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Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The structural component that makes detergent dissolve more quickly in water than soap is
A
-SO3- Na+
B
-COO-Na-
C
-SO4- Na+
D
-COO-K+
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Soaps are made up of a fatty acid with a long alkyl chain and a '-COONa' group, while detergents are made up of a long alkyl chain and a '-SO3 Na\(^+\) group. The polar sulfonate in detergents makes them more soluble in hard water than soaps because it's less likely to bind to calcium and other ions in hard water.
Source: Myschool Past Questions Archive (Record #2257)
Chemistry
UTME / JAMB 2003
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
A liquid that will dissolve fat is?
A
Hydrochloric acid
B
Calcium hydroxide
C
Kerosene
D
Water
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Organic solvents, such as alcohol, chloroform, petroleum ether, and hexane, can dissolve fats and oils. Other organic solvents that can dissolve fats include: benzene, diethylether, and tetrachloromethane. Kerosene also falls within this category of non-polar solvents.
Fats are insoluble in water because they are hydrophobic and do not have polar bonds. Water is a polar molecule, meaning that the oxygen atom has a partial negative charge and the hydrogen atoms have partial positive charges.
Source: Myschool Past Questions Archive (Record #2258)
Chemistry
UTME / JAMB 2003
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
What mass of K2CrO4 is required to prepare 250cm3 of 0.020 mol dm3 solution?
[K2CrO4 = 194.2g mol-1]
A
0.97g
B
9.70g
C
19.42g
D
97.10g
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
1 mole m-3 K2CrO4 contains 194.2g mol-1 in 1000cm3
1 mole m-3 K2CrO4 contains 92.2g mol-1 in 500cm3
1 mole m-3 K2CrO4 contains 48.55g mol-1 in 250cm3
If n molm-3 K2CrO4 contain 48.55
0.02 molm-3 will contain (0.02/1) * (48.55/1) = 0.97g
Source: Myschool Past Questions Archive (Record #2259)
Chemistry
UTME / JAMB 2003
Air & Environmental Chemistry
Solution
Farmlands affected by crude-oil spillage can be decontaminated by
A
Adding acidic solution
B
Using aerobic bacteria
C
Pouring water on the affected water area
D
Burning off the oil from the area
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Biological methods use microorganisms, such as bacteria and fungi, to break down petroleum hydrocarbons. You can till the contaminated soil. This allows for aerobic action that will break down the oil. Wetting the contaminated soil with a bio-friendly detergent will help break down the oil faster. Hydrogen peroxide is also used to aid in breaking down the oil as the oxygen helps the microbes.
Source: Myschool Past Questions Archive (Record #2261)
Chemistry
UTME / JAMB 2003
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
When 10g of sodium hydroxide is dissolved in 1000cm\(^3\) of water, the sodium formed is approximately
[Na = 23, H = 1, O = 16]
A
0.01 mol dm-3
B
0.10 mol dm-3
C
0.25 mol dm-3
D
0.50 mol dm-3
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Note that Number of moles = \(\frac{mass}{Molar mass}\)
n = \(\frac{10}{40}\) = 0.25 mol.
⇒ 0.25 mol of Sodium hydroxide is dissolved in 1000cm\(^3\) = 1 dm\(^3\)
i.e 0.25mol dm\(^3\)
Source: Myschool Past Questions Archive (Record #2262)
Chemistry
UTME / JAMB 2003
Water, Solutions & Solubility
Solution
A change in temperature of a saturated solution disturb the equilibrium between the
A
Dissolved solute and the solvent
B
Solvent and undissolved solute
C
Dissolved solute and undissolved solute
D
Dissolved solute and the solution
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A saturated solution is one in which no more solute can be dissolved in a given amount of solvent at a specified temperature and pressure.
Source: Myschool Past Questions Archive (Record #2263)
Chemistry
UTME / JAMB 2003
Chemical Energetics & Thermochemistry
Solution
If an equilibrium reaction has \DeltaH > 0, the reaction will proceed favourably in the forward direction at
A
High temperature
B
Any temperature
C
Low temperature
D
Minimum temperature
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
If \DeltaH > 0, it simply means it is an endothermic reaction. However, in an endothermic reaction, the reaction will proceed favourably if the temperature is increased.
Source: Myschool Past Questions Archive (Record #2266)
Chemistry
UTME / JAMB 2003
Electrolysis & Electrochemical Cells
Solution
The commonest feature of reactions at the anode is that
A
electrons are consumed
B
oxidation is involved
C
ions are reduced
D
electrode dissolves
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The commonest feature of reactions at the anode is that oxidation is involved, because electrons are being lost as the substance becomes positively charged.
Source: Myschool Past Questions Archive (Record #2267)
Chemistry
UTME / JAMB 2003
Reaction Rates & Chemical Equilibrium
Solution
Which of the following will change when a catalyst is added to a chemical reaction?
A
The activation energy
B
The potential energy of the reactants
C
The heat of the reaction
D
the potential energy of the product
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Adding a catalyst to a chemical reaction lowers the activation energy.
A catalyst speeds up a reaction by providing an alternative reaction pathway that requires less energy. This is similar to how an escalator requires less energy to get to a destination than stairs.The catalyst does not change the energy of the reactants or products. It also doesn't change the standard enthalpy change or the Gibbs energy of the reaction.
Source: Myschool Past Questions Archive (Record #2269)
Chemistry
UTME / JAMB 2003
Oxidation, Reduction & Redox Reactions
Solution
If y is an oxidizing agent that reacts with a reducing agent, Z, which of the following is correct?
A
Y increases in oxidation number
B
Y becomes reduced
C
Z loses protons
D
Z gains protons
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
An oxidizing agent is reduced in a chemical reaction, meaning it gains electrons and its oxidation state decreases. An oxidizing agent, also known as an oxidant or oxidizer, is a substance that causes oxidation by accepting electrons from another compound, called the reducing agent. This process is called reduction, and it makes the oxidizing agent more negative.
Source: Myschool Past Questions Archive (Record #2270)
Chemistry
UTME / JAMB 2003
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
When at equilibrium, which of the reactions below will shift to the right if the pressure is increased and the temperature is kept constant?
A
2SO3(g) ↔ 2SO2(g) + O2(g)
B
2CO2(g) ↔ 2CO(g) + O2(g)
C
2H2(g) + O2(g) ↔ 2H2O(g)
D
2NO(g) ↔ N2(g) + O2(g)
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
An increase in pressure will usually favour the side with a lesser value of total number of moles of gaseous substances, thereby causing the equilibrium position to shift. However, for the equilibrium position to shift to the right if the pressure is increased, it means the total number of moles of the gaseous species on the RHS must be lesser than the total number of moles on the LHS. Consequently, option C is the only option having 2moles of water on the RHS against 3moles on the LHS.
Source: Myschool Past Questions Archive (Record #2271)
Chemistry
UTME / JAMB 2003
Electrolysis & Electrochemical Cells
Solution
In the electrolysis of a concentrated solution of sodium chloride using electrodes, which of the following ions are discharged at the cathode and anode respectively?
A
Na+ and Cl-
B
Na+ and OH-
C
H+ and OH-
D
H+ and Cl-
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The electrolysis of sodium chloride solution, also known as brine, produces chlorine gas at the anode and hydrogen gas at the cathode. Sodium hydroxide is also formed as a by-product, depending on the concentration of sodium chloride in water. During the electrolysis of a concentrated sodium chloride solution, hydrogen ions are discharged at the cathode and chloride ions are discharged at the anode.
Source: Myschool Past Questions Archive (Record #2274)
Chemistry
UTME / JAMB 2003
Chemical Energetics & Thermochemistry
Solution
CO(g) + H2O(g) → CO2(g) + H2(g)
From the reaction above, calculate the standard enthalpies of formation if CO2(g), H2O(g) and CO(g) in kJ mol-1 are -394, -242, and -110 respectively.
A
-262 kJ mol-1
B
-42 kJ mol-1
C
+42 kJ mol-1
D
+262 kJ mol-1
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
CO + H2O → CO2 + H2 DH = - 394 kJ mol-1
The equation for the standard enthalpy change of formation is
\DeltaHreaction = \DeltaH(products) − \DeltaH(reactants)
= - 394 - ( - 242 - 110)
= - 394 - ( - 352)
= - 394 + 352
= - 42 kJ mol-1
Source: Myschool Past Questions Archive (Record #2511)
Chemistry
UTME / JAMB 2003
Chemical Energetics & Thermochemistry
Solution
When sugar is dissolved in tea, the reaction is always accomplished by
A
positive change in entropy
B
negative entropy change
C
no entropy change
D
a minimum entropy change
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The dissolution of sugar in tea is accompanied by positive change in entropy. When there is a change in the state of a substance from solid to liquid, there is an increase in entropy. In general, if a substance changes its structure from a condensed state to a less condensed state, then we say there is an increase in entropy.
Source: Myschool Past Questions Archive (Record #2512)
Chemistry
UTME / JAMB 2003
Electrolysis & Electrochemical Cells
Solution
Which of the following is an electrolyte?
A
Alcohol
B
Sodium acetate solution
C
Solid potassium hydroxide
D
Mercury
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
An electrolyte is a compound that dissociates into ions in an aqueous solution. When sodium acetate is dissolved in water, it dissociates into sodium cations, Na\(^+\) and acetate anions CH\(_3\)COO\(^-\). Sodium acetate is a strong electrolyte in an aqueous solution.
Source: Myschool Past Questions Archive (Record #2513)