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Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The boiling of fat and aqueous caustic soda is referred to as
A
hydrolysis
B
esterification
C
acidification
D
saponification
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Saponification is a process that involves the conversion of fat, oil, or lipid, into soap and alcohol by the action of aqueous alkali.
Source: Myschool Past Questions Archive (Record #2140)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The most important use of hydrogen is in the
A
manufacture of ammonia
B
manufacture of methyl alcohol
C
manufacture of ethyl alcohol
D
hydrogenation of oils
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The most important use of hydrogen is the ammonia synthesis or manufacture of ammonia(Haber process). The use of hydrogen is extending quickly in fuel refinement, like the breaking down by hydrogen (hydrocracking), and in sulphur elimination.
Source: Myschool Past Questions Archive (Record #2141)
Chemistry
UTME / JAMB 2002
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
which of the following polymers is suitable for packaging and electrical insulation?
A
polyamide
B
polyethene
C
polycarbonate
D
polystyrene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Polyvinyl Chloride (PVC) and polyethylene (PE) are polymers that are used for both packaging and electrical insulation.
Polyethylene or polyethene (PE) is a popular plastic used for insulating cables, wires, bushings, and transformer components. PE has excellent insulation properties and high dielectric strength. However, Polyethylene is a good choice for packaging because it's non-toxic, food safe, and can be customized into many shapes and sizes. It's also resistant to chemicals, UV light, and moisture, and can be reused while polystyrene is a good choice for electrical insulation because it has low thermal conductivity and prevents the flow of electrical current. Since polystyrene can serve both purposes, it's a better answer compared to polyethene.
Source: Myschool Past Questions Archive (Record #2142)
Chemistry
UTME / JAMB 2002
Periodic Table & Periodicity
Solution
Hydrogen is readily released when dilute hydrochloric acid reacts with
A
Cu
B
Na
C
Au
D
Ag
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When alkali metals react with Hydrochloric acids. hydrogen gas is usually produced. Hence, Sodium belongs to the group of Alkali metals.
Na + HCl → NaCl + H\(_2\)
Source: Myschool Past Questions Archive (Record #2143)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The intermediate product formed when ethanol is progressively oxidized to ethanoic acid with potassium heptaoxodichromate (IV) is
A
butanal
B
ethanal
C
methanal
D
propanal
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The complete oxidation of ethanol to ethanoic acid is a stepwise process that involves the following steps:
Ethanol is oxidized to ethanal
Water adds an oxygen atom to ethanal
Ethanoic acid is formed.
Source: Myschool Past Questions Archive (Record #2144)
Chemistry
UTME / JAMB 2002
Oxidation, Reduction & Redox Reactions
Solution
A rock sample was added to cold dilute HNO3. The gas evolved was passed into a solution of acidified K2Cr2O7 and the solution turned green. The sample contains
A
Cl-
B
NO3-
C
SO32-
D
SO42-
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Sulphur dioxide reacts with potassium dichromate and sulphuric acid to produce potassium sulphqqqqqqqqqqqqqqqate, chromium(III) sulfate and water and the solution turns from orange to green.
Source: Myschool Past Questions Archive (Record #2145)
Chemistry
UTME / JAMB 2002
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
Which of the following statement is true of a proton?
A
The mass of a proton is 1840 times the mass of electron
B
the total mass of the protons in a particular nucleus is always half the nuclear size
C
The mass of a proton is one - twelfth the molar mass of carbon
D
The mass of a proton is 1.0008g
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The mass of a proton is 1.6726\times10−24 g, while the mass of a proton = 1.00727 a . m. u. so OPTION A is correct because the mass of an electron is \(\frac{1}{1840}\) of that of a proton, which is the same as say the mass of a proton is 1840 times the mass of an electron.
Source: Myschool Past Questions Archive (Record #2146)
Chemistry
UTME / JAMB 2002
Periodic Table & Periodicity
Solution
Which of the following chloride would exhibit the least ionic character?
A
MgCl2
B
CaCl2
C
LiCl
D
AlCl3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Though all the salts in the options are chloride salts but the focus should be on the Metals that formed the chlorides. In terms of reactivity, Group I metals(Li) are the most reactive, followed by Group II(Mg and Ca) and then group III (Al). Therefore, AlCl\(_3\) would exhibit the least ionic character, as the ionic bond formed is not as strong as those found in other options.
Also, most importantly, according to Fajan's Rule, the greater the charge on the cation, the greater will be the covalent character in the bond. Since, LiCl has low charge on cation(Li+), it has the most ionic character, while AlCl\(_3\) has a very high charge on Cation Al\(^{3+}\), it will exhibit the least ionic character.
Source: Myschool Past Questions Archive (Record #2147)
Chemistry
UTME / JAMB 2002
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
A fixed mass of gas has a volume of 92\(cm^3\) at 3ºC. What will be its volume at 18ºC if the pressure remains constant?
A
15.3cm3
B
87.3cm3
C
552.0cm3
D
97.0cm3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
According to Charle's law,
\(\frac{V_1}{T_1}\) =\(\frac{V_2}{T_2}\)
T\(_1\) = 3+273 = 276K and T\(_2\) = 18 + 273 = 291K
∴ \(\frac{92}{276}\) = \(\frac{V_2}{291}\)
V\(_2\) = \(\frac{92}{291}\) X 276
= 97.0\(cm^3\)
Source: Myschool Past Questions Archive (Record #2148)
Chemistry
UTME / JAMB 2002
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
The processes which return carbon (IV) oxide to the atmosphere include
A
respiration, decay and combustion
B
photosynthesis, respiration and transpiration
C
ozone depletion, combustion and decay
D
photosynthesis, decay and respiration
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Carbon(IV) oxide is returned to the atmosphere through various processes including combustion( Burning fossil fuels, wood, or gasoline releases carbon dioxide into the atmosphere), respiration (All living organisms, including plants and animals, release carbon dioxide when they breathe. This process is also known as cellular respiration), and decay(when organisms die, the process of decomposition breaks down complex carbon compounds into simpler ones. This process releases CO\(_2\) into the atmosphere).
Conversely,Photosynthesis is a process that removes CO\(_2\) from the atmosphere and uses it to create carbohydrates and oxygen.
Source: Myschool Past Questions Archive (Record #2149)
Chemistry
UTME / JAMB 2002
Particulate Nature of Matter, Laws & Formulae
Solution
The postulate of Dalton's atomic theory which still holds is that
A
atoms can neither be created nor destroyed
B
the particles of the same element are exactly alike
C
particles of different elements combine in simple whole number ratio
D
all elemets are made of small indivisible particles
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Two postulates of Dalton's atomic theory that are still considered correct today are:
Atoms of different elements have different masses and properties: This is considered the most fundamental and important postulate.
Matter is neither created nor destroyed in a chemical reaction: This postulate reflects the Law of Conservation of Mass.
Atom of an element cannot be created, divided, destroyed, or split into smaller particles or transformed into atoms of other elements or transformed into other atoms in a chemical reaction. They are simply rearrangement of new compound. Dalton’s atomic theory based this hypothesis on the law of conservation of mass and on centuries of experimental evidence.
Source: Myschool Past Questions Archive (Record #2150)
Chemistry
UTME / JAMB 2002
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
\(^{14}\) \(_6\)C → X + \beta
X in the equation above represents
A
126C
B
125B
C
147N
D
136C
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
146C → X + \beta
→ X + 0-1e
→ 147X
Source: Myschool Past Questions Archive (Record #2151)
Chemistry
UTME / JAMB 2002
Kinetic Theory of Matter & Gas Laws
Solution
If 0.75 mole of cyclopropane and 0.66 mole of oxygen are mixed in vessel with a total pressure of 0.7 atmosphere, what is the partial pressure of oxygen in the mixture
A
0.44 atmosphere
B
0.22 atmosphere
C
0.55 atmosphere
D
0.33 atmosphere
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Parameters given:
Number of moles of Cyclopropane, N\(_c\) = 0.75 mole
Number of moles of Oxygen, N\(_o\) = 0.66 mole
Total pressure of mixture of gases, P\(_T\) = 0.70 atm
Partial pressure of Oxygen in the mixture, P\(_O\) = ?
Using the formula, P\(_O\) = \(\frac{N_o}{{N_o} + {N_c}}\) X P\(_T\)
= \(\frac{0.66}{{0.66} + {0.75}}\) X 0.70
= \(\frac{0.66}{1.41}\) X 0.70
= 0.3276
= 0.33 atm
Source: Myschool Past Questions Archive (Record #2152)
Chemistry
UTME / JAMB 2002
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The compound above is
A
glycol
B
primary alkanol
C
secondary alkanol
D
tertiary alkanol
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A secondary alcohol is an organic compound where a hydroxyl group (-OH) is attached to a carbon atom that is bonded to two other carbon atoms.
Source: Official Exam / Past Question Archive
Chemistry
UTME / JAMB 2002
Nature of Matter & Separation Techniques
Diagram
Solution
In the diagram above, the curve that represents the production of oxgyen gas from the decomposition of KCIO3 in the presence of MnO2 catalyst is
Attached Figure / Diagram
A
R
B
P
C
S
D
Q
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The decomposition of KClO\(_3\) in the presence of MnO\(_2\) catalyst changes solid to gas, which is a sublimation process, as Oxygen gas is produced.
MnO\(_2\)
2KClO\(_3\) → 2KCl + 3O\(_2\)
Decreasing the pressure on a solid causes it to turn into a gas through a process called sublimation. Thus, the effect of pressure on solid is negligible. Consequently, from the curve given in the question, it means pressure is constant as the decomposition reaction proceeds to completion.Therefore, the curve is represented by R.
Source: Myschool Past Questions Archive (Record #31608)