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Chemistry
UTME / JAMB 2001
Oxidation, Reduction & Redox Reactions
Solution
In which of the following reactions has the oxidation number of nitrogen increased?
A
2NO(g) + Br2(l) → 2NOBr(l)
B
2NO(g) + O2(g) → 2NO2(g)
C
FeSO4(aq) + NO(g) → Fe(NO)SO4(s)
D
2NO(g) + Cl2(g) → 2NOCl(l)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
In option B, the oxidation of Nitrogen increases from +2 to +4, when you calculate the oxidation number.
Source: Myschool Past Questions Archive (Record #1722)
Chemistry
UTME / JAMB 2001
Chemical Energetics & Thermochemistry
Solution
NH\(_3\)\(_{(g)}\) + HCl\(_{(g)}\) → NH\(_4\)Cl\(_{(s)}\)
The entropy change in the system above is
A
negative
B
indeterminate
C
positive
D
zero
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Deposition is a thermodynamic process that occurs when a substance changes from a gas to a solid without passing through the liquid phase. This happens due to a decrease in temperature.The entropy change for the transition from gas to solid is negative because solids have lower entropy compared to gases, gas particles are more disordered and have a higher rate of motion compared to solids that have closely packed particles.
Source: Myschool Past Questions Archive (Record #1723)
Chemistry
UTME / JAMB 2001
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Fermentation is the
A
breaking down of carbohydrate to glucose
B
conversion of sugar to alcohol in the presence of yeast
C
breaking down of sugar to carbohydrate
D
conversion of alcohol to sugar in the presence of yeast
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Microorganisms, such as yeasts, molds, and bacteria, break down organic substances, usually in the absence of oxygen. This process breaks down starch or cellulose chains into individual sugar molecules, which are then fermented into ethanol and carbon dioxide.
Source: Myschool Past Questions Archive (Record #1724)
Chemistry
UTME / JAMB 2001
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The general formula for the alkanals is
A
ROH
B
R2CO
C
RCOOR1
D
RCHO
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
ROH - Alkanols
R\(_2\)CO - Ketones
RCOOR\(^1\) - Esters or alkanoates
The general formula for alkanals is C\(_n\)H\(_{2n+1}\)CHO, where n = 0, 1, 2, 3, and so on. In other words, it is RCHO
Alkanals are compounds that are formed when long-chain primary alcohols are oxidized. Primary alkylsulphates biodegrade to produce these alcohols.
Source: Myschool Past Questions Archive (Record #1725)
Chemistry
UTME / JAMB 2001
Acids, Bases, pH & Salts
Solution
The main impurity in iron ore during the extraction of iron is
A
Silicon (IV) oxide
B
Carbon (IV) oxide
C
Calcium trioxosilicate
D
Sulphur (II) oxide
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Iron ore is typically found with various impurities, with the main impurity being silicon dioxide (SiO\(_2\)). To remove silicon dioxide from iron ore, calcium oxide (CaO) is added to the blast furnace. This is a neutralization reaction because silicon dioxide is acidic and calcium oxide is basic.
CaO\(_{(s)}\) + (SiO\(_2\))\(_{(s)}\) → CaSiO\(_2\)\(_{(s)}\).
Base Acid
Source: Myschool Past Questions Archive (Record #1726)
Chemistry
UTME / JAMB 2001
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
During the vulcanization of rubber, sulphur is added to
A
Break down rubber polymer
B
Lengthen the chain of rubber
C
Bind rubber molecules together
D
Act as a catalyst
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sulphur is added to rubber during vulcanization to create strong chemical bonds that improve the rubber's durability, strength, and elasticity. In other words it binds the molecules of rubber together
Source: Myschool Past Questions Archive (Record #1727)
Chemistry
UTME / JAMB 2001
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Catalytic hydrogenation of benzene produces
A
Oil
B
Cyclohexene
C
Cyclohexane
D
Margarine
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Hydrogenation of benzene involves the addition of 3 molecules of H\(_2\) = 6 Hydrogen atoms in all.
To do this, the three double bonds present in the Benzene (C\(_6\)H\(_6\)) will be opened so that the 6 Hydrogen molecules can attach to the Carbon atoms each, resulting into C\(_6\)H\(_{12}\) (in a cyclic form, hence the name cyclo). Recall, Saturated Hydrocarbon with 6C atoms is called Hexane, hence the name is cyclohexane.
Source: Myschool Past Questions Archive (Record #1728)
Chemistry
UTME / JAMB 2001
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
A trihydric alkanol is
A
Glycerol
B
Phenol
C
Glycol
D
Ethanol
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
A trihydric alkanol is an alkanol with three hydroxyl (OH) groups. Glycerol is an example of a trihydric alkanol.
Trihydric alkanol (e.g propan-1,2,3- triol, also known as glycerol) has three -OH group attached to the three C atoms.
See diagram above
Source: Myschool Past Questions Archive (Record #1729)
Chemistry
UTME / JAMB 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
When chlorine Is passed into water and the resulting solution exposed to sunlight, the product formed are
A
Chlorine gas and hydrogen
B
Oxygen and oxochlorate (I) acid
C
Chlorine gas and oxochlorate (I) acid
D
Hydrochloric acid and oxygen
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
When chlorine is passed into water and the resulting solution is exposed to sunlight, the products formed are hydrochloric acid and oxygen gas.
Firstly, Chlorine reacts with water to form hypochlorous acid.
Cl\(_2\) + H\(_2\)O → HClO
Secondly, hypochlorous acid breaks down into Hydrochloric acid and Oxygen gas.
2HClO → 2HCl + O\(_2\)
Ultraviolet light from the sun provides the energy needed to break the chlorine molecule and starts the reaction.
Source: Myschool Past Questions Archive (Record #1730)
Chemistry
UTME / JAMB 2001
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Proteins in acid solution undergo
A
Polymerization
B
Substitution
C
Fermentation
D
Hydrolysis
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Proteins can undergo a hydrolysis reaction when treated with a concentrated acid solution at a high temperature. This reaction breaks the peptide bonds that hold amino acids together, releasing the amino acids.
Source: Myschool Past Questions Archive (Record #1731)
Chemistry
UTME / JAMB 2001
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
A characteristic reaction of the compounds with the general formula C\(_n\)H\(_{2n}\) is
A
Esterification
B
Polymerization
C
Decarboxylation
D
Substitution
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Polymerization of alkenes is a chemical reaction that combines small molecules called monomers into large molecules called polymers. This process occurs when the double bonds of alkene molecules break, and new single bonds form between the carbon atoms of adjacent monomer.
Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO\(_2\)). It usually refers to the removal of a carbon atom from a carbon chain in carboxylic acids.
Source: Myschool Past Questions Archive (Record #1732)
Chemistry
UTME / JAMB 2001
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The pair of organic compounds that are isomers is
A
Benzene and methylbenzene
B
Trichloromethane and tetrachloromethane
C
Ethanol and propane
D
But-1-ene and but-2-ene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Isomers refer to compounds that have the same molecular formula but are structurally different. Both But-1-ene and But-2-ene have the same number of Carbons and the same number of Hydrogen. The only difference is the positions of the double bond. Therefore, they are isomers
Source: Myschool Past Questions Archive (Record #1733)
Chemistry
UTME / JAMB 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
A burning candle produces water and
A
Carbon (II) oxide
B
Carbon (IV) oxide
C
Oxygen
D
Hydrogen
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
A candle is an hydrocarbon. Generally when hydrocarbons undergo combustion (like a burning candle), there are ususally two products yielded, which are water and carbon (iv)oxide. The answer is option B
Source: Myschool Past Questions Archive (Record #1734)
Chemistry
UTME / JAMB 2001
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The gas that can best be collected by downward displacement of air is
A
Chlorine
B
Sulphur (IV) oxide
C
Ammonia
D
Carbon (IV) oxide
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The method used to collect a gas depends on whether it is denser or lighter than air. For example, ammonia gas is collected by downward displacement of air because it is lighter than air. Option C is the correct answer.
Chlorine is heavier than air.
SO\(_2\) is denser than air.
CO\(_2\) is denser than air.
Source: Myschool Past Questions Archive (Record #1735)
Chemistry
UTME / JAMB 2001
Metals, Transition Elements & Extraction
Solution
Which of the following metals burn with brick red flame?
A
Pb
B
Ca
C
Na
D
Mg
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When heated, lead (Pb) burns with a bluish-white or greyish-white flame.
When heated, calcium burns with a brick red flame and forms a white solid. The calcium ion (Ca2+) produces a brick red color in a flame test.
When heated in air, sodium (Na) burns with a bright, golden yellow flame.
When heated, magnesium burns with a bright, dazzling white flame.
Source: Myschool Past Questions Archive (Record #1736)