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Chemistry
UTME / JAMB 1978
Particulate Nature of Matter, Laws & Formulae
Solution
An element X forms the following compounds with chlorine; XCl4, XCl3, XCl2. This illustrates the
A
law of multiple proportions
B
law of chemical proportions
C
law of simple proportions
D
law of conservation of mass
E
law of definite proportions
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
this question expresses the law of multiple proportions which states that if two elements A and B combine together to form more than one compound, the various masses of element B which combines with a fixed mass of B are in simple whole number ratios. e.g
Source: Myschool Past Questions Archive (Record #38)
Chemistry
UTME / JAMB 1978
Oxidation, Reduction & Redox Reactions
Solution
The oxidation state of chlorine in potassium chlorate is?
A
+1
B
+2
C
+3
D
+5
E
+7
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
- potassium chlorate --> KClO\(_3\)
valencies of K = +1, O = -2.
: (+1) + Cl + ( -2 X 3 atoms ) = 0
Cl + 1 - 6 = 0
Cl = 5
∴ The oxidation state of chlorine in potassium chlorate is +5
Source: Myschool Past Questions Archive (Record #39)
Chemistry
UTME / JAMB 1978
Acids, Bases, pH & Salts
Solution
When air which contains the gases Oxygen, nitrogen, carbondioxide, water vapour and the rare gases, is passed through alkaline pyrogallol and then over quicklime, the only gases left are?
A
nitrogen and carbondioxide
B
the rare gases
C
nitrogen and oxygen
D
nitrogen and the rare gases
E
nitrogen, carbondioxide and the rare gases
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
- Alkaline solutions of pyrogallol absorb oxygen efficiently.
- Quicklime have a strong chemical affinity to absorb water.
- At room temperature, Calcium oxide (CaO) will spontaneously absorb carbon dioxide from the atmosphere.
Source: Myschool Past Questions Archive (Record #40)
Chemistry
UTME / JAMB 1978
Reaction Rates & Chemical Equilibrium
When heat is absorbed during a chemical reaction, the reaction is said to be
A
thermodynamic
B
exothermic
C
isothermal
D
endothermic
E
thermostatic
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #41)
Chemistry
UTME / JAMB 1978
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
When large hydrocarbon molecules are heated at high temperature in the presence of a catalyst to give smaller molecules, the process is known as
A
disintegration
B
polymerization
C
cracking
D
degradation
E
distillation
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The process described is called cracking. When large hydrocarbon molecules are heated to high temperatures, often in the presence of a catalyst, they break down into smaller, more useful molecules. This process is crucial in the petrochemical industry for converting heavy fractions of crude oil into lighter, more valuable products like gasoline and fuel oil.
Source: Myschool Past Questions Archive (Record #43)
Chemistry
UTME / JAMB 1978
Acids, Bases, pH & Salts
Solution
The pH of four solutions W, X, Y, Z are 4, 6, 8, 10 respectively, therefore
A
none of these solutions is acidic
B
the pH of Y is made more acidic by addition of distilled water
C
Z is the most acidic solution
D
W is the most acidic solution
E
X is neutral
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
W is the most acidic solution since 4 < 6 < 8 < 10. The lower the value on the pH scale, the more acidic a solution.
Source: Myschool Past Questions Archive (Record #47)
Chemistry
UTME / JAMB 1978
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
When each of the nitrates of Potassium, Magnesium and iron is heated,
A
all the nitrates decompose to their oxides
B
the nitrate of magnesium gives the nitrite and oxygen
C
the nitrates of magnesium and iron give the oxides
D
the nitrate of iron gives the nitrite and oxygen
E
the nitrate of the magnesium is not decomposed
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When heated, the nitrates of potassium, magnesium, and iron decompose as follows:
- Potassium nitrate (KNO₃) decomposes to potassium nitrite (KNO₂) and oxygen (O₂).
- Magnesium nitrate (Mg(NO₃)₂) decomposes to magnesium oxide (MgO) and nitrogen dioxide (NO₂) and oxygen (O₂).
- Iron(III) nitrate (Fe(NO₃)₃) decomposes to iron(III) oxide (Fe₂O₃) and nitrogen dioxide (NO₂) and oxygen (O₂).
So, all three nitrates would not decompose to their respective oxides except Nitrates of Magnesium and Iron.
The correct answer is C.
Source: Myschool Past Questions Archive (Record #50)
Chemistry
UTME / JAMB 1978
Metals, Transition Elements & Extraction
Solution
Which of the following metals cannot replace hydrogen from water or steam?
A
Sodium
B
Magnesium
C
Iron
D
Calcium
E
Copper
medium Difficulty
Verified Correct Answer: Option E
Chemical Principles & Mechanism
Copper cannot replace hydrogen from water or steam because it is less reactive than hydrogen and therefore cannot displace it in a chemical reaction.
Copper is located below hydrogen in the reactivity series, indicating that it is less reactive and cannot displace hydrogen.
Source: Myschool Past Questions Archive (Record #51)
Chemistry
UTME / JAMB 1978
Water, Solutions & Solubility
A sample of hard water contains some calcium sulphate and calcium hydrogen carbonate. The total hardness may therefore be removed by
A
boiling the water
B
adding excess calcium hydroxide
C
adding a calculated amount of calcium hydroxide
D
adding sodium carbonate
E
adding magnesium hydroxide
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #54)
Chemistry
UTME / JAMB 1978
Electrolysis & Electrochemical Cells
Solution
During the electrolysis of copper II sulphate between platinum electrodes, if litmus solution is added to the anode compartment,
A
the litmus turns blue but no gas is evolved
B
the litmus turns blue and oxygen is evolved
C
the litmus turns blue and hydrogen is evolved
D
the litmus turns red and oxygen is evolved
E
the litmus turns red and then becomes colourless
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Cu\(^+\) is discharged preferentially at the cathode
OH\(^-\) is discharged preferentially at the anode
The presence of SO\(_4\)\(^2-\) and H\(^+\) makes the medium acidic
Which makes the litmus turns red and oxygen is evolved
Source: Myschool Past Questions Archive (Record #58)
Chemistry
UTME / JAMB 1978
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The reaction between an organic acid and an alcohol in the presence of an acid catalyst is known as;
A
saponification
B
dehydration
C
esterification
D
hydrolysis
E
hydration
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Esterification, a reaction in which a carboxylic acid and an alcohol, heated in the presence of a mineral acid catalyst, form an ester and water:
Source: Myschool Past Questions Archive (Record #60)
Chemistry
UTME / JAMB 1978
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The IUPAC names of the compounds CH3COOH and CH2=CH2 are respectively;
A
acetic acid and ethene
B
methanoic acid and ethene
C
methanoic acid and ethylene
D
ethanol and ethene
E
acetic acid and ethylene
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The IUPAC id for \(CH_{3}COOH\) is Acetic acid, while for \(C_{2}H_{4}\) is ethene.
Source: Myschool Past Questions Archive (Record #64)
Chemistry
UTME / JAMB 1978
Kinetic Theory of Matter & Gas Laws
Solution
If 30cm\(^3\) of oxygen diffuses through a porous pot in 7 seconds, how long will it take 60cm\(^3\) of chlorine to diffuse through the same pot, if the vapour densities of oxygen and chlorine are 16 and 36 respectively?
A
9.3 sec
B
14 sec
C
21 sec
D
28 sec
E
30.3 sec
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
According to Graham's law of diffusion of gases,the rate of diffusion of a gas is proportional to the square root of the density.
From the question, the given parameters are:
Volume of Oxygen, V\(_o\) = 30cm\(^3\), Time of diffusion of Oxygen, t\(_o\) = 7s, Vapour density of Oxygen, d\(_o\) = 16
Volume of Chlorine, V\(_c\) = 60cm\(^3\), Time of diffusion of chlorine, t\(_c\) = ?, Vapour density of Chlorine, d\(_c\) = 36
\(\frac{t_o}{t_c}\) = \(\sqrt{\frac{d_o}{d_c}}\)
\(\frac{7}{t_c}\) = \(\sqrt{\frac{16}{36}}\)
\(\frac{7}{t_c}\) = \(\frac{4}{6}\)
t\(_c\) = \(\frac{7}{4}\times {6}\)
t\(_c\) = \(\frac{21}{2}\)
Recall that the volume of Chlorine is twice that of Oxygen. Hence, t\(_c\) = 2t\(_o\)
t\(_c = 2\times \frac{21}{2}\)
t\(_c\) = 21sec - Option C
Source: Myschool Past Questions Archive (Record #65)
Chemistry
UTME / JAMB 1978
Metals, Transition Elements & Extraction
Brass and bronze are both metallic alloys. Which of the following constituents is common to both alloys?
A
Tin
B
Zinc
C
Copper
D
Lead
E
Aluminium
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option C.
Source: Myschool Past Questions Archive (Record #67)
Chemistry
UTME / JAMB 1978
Stoichiometry, Mole Concept & Volumetric Analysis
Which of the following gases may not be dried with concentrated sulphuric acid?
A
HCl
B
N2
C
Cl2
D
SO2
E
NH3
medium Difficulty
Verified Correct Answer: Option E
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option E.
Source: Myschool Past Questions Archive (Record #69)