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Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
127g of sodium chloride was dissolved in 1.0dm\(^3\) of distilled water at 25\(^0\)C . Determine the solubility in moldm\(^{-3}\) of sodium chloride at that temperature. [Na = 23, Cl = 35.5]
A
1.0
B
2.0
C
2.2
D
4.1
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Solubility = Amount of solute dissolved in 1dm\(^3\) of solvent divided by the volume of solvent
Solubility = \(\frac{mass}{molar mass}\) x 1 dm\(^3\)
Molar mass of NaCl = 23 + 35.5 = 58.5 g/mol
Solubility = \(\frac{127}{58.5}\) x 1 dm\(^3\)
= 2.17
= 2.2 moldm\(^{-3}\)
Source: Myschool Past Questions Archive (Record #70241)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
The quantity of electricity required to deposit 180g of Ag from a molten silver trioxonitrate(V) is
[Ag = 108]
A
1.08F
B
3.30F
C
1.67F
D
1.80F
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Ag\(^+\) + e\(^-\) → Ag
1mole = 1F
If 1F produced 108g of Ag
x F will produce 180g of Ag
x = \(\frac{180 x 1}{108}\)
x = 1.666 F
x = 1.67 F
Source: Myschool Past Questions Archive (Record #70242)
Chemistry
UTME / JAMB 2024
Acids, Bases, and Salts
Solution
What would be the order of the electrolytic cell in an industry intending the production of silver plated spoons?
A
Cathode is the spoon; anode is a silver rod; electrolyte is a soluble silver salt
B
Cathode is a silver rod; anode is the spoon; electrolyte is a soluble silver salt
C
Cathode is the spoon; anode is any rod; electrolyte is a soluble silver salt
D
Cathode is any rod; anode is the spoon; electrolyte is a soluble salt
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
In an electrolytic refining process, the anode is made of impure metal, and the cathode is made of a strip of pure metal. When an electric current is passed through the electrolyte, metal ions from the electrolyte are deposited as a pure metal on the cathode. A soluble silver salt is used as an electrolyte in the electrolysis of silver metal because it allows for the deposition of a pure metal on the cathode.
In the electrolysis of silver metal, you cannot use any rod at the anode; it is crucial to use a silver rod as the anode because the process relies on the oxidation of silver ions from the silver anode into the solution to deposit pure silver at the cathode; using a different metal would not produce the desired result. The net result is that silver metal has been transferred from the anode to the cathode.
In summary, a silver rod is used at the anode, the spoon has to be cathode since we must obtain a pure silver spoon while the electrolyte must be a soluble silver salt because it allows easy deposition of metal ions as a pure metal on the cathode.
Source: Myschool Past Questions Archive (Record #70243)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Diagram
Solution
The table above shows the formulae of some ions. In which of these compounds is the formula not correct?
Attached Figure / Diagram
A
Aluminiumtetraoxosulphate(VI), Al\(_2\)(SO\(_4\))\(_3\)
B
Calciumtrioxonitrate(V), Ca(NO\(_3\))\(_2\)
C
Iron(III)bromide, Fe\(_3\)Br
D
Potassiumsulphide, K\(_2\)S
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Iron(III)bromide is the correct answer because Fe has a valency of +3 while Br has a valency of -1,
In the bid to form compounds, they bond together and exchange their valency.
⇒ Fe takes the valency of Br which is 1 while Br takes the valency of Fe which is 3.
Therefore, the formula for the compound formed should be FeBr\(_3\) and not Fe\(_3\)Br
Source: Myschool Past Questions Archive (Record #70244)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
The pH of a 0.001 mol dm\(^{-3}\) of H\(_2\)SO\(_4\) is
[Log\(_{10}\)2 = 0.3]
A
2.7
B
3.0
C
3.3
D
2.0
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
H\(_2\)SO\(_4\) is a strong acid, so it will completely dissociate into corresponding ions.
On dissociation, H\(_2\)SO\(_4\) → 2H\(^+\) + SO\(_4\)\(^{2-}\)
If the concentration of H\(_2\)SO\(_4\) is 0.001 M so, the concentration of 2H\(^+\) will be 0.002 M (0.001 x 2). This is because 1 molecule of H\(_2\)SO\(_4\) gives 2H\(^+\) ions.
Recall that pH = - Log\(_{10}\)[H\(^+\)]
pH = - Log\(_{10}\)[2H\(^+\)] (basicity is 2)
= - Log\(_{10}\)[2 x 0.001]
= - (Log\(_{10}\)2 + Log\(_{10}\) 0.001)
= - (Log\(_{10}\)2 + Log\(_{10}\) 10\(^{-3}\))
Also recall that Log\(_{10}\)2 = 0.3 and Log\(_{10}\)10 = 1
Therefore, pH = - (0.3 - 3)
= - ( - 2.7)
= 2.7 - Option A
Source: Myschool Past Questions Archive (Record #70245)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
The principle which states that no two electrons in the same orbitals of an atom have same value for all four quantum numbers is the
A
Aufbau principle
B
Hund's rule
C
Pauli Exclusion principle
D
Dilution principle
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The Aufbau Principle states that, in the ground state of an atom or ion, electrons fill atomic orbitals of the lowest available energy level before occupying higher-energy levels.i.e 1S2S2P..
Hund's rule states that electrons fill orbitals singly before pairing up, and that electrons in singly occupied orbitals have the same spin.
The Pauli Exclusion Principle states that, in an atom or molecule, no two electrons can have the same four electronic quantum numbers.
The dilution principle is a method for measuring the concentration of a solute in a solution, or the volume of a fluid compartment.
Option C is the correct answer.
Source: Myschool Past Questions Archive (Record #70267)
Chemistry
UTME / JAMB 2024
Stoichiometry & Mole Concept
Solution
How much of 5g of radioactive element whose half life is 50days remains after 200days?
A
2.50 g
B
1.25 g
C
0.63 g
D
0.31 g
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
There are several methods of solving this radioactivity problem. One of the easiest is:
\(\frac{Original mass}{2^n}\) = Residual mass
Where n = number of activity = \(\frac{exposure time}{half life}\)
Given:
Original mass = 5g, exposure time = 200 days , half life = 50 days, Residual mass = ?
Substituting all the given parameters appropriately, we have
n = \(\frac{200}{50}\)
n = 4
\(\frac{Original mass}{2^n}\) = Residual mass
\(\frac{5}{2^4}\) = Residual mass
\(\frac{5}{16}\) = Residual mass
Residual mass = 0.3125g = 0.31g
Source: Myschool Past Questions Archive (Record #70268)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
The group VIII elements are the inert gases because they
A
have lone pair of electrons on their valence shells
B
all have completely filled valence shells
C
are all solids
D
are all polyatomic molecules
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Group VIII also known as inert gases all have their valence shell completely filled with electrons, hence they are referred to as Group O.
Source: Myschool Past Questions Archive (Record #70270)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
Na\(_2\)X ⇌ 2Na\(^+\) + X\(^{2-}\)
The bond between Na and X is likely to be
A
covalent
B
dative
C
ionic
D
metallic
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sodium is a metal and X is a non-metal, so the bond between them is ionic. Ionic bonds form when a metal bonds with a non-metal.
Element X receives 2 electrons from Na metal and became negatively charged.
Source: Myschool Past Questions Archive (Record #70275)
Chemistry
UTME / JAMB 2024
Atomic Structure and Periodic Table
Solution
The highest isotope of hydrogen is
A
Deuterium
B
protium
C
tritium
D
positron
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The most common isotope of hydrogen, making up more than 99.98% of all hydrogen in the universe. Protium is the lightest isotope of hydrogen and is also known as ordinary hydrogen. Its symbol is 1H. However, the highest isotope of Hydrogen is Tritium \(^3\)T with 1 proton and 2 neutrons.
Source: Myschool Past Questions Archive (Record #70276)
Chemistry
UTME / JAMB 2024
Acids, Bases, and Salts
Solution
The ions responsible for permanent hardness in water are sulphates of
A
Fe\(^{3+}\) and Mg\(^{2+}\)
B
Ca\(^{2+}\) and Mg\(^{2+}\)
C
Fe\(^{2+}\) and Fe\(^{3+}\)
D
Na\(^{+}\) and Ca\(^{2+}\)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Water is considered permanently hard when it contains soluble chlorides and sulphates of calcium and magnesium. These salts do not precipitate out when the temperature increases, so boiling the water will not remove them.
Source: Myschool Past Questions Archive (Record #70261)
Chemistry
UTME / JAMB 2024
Acids, Bases, and Salts
Solution
One of the following is not a water pollutant?
A
Inorganic fertilizers
B
Warm water affluent
C
Oxygen gas
D
Biodegradable waste
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Oxygen is not a water pollutant. In fact, oxygen is essential for the survival of life in water.
Some examples of water pollutants include:
Chemical pollutants: Pesticides, fertilizers, and waste from landfills and septic systems
Organic wastes, Microbial contaminants ,Nutrients ,Plastics ,Faecal waste ,Radioactive substances ,Phosphorus and nitrogen.
Source: Myschool Past Questions Archive (Record #70262)
Chemistry
UTME / JAMB 2024
Matter & Separation Techniques
Solution
What method is suitable for the separation of gases present in air?
A
Catalytic cracking of liquid air
B
Fractional distillation of liquid air
C
Thermal decomposition of air
D
Catalytic decomposition of air
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Fractional distillation is the most common method for separating the gases in air. This method is used because the gases in air have a difference in boiling points of less than 25 K, making them suitable for fractional distillation.
Here's how fractional distillation works:
1. Liquefy the gases: Air is converted into liquid air by increasing the pressure and decreasing the temperature.
2. Separate carbon dioxide and water vapour: As the temperature drops below 0^\circC, carbon dioxide separates as dry ice and water vapor separates as ice.
3. Pass the liquid air through a column: The liquid air is then passed through a fractional distillation column, where the gases are separated based on their boiling points.
Source: Myschool Past Questions Archive (Record #70265)
Chemistry
UTME / JAMB 2024
Acids, Bases, and Salts
Solution
When Sulphur(IV)oxide is passed into solution of acidified tetraoxomanganate(VII), the colour changes from
A
blue to green
B
pink to yellow
C
purple to colourless
D
Orange to green
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When sulphur dioxide (SO\(_2\) gas is passed through an acidified potassium permanganate (KMnO\(_4\)) solution, the solution changes from purple to colourless. This is because of a redox reaction, where KMnO\(_4\) acts as an oxidizing agent and SO\(_2\) acts as a reducing agent.
Source: Myschool Past Questions Archive (Record #70277)
Chemistry
UTME / JAMB 2024
Matter & Separation Techniques
Solution
Water gas obtained from the gasification of coke is made up of
A
Nitrogen and Carbon(II) oxide
B
Nitrogen and Hydrogen
C
Hydrogen and Carbon(II) oxide
D
Carbon(II)oxide and Carbon(IV)oxide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Water gas also known as synthesis gas is obtained from the gasification of coke. It is a flammable, poisonous gas mixture that's made up of carbon monoxide (CO) and hydrogen (H\(_2\)).
Source: Myschool Past Questions Archive (Record #70278)