questions Archive (Record #70236)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
The number of geometrical isomers of butene are
A
2
B
3
C
5
D
4
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Geometric isomers are two or more compounds with the same number and types of atoms, and bonds, but which have different geometries for the atoms.
Geometric isomers have the same connectivity but different geometries. They occur when substituents are locked in position next to or opposite each other.
Butene has four isomers:
But-1-ene: CH\(_3\)CH\(_2\)CH=CH\(_2\)
But-2-ene: CH\(_3\)CH=CHCH\(_3\)
Cis but-2-ene: A geometrical isomer
Trans but-2-ene: A geometrical isomer.
Out of the four isomers, there are only two geometric isomers which are cis but-2-ene and trans but-2-ene. Consequently, butene has two geometrical isomers; which are the cis but-2-ene and the trans but-2-ene.
Source: Myschool Past Questions Archive (Record #70237)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
How many isomers has the organic compound represented by the formula C\(_3\)H\(_8\)O ?
A
2
B
3
C
4
D
5
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The molecular formula C3H8O has three stable isomers:
1-propanol: A primary alcohol with the structure CH3−CH2−CH2−OH
2-propanol: A secondary alcohol with the structure CH3−CH(OH)−CH3
Ethyl methyl ether: An ether with the structure CH3−CH2−O−CH3
Two of the isomers are alcohols, while the third is an ether. Ethers cannot be oxidized, so they do not react with potassium permanganate (KMnO4). However, alcohols can oxidize, and when they react with KMnO4, they produce carboxylic acid.
Source: Myschool Past Questions Archive (Record #70238)
Chemistry
UTME / JAMB 2024
Matter & Separation Techniques
Solution
When a few drops of Millon reagents is added to egg-white solution in a test tube, the white precipitate changes to
A
orange
B
brick red
C
reddish brown
D
blue
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When a few drops of Millon's reagent is added to an egg-white solution in a test tube and the solution is boiled, the white precipitate turns brick red. This indicates the presence of proteins.
Source: Myschool Past Questions Archive (Record #70239)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
If the solubility of KNO\(_3\) at 30\(^0\)C is 3.10 mol/dm\(^3\) a solution containing 303g/dm\(^3\) KNO\(_3\) is likely to be
A
saturated
B
unsaturated
C
supersaturated
D
at saturation point
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
To determine whether the solution is saturated or unsaturated, we need to compare the actual concentration of the solution (g/dm³) with the solubility of KNO₃ at the same temperature (mol/dm³).
First, let’s convert the given mass concentration to mol/dm³ using the molar mass of KNO₃.
Molar mass of KNO₃ = (39 g/mol) + (14 g/mol) + (3 x 16 g/mol) = 101g/mol
Molar Concentration (mol/dm³)\} = \(\frac{mass concentration}{Molar mass}\)
= \(\frac{303}{101}\)
= 3.00moldm\(^3\)
Comparing, the concentration (3.00 mol/dm³) with the solubility of KNO₃ at 30^\circC (3.10 mol/dm³).
If the concentration is less than the solubility, the solution is unsaturated because more solute can dissolve. If the concentration is equal to the solubility, the solution is saturated because no more solute can dissolve. If the concentration is greater than the solubility, the solution is supersaturated, but this case is not relevant to our comparison.
In this case, the concentration (3.00mol/dm³) is less than the solubility (3.10 mol/dm³). Therefore, the solution is unsaturated at 30^\circC because more KNO₃ can dissolve in the solution.
Source: Myschool Past Questions Archive (Record #70240)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
Strong acids can be distinguished from weak acids by any of the following methods, EXCEPT
A
Conductivity measurement
B
The use of litmus paper
C
Measurement of pH
D
Measurement of heat of reaction
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Strong and weak acids can be distinguished by their pH value, electrical conductivity, and reactivity.
A conductivity measurement can distinguish between strong and weak acids as strong acids have a higher concentration of H+ and ionize completely in water, resulting in a higher concentration of ions and greater electrical conductivity. Weak acids only partially ionize, resulting in fewer ions and lower electrical conductivity.
Generally, all acids turn blue litmus red.
Strong acids have lower pH values than weak acids. The pH scale measures the concentration of H+ in a solution, and the more H+ present, the closer the pH is to 0. Thus, measurement of pH can be used to distinguish between strong and weak acids.
The measurement of heat of reaction can distinguish between strong and weak acids.Strong acids have a higher enthalpy of neutralization than weak acids. This is because strong acids completely ionize in water, releasing all of their protons (H+ ions), while weak acids have a lower enthalpy of neutralization than strong acids. This is because weak acids only partially ionize, releasing a small fraction of their protons.
Consequently, since the use of litmus paper can't tell us how strong a solution is, option B is the correct answer.
Source: Myschool Past Questions Archive (Record #70246)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
The chemical formula for potassiumhexacyanoferrate(II) is
A
[Fe(CN)\(_6\)]\(^{4-}\)
B
K\(_3\)Fe(CN)\(_6\)
C
Fe(CN)\(_6\)
D
K\(_4\)Fe(CN)\(_6\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Potassium hexacyanoferrate(II) has a complex polymeric structure made up of octahedral [Fe(CN)6]4 centers bonded together by K+ ions. It is a complex salt as well as a
potassium hexacyanoferrate(II) is a bridging ligand (a ligand that bonds to two different metals, forming a bridge between them).
Hexacyano ⇒ 6 molecules of CN. Hence, because CN is negatively charged, it wil also need 6 positively charged ions(metals) to bond with it. However, since ferrate is already said to be ferrate(II), it implies, 4 positive ions will be needed more, and that should be from potassium.
Thus the correct formula for potassium hexacyanoferrate(II) is K\(_4\)Fe(CN)\(_6\)
Source: Myschool Past Questions Archive (Record #70247)
Chemistry
UTME / JAMB 2024
Kinetics, Energetics and Equilibrium
Solution
For chemical reaction to be spontaneous, ∆G must be
A
positive
B
negative
C
zero
D
equal to the enthalpy change
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
A spontaneous reaction is a reaction that proceeds on its own in a given set of conditions, without the external addition of energy.
Gibbs Free Energy (∆G), is thermodynamic quantity which represents the amount of usable energy available in a system at constant temperature and pressure. A negative value for \DeltaG indicates a spontaneous process; a positive \DeltaG indicates a nonspontaneous process; and a \DeltaG of zero indicates that the system is at equilibrium.This is because it means the system is releasing free energy, moving towards a lower energy state, and thus the reaction can occur without external energy input; essentially, the products have less free energy than the reactants, making the process naturally favourable.
Source: Myschool Past Questions Archive (Record #70248)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
How many moles of CO\(_2\) are produced when ethanol is burnt with 6g of oxygen
A
0.125
B
0.250
C
0.375
D
0.750
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
First, write a balanced chemical equation of the reaction:
C\(_2\)H\(_5\)OH + 3 O\(_2\) → 2 CO\(_2\) + 3H\(_2\)O
3moles : 2 moles
Using n = \(\frac{mass}{Molar mass}\), \(\frac{6}{32}\) : x mole
0.1875 mole : x mole
By simple proportion, X = \(\frac{0.1875 X 2}{3}\)
X = 0.125 mole
Source: Myschool Past Questions Archive (Record #70252)
Chemistry
UTME / JAMB 2024
Matter & Separation Techniques
Solution
Which of these is the most preferred separation technique for the isolation of solutes where the purity of the constituent is of utmost importance?
A
sieving
B
Distillation
C
recrystallization
D
Precipitation
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Distillation separates components of a liquid mixture by heating and cooling, which vaporizes and condenses the components based on their boiling points. This technique is often used in industries like pharmaceuticals and fine chemicals. This is better suited for separation mixtures based on differences in boiling points.
Recrystallization separates a dissolved solid from a solution by heating the solution until the solvent evaporates, leaving a saturated solution. This technique is often used to purify solids.
However, recrystallization is generally considered a better method of achieving high purity of solutes because of higher purity of 99.9% while distillation 99%, less contamination, better separation etc.
Nonetheless, the choice between recrystallization and distillation ultimately depends on the specific properties of the solutes. Thus option C is the correct answer
Source: Myschool Past Questions Archive (Record #70257)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
127g of sodium chloride was dissolved in 1.0dm\(^3\) of distilled water at 25\(^0\)C . Determine the solubility in moldm\(^{-3}\) of sodium chloride at that temperature. [Na = 23, Cl = 35.5]
A
1.0
B
2.0
C
2.2
D
4.1
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Solubility = Amount of solute dissolved in 1dm\(^3\) of solvent divided by the volume of solvent
Solubility = \(\frac{mass}{molar mass}\) x 1 dm\(^3\)
Molar mass of NaCl = 23 + 35.5 = 58.5 g/mol
Solubility = \(\frac{127}{58.5}\) x 1 dm\(^3\)
= 2.17
= 2.2 moldm\(^{-3}\)
Source: Myschool Past Questions Archive (Record #70241)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
The quantity of electricity required to deposit 180g of Ag from a molten silver trioxonitrate(V) is
[Ag = 108]
A
1.08F
B
3.30F
C
1.67F
D
1.80F
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Ag\(^+\) + e\(^-\) → Ag
1mole = 1F
If 1F produced 108g of Ag
x F will produce 180g of Ag
x = \(\frac{180 x 1}{108}\)
x = 1.666 F
x = 1.67 F
Source: Myschool Past Questions Archive (Record #70242)
Chemistry
UTME / JAMB 2024
Acids, Bases, and Salts
Solution
What would be the order of the electrolytic cell in an industry intending the production of silver plated spoons?
A
Cathode is the spoon; anode is a silver rod; electrolyte is a soluble silver salt
B
Cathode is a silver rod; anode is the spoon; electrolyte is a soluble silver salt
C
Cathode is the spoon; anode is any rod; electrolyte is a soluble silver salt
D
Cathode is any rod; anode is the spoon; electrolyte is a soluble salt
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
In an electrolytic refining process, the anode is made of impure metal, and the cathode is made of a strip of pure metal. When an electric current is passed through the electrolyte, metal ions from the electrolyte are deposited as a pure metal on the cathode. A soluble silver salt is used as an electrolyte in the electrolysis of silver metal because it allows for the deposition of a pure metal on the cathode.
In the electrolysis of silver metal, you cannot use any rod at the anode; it is crucial to use a silver rod as the anode because the process relies on the oxidation of silver ions from the silver anode into the solution to deposit pure silver at the cathode; using a different metal would not produce the desired result. The net result is that silver metal has been transferred from the anode to the cathode.
In summary, a silver rod is used at the anode, the spoon has to be cathode since we must obtain a pure silver spoon while the electrolyte must be a soluble silver salt because it allows easy deposition of metal ions as a pure metal on the cathode.
Source: Myschool Past Questions Archive (Record #70243)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Diagram
Solution
The table above shows the formulae of some ions. In which of these compounds is the formula not correct?
Attached Figure / Diagram
A
Aluminiumtetraoxosulphate(VI), Al\(_2\)(SO\(_4\))\(_3\)
B
Calciumtrioxonitrate(V), Ca(NO\(_3\))\(_2\)
C
Iron(III)bromide, Fe\(_3\)Br
D
Potassiumsulphide, K\(_2\)S
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Iron(III)bromide is the correct answer because Fe has a valency of +3 while Br has a valency of -1,
In the bid to form compounds, they bond together and exchange their valency.
⇒ Fe takes the valency of Br which is 1 while Br takes the valency of Fe which is 3.
Therefore, the formula for the compound formed should be FeBr\(_3\) and not Fe\(_3\)Br
Source: Myschool Past Questions Archive (Record #70244)