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Chemistry
WAEC / WASSCE 2024
Atomic Structure and Periodic Table
Solution
Which of the following arrangements of elements is in order of increasing ionization energy?
A
Si, Al, S, P
B
S, P, Si, Al
C
Al, Si, P, S
D
P, Si, S, Al
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Ionization energy is said to be the amount of energy required to remove a valence electron from the atom of an element to become a gaseous specie.
Ionization energy decrease as you move down the group and increase across the period in the periodic table. Consequently, the elements under consideration are in the same period, period 3, ranging from Aluminium to Silicon to Phosphorus to Sulphur. i.e Al < Si < P < S.
Source: Myschool Past Questions Archive (Record #72184)
Chemistry
WAEC / WASSCE 2024
Stoichiometry & Mole Concept
Solution
Consider the reaction represented by the equation:
C\(_3\)H\(_8\) + 5 O\(_2\) → 3CO\(_2\) + 4H\(_2\)O
If 0.1 mole of C\(_3\)H\(_8\) was completely burnt, what volume of CO\(_2\) would be produced at stp? [volume of gas at stp = 22.4dm\(^3\)mol\(^{-1}\)].
A
6.72dm\(^3\)
B
2.24dm\(^3\)
C
0.30 dm\(^3\)
D
0.10dm\(^3\)
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
C\(_3\)H\(_8\) + 5 O\(_2\) → 3CO\(_2\) + 4H\(_2\)O
From the equation: 1 mole : 3 moles
If 0.1 mole reacted, then 0.3 mole will be formed.
⇒ 0.3 mole of CO\(_2\) will be produced.
Recall that Number of moles of gases = \(\frac{Volume}{Molar Volume of gas at stp}\)
n = \(\frac{V}{M.V}\)
0.3 = \(\frac{V}{22.4}\)
V = 0.3 x 22.4
V = 6.72 dm\(^3\)
Source: Myschool Past Questions Archive (Record #72185)
Chemistry
WAEC / WASSCE 2024
Stoichiometry & Mole Concept
Solution
Naturally occurring Boron is made up of 19.9% \(^{10}\)B and 80.1% \(^{11}\)B. The relative atomic mass of Boron is
A
21.0
B
10.8
C
10.5
D
10.0
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Relative Atomic Mass of Boron = [19.9% \(^{10}\)B} + [80.1% \(^{11}\)B]
= [ 19.9% of 10] + [80.1% of 11]
= [ \(\frac{19.9}{100}\times{10}\) ] + [ \(\frac{80.1}{100}\times{11}\)]
= 1.99 + 8.811
= 10.801
Source: Myschool Past Questions Archive (Record #72186)
Chemistry
WAEC / WASSCE 2024
Atomic Structure and Periodic Table
Solution
The number of shared pair of electrons in a molecule of methane is
A
2
B
4
C
6
D
8
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
In methane (CH\(_4\)), there are four shared pairs of electrons. A single carbon atom in the center shares one pair of electrons with each of the four hydrogen atoms, resulting in four shared pairs.
Source: Myschool Past Questions Archive (Record #72187)
Chemistry
WAEC / WASSCE 2024
Atomic Structure and Periodic Table
Solution
Isotopes of the same element have similar chemical properties because they have the same number of
A
nuclides
B
protons
C
neutrons
D
atoms
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Isotopes differ in the number of neutrons in their nucleus, but they have the same number of protons (which determines the number of electrons). Since chemical properties are primarily determined by the electron configuration, isotopes of the same element behave similarly in chemical reactions.
Source: Myschool Past Questions Archive (Record #72188)
Chemistry
WAEC / WASSCE 2024
Acids, Bases, and Salts
Solution
Which of the following household liquids would be effective in treating someone with too much acid in the stomach?
A
Strong salt solution with pH 7.0
B
Tomato juice with pH 4.1
C
Milk of Magnesia with pH 10.5
D
Black coffee with pH 5.0
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Milk of magnesia is alkaline because it has a pH of 10.5, which means that it would neutralize any acidic substance encountered. Hence, it is an excellent antacid. It neutralizes excess stomach acid or hydrochloric acid. The hydroxide ions of the milk combine with the hydrogen ions in the stomach acid to reduce excess acidity in the stomach.
Source: Myschool Past Questions Archive (Record #72189)
Chemistry
WAEC / WASSCE 2024
Stoichiometry & Mole Concept
Solution
The percentage by mass of Oxygen in MgSO\(_4\).7H\(_2\)O is [ M\(_r\) of MgSO\(_4\).7H\(_2\)O = 246 ]
A
26.0%
B
45.5%
C
71.5%
D
84.0%
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Given:
M\(_r\) of MgSO\(_4\).7H\(_2\)O = 246
M\(_r\) of Oxygen = 16
Percentage by mass of Oxygen = \(\frac{Total mass of Oxygen}{Total mass of MgSO_4.7H_2O}\times 100\)
% by mass of Oxygen = \(\frac{11moles of oxygen}{MgSO_4.7H_2O}\times 100\) (4moles of oxygen + 7 moles of oxygen from 7H\(_2\)O )
= \(\frac{11 X 16}{246}\times 100\)
= \(\frac{176}{246}\times 100\)
= 71.544%
= 71.5%
Source: Myschool Past Questions Archive (Record #72190)
Chemistry
WAEC / WASSCE 2024
Kinetics, Energetics and Equilibrium
Solution
Catalysts alter reaction rates by
A
providing an alternative reaction pathway
B
lowering the energy of reaction
C
increasing the surface area of reactants
D
aligning the reactant molecules properly
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
A catalyst alters the rate of a chemical reaction by providing an alternative reaction pathway with a lower activation energy, meaning it makes it easier for reactants to reach the transition state and form products, thus significantly increasing the reaction rate without being consumed in the process.
Source: Myschool Past Questions Archive (Record #72191)
Chemistry
WAEC / WASSCE 2024
Stoichiometry & Mole Concept
Solution
Ethane of volume 400 cm\(^3\) was completely burnt in excess oxygen according to the following equation:
2C\(_2\)H\(_6\)\(_(g)\) + 7O\(_2\)\(_(g)\) → 6H\(_2\)O\(_(g)\) + 4CO\(_2\)\(_(g)\)
Calculate the volume of steam that would be produced.
A
200 cm\(^3\)
B
400 cm\(^3\)
C
600 cm\(^3\)
D
1200 cm\(^3\)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
2C\(_2\)H\(_6\)\(_(g)\) + 7O\(_2\)\(_(g)\) → 6H\(_2\)O\(_(g)\) + 4CO\(_2\)\(_(g)\)
2 moles 6 moles
400cm\(^3\) X cm\(^3\)
X = \(\frac{{400}\times{6}}{2}\)
X = 1200cm\(^3\)
Source: Myschool Past Questions Archive (Record #72192)
Chemistry
WAEC / WASSCE 2024
Matter & Separation Techniques
Solution
A saturated solution at 30\(^0\)C will normally produce crystals at a temperature of
A
50\(^0\)C
B
40\(^0\)C
C
35\(^0\)C
D
20\(^0\)C
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
A saturated solution at 30^\circC will normally produce crystals when it is cooled below the saturation point for that specific solute at a lower temperature; this means that crystals will typically begin to form as the solution cools down from 30^\circC, with the exact temperature depending on the solubility curve of the dissolved substance.
Source: Myschool Past Questions Archive (Record #72193)
Chemistry
WAEC / WASSCE 2024
Atomic Structure and Periodic Table
Solution
The following organic compounds are polymers except
A
rubber
B
starch
C
proteins
D
fats
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Although fats are complex molecules that are made up of fatty acids and glycerol, they are not polymers. Polymers are large molecules made up of many smaller units called monomers that are chemically bonded together.
Rubber, starch and proteins are polymers because they have several units of isoprene, glucose and amino acids respectively, chemically bonded together.
Source: Myschool Past Questions Archive (Record #72194)
Chemistry
WAEC / WASSCE 2024
Stoichiometry & Mole Concept
Solution
According to the collision theory of reaction rates, which of the following conditions is not required for two molecules to react? The molecules must
A
come into contact without loss of energy on colliding with each other
B
collide with enough energy to overcome the activation energy barrier
C
collide in an orientation that makes formation of product possible
D
possess enough speed to overcome intermolecular forces of attraction
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The collision theory assumes that the colliding molecules have sufficient energy to be able to overcome the intermolecular forces of attraction and the activation energy barriers, but it does not require that the collision be perfectly elastic. i.e no loss of energy.
Source: Myschool Past Questions Archive (Record #72195)
Chemistry
WAEC / WASSCE 2024
Acids, Bases, and Salts
Solution
A weak acid is one which
A
is not corrosive
B
completely ionizes in water
C
does not produce salt with alkali
D
slightly ionizes in water
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
While a strong acid dissociates or ionizes completely in water, weak acids only partially ionizes in water.
Source: Myschool Past Questions Archive (Record #72196)
Chemistry
WAEC / WASSCE 2024
Acids, Bases, and Salts
Solution
Which of the following conditions are necessary for the preparation of alkanoates from alkanols and alkanoic acid?
A
Water and NaOH
B
Conc. H\(_2\)SO\(_4\) and heat
C
NaOH and heat
D
water and aqueous HCl
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Esterification reaction is the reaction between an alkanol (alcohol) and an alkanoic acid (carboxylic acid) in the presence of an acid catalyst forms an ester (alkanoate) and water. To produce alkanoates (esters) from alkanols and alkanoic acids, you need to perform esterification, which requires a concentrated acid catalyst (like sulphuric acid) and heat.
Source: Myschool Past Questions Archive (Record #72197)
Chemistry
WAEC / WASSCE 2024
Stoichiometry & Mole Concept
Solution
The volume of 22g of CO\(_2\) at stp is equivalent to [C =12, O =16, molar volume at stp = 22.4 dm\(^3\) ]
A
22.0 dm\(^3\)
B
22.4 dm\(^3\)
C
11.2 dm\(^3\)
D
5.6 dm\(^3\)
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Given:
m = 22g
M.V = 22.4dm\(^3\)
V = ?
First, calculate the number of moles n, by dividing mass of CO\(_2\) by the molar mass of CO\(_2\), since n = \(\frac{mass}{Molar mass}\)
Molar mass of CO\(_2\) = 12 + (2 x 16) = 44g/mol
So, n = \(\frac{mass}{Molar mass}\)
n = \(\frac{22}{44}\) = 0.5 mole
Also recall that number of moles of gases, n = \(\frac{Volume}{Molar Volume}\)
n = \(\frac{V}{M.V}\)
0.5 = \(\frac{V}{22.4}\)
V = 0.5 X 22.4
V = 11.2 dm\(^3\)
Alternatively,
Given the mass of CO\(_2\) = 22g
Molar mass of CO\(_2\) = 12 + (16X2) = 44g
number of moles, n = \(\frac{m}{M}\) = \(\frac{22}{44}\) = 0.5 mole.
If 1 mole of CO\(_2\) = 22.4dm\(^3\)
0.5 mole of CO\(_2\) = X dm\(^3\)
X = 0.5 x 22.4 = 11.2 dm\(^3\)
Source: Myschool Past Questions Archive (Record #72198)