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Chemistry
UTME / JAMB 2005
Chemical Bonding & Intermolecular Forces
Solution
The shape of the hydrocarbon compound CH\(_4\) is
A
square planar
B
planar
C
linear
D
tetrahedral
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Methane (CH\(_4\)) has a tetrahedral shape with four equivalent C-H bonds and bond angles of 109.5 degrees.
The tetrahedral shape of methane can be explained using the Valence Shell Electron Pair Repulsion (VSEPR) theory, which states that electron pairs around an atom will arrange themselves to minimize repulsion. The carbon atom in methane undergoes sp3 hybridization, meaning that it combines one s orbital and three p orbitals to form four equivalent sp3 hybrid orbitals.
Source: Myschool Past Questions Archive (Record #2979)
Chemistry
UTME / JAMB 2005
Chemical Bonding & Intermolecular Forces
Solution
Which of these properties gives a solid its definite shape?
A
strong intermolecular attraction
B
high melting point
C
high boiling point
D
weak intermolecular attraction
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
In solids, the particles (atoms, molecules, or ions) are closely packed together due to strong intermolecular forces. These forces are strong enough to overcome the thermal energy of the particles, preventing them from moving freely.
Strong intermolecular forces of attraction are primarily responsible for the definite shapes and volumes of solids because they hold the constituent particles in fixed positions.
Source: Myschool Past Questions Archive (Record #2980)
Chemistry
UTME / JAMB 2005
Nature of Matter & Separation Techniques
Solution
Sugar is separated from its impurities by
A
precipitation
B
crystallization
C
distillation
D
evaporation
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Sugar can be separated from its impurities in a solution primarily through crystallization, a process that allows for the separation of pure solute (sugar) from the solvent (water). Separation by evaporation method can lead to sugar charring.
Charring of sugar is a chemical change which occurs when sugar is heated, causing it to evaporate, become foggy due to water vapor, and ultimately produce a black, powdery substance called charcoal. This process involves the breakdown of sugar molecules into carbon, water, and other volatile compounds.
Source: Myschool Past Questions Archive (Record #2981)
Chemistry
UTME / JAMB 2005
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
The component of an atom that contributes least to its mass is the
A
proton
B
nucleus
C
neutron
D
electron
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The electron is indeed the sub-particle of an atom that contributes the least to its mass, as its mass is significantly smaller compared to protons and neutrons, which make up the nucleus and thus account for the majority of an atom's mass.
Source: Myschool Past Questions Archive (Record #2982)
Chemistry
UTME / JAMB 2005
Chemical Bonding & Intermolecular Forces
Solution
An element will readily form an electrovalent compound if its electron configuration is
A
2, 8, 1
B
2, 8, 4
C
2, 8, 8
D
2, 8, 5
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Alkali metals readily form electrovalent bonds because they have a single valence electron that they easily lose, becoming positively charged ions, and readily react with nonmetals to form ionic compounds.
Only option A has the electronic configuration that fits the description of alkali metals; 2, 8, 1
Source: Myschool Past Questions Archive (Record #3088)
Chemistry
UTME / JAMB 2005
Nature of Matter & Separation Techniques
Solution
A heterogenous mixture can be defined as any mixture
A
of a solute and a solvent
B
whose composition is uniform
C
whose composition is not uniform
D
formed by solids and liquids
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A heterogeneous mixture is a mixture in which the composition is not uniform. It consists of two or more phases. When oil and water are combined, they do not mix evenly, but instead form two separate layers. Other examples include;
Soil (containing sand, pebbles, and organic matter).
Blood (containing red blood cells, white blood cells, platelets, and plasma).
Sand and water.
Vegetable soup (you can see the different vegetables and broth) etc
Source: Myschool Past Questions Archive (Record #3092)
Chemistry
UTME / JAMB 2005
Kinetic Theory of Matter & Gas Laws
Solution
The pressure of 100cm\(^3\) of oxygen at 35\(^0\)C is 750mmHg. What will be the volume of gas if the pressure is reduced to 100mmHg without changing the temperature?
A
650 cm3
B
850 cm3
C
580 cm3
D
750 cm3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Given:
V\(_1\) = 100 cm\(^3\) T\(_1\) = 35\(^0\)C + 273 = 308K P\(_1\) = 750 mmHg
V\(_2\) = ? T\(_2\) = 35\(^0\)C + 273 = 308K P\(_2\) = 100 mmHg
According to Boyle's law, the volume of a given mass of gas is inversely proportional to pressure, provided temperature remains constant.
Since temperature remains unchanged, it means T\(_1\) = T\(_2\), invariably meaning that temperature remains constant.
So, applying Boyle's law, P\(_1\) V\(_1\) = P\(_2\)V\(_2\) ( At constant temperature)
V\(_2\) = \(\frac{{P_1}{V_1}}{P_2}\)
V\(_2\) = \(\frac{{750}\times{100}}{100}\)
V\(_2\) = 750cm\(^3\)
Source: Myschool Past Questions Archive (Record #3100)
Chemistry
UTME / JAMB 2005
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
I. Treatment of cancer
II. Detection of leakages in water mains
III. Detection of the ages of ancient tools
IV. Preparation of drugs
Which combination of the above refers to the uses of radioactive isotopes?
A
I and III
B
I and II
C
I, II and III
D
I, II, III and IV
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Radioactive isotopes are used in the preparation of drugs, specifically in the form of radiopharmaceuticals, which are drugs containing radioactive isotopes used for both diagnosis and treatment of various medical conditions such as treatment of cancer.
Also, radioactive isotopes, acting as tracers, are used to detect leaks in water mains, with gamma-emitting isotopes added to the water, and their accumulation in the soil around a leak detected by radiation detectors.
Radioactive isotopes, particularly carbon-14, are used in a method called radiocarbon dating to determine the age of ancient tools and other organic materials, up to approximately 60,000 years old.
Source: Myschool Past Questions Archive (Record #3217)
Chemistry
UTME / JAMB 2005
Atomic Structure, Orbitals & Nuclear Chemistry
Solution
What is the valence shell electron configuration of the element with atomic number 17?
A
1s2 2s2 2p6 3s2 3p4
B
1s2 2s2 2p6 3s2 3p5
C
2s2 2p6
D
3s2 3p5
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
It's important to take note of "valence shell" used in the presentation of the question.
Electronic configuration and valence shell electronic configuration are not the same. Electronic configuration describes the arrangement of all electrons in an atom, while valence shell electronic configuration focuses specifically on the electrons in the outermost shell, which are the valence electrons.
Hence; Option D carries the answer as specified in the question.
Source: Myschool Past Questions Archive (Record #3221)
Chemistry
UTME / JAMB 2005
Kinetic Theory of Matter & Gas Laws
Solution
The density of a certain gas is 1.98gdm\(^{-3}\) at s.t.p. What is the molecular mass of the gas?
A
44.0 g
B
54.0 g
C
26.0 g
D
31.0 g
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Density = \(\frac{mass}{volume}\)
Recall that the molar volume of gases at s.t.p = 22.4 dm\(^3\)
∴ 1.98 = \(\frac{mass}{22.4}\)
Mass = 1.98 x 22.4
Molecular mass = 44.35g
Source: Myschool Past Questions Archive (Record #3227)
Chemistry
UTME / JAMB 2005
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
When pure aluminium metal is heated to red hot in the presence of nitrogen gas, the compound formed is
A
Al2N
B
Al2N2
C
AlN
D
Al2N3
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
When pure aluminum metal is heated to red-hot in the presence of nitrogen gas, it undergoes a chemical reaction, forming aluminum nitride (AlN).
The reaction can be represented by the following balanced chemical equation: 2 Al(s) + N₂(g) → 2 AlN(s).
Source: Myschool Past Questions Archive (Record #3229)
Chemistry
UTME / JAMB 2005
Acids, Bases, pH & Salts
Solution
A dense white fume is formed when ammonia gas reacts with
A
O2(g)
B
H2(g)
C
Cl2(g)
D
HCl(g)
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
When ammonia (NH\(_3\)) gas reacts with hydrogen chloride (HCl) gas, they form solid ammonium chloride (NH\(_4\)Cl), observable as white fumes or clouds.
The reaction is a neutralization reaction where ammonia, acting as a base, accepts a proton (H+) from the acid, hydrogen chloride.
NH\(_3\)(g) + HCl(g) → NH\(_4\)Cl(s)
Source: Myschool Past Questions Archive (Record #3230)
Chemistry
UTME / JAMB 2005
Chemical Energetics & Thermochemistry
Solution
N\(_2\)(g) + 3H\(_2\)(g) ↔ 2NH\(_3\)(g) \DeltaH = - 90 kJ
In the equation above, the yield of ammonia can be decreased by
A
increasing the pressure
B
removing the ammonia as it is formed
C
increase the temperature
D
adding a catalyst
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Increasing temperature in the Haber process decreases the yield of ammonia because the forward reaction is exothermic, and Le Chatelier's principle states that increasing temperature shifts the equilibrium position towards the endothermic (reverse) direction, reducing ammonia production.
Source: Myschool Past Questions Archive (Record #3231)
Chemistry
UTME / JAMB 2005
Water, Solutions & Solubility
Solution
The gas that can be dried using concentrated tetraoxosulphate (VI) acid is
A
hydrogen bromide
B
Sulphur (IV) oxide
C
hydrogen sulphide
D
ammonia
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Concentrated tetraoxosulphate(VI) acid, a hygroscopic liquid is a very strong drying agent as it absorbs moisture from the air, and becomes diluted to about three times its original volume. It can be used to dry all gases except ammonia and Hydrogen sulphide.
Consequently, for drying SO₂ gas, concentrated sulphuric acid (H₂SO₄) is a suitable drying agent, as it effectively absorbs water vapour without reacting with the sulphur dioxide. On the contrary, concentrated sulphuric acid (H₂SO₄) cannot be used to dry hydrogen bromide (HBr) gas because it is a strong oxidizing agent that will react with HBr, oxidizing it to bromine (Br₂) and sulphur dioxide (SO₂).
Also, H₂S cannot be dried using concentrated tetraoxosulphate(VI) acid (H₂SO₄) because it reacts with H₂S, producing water, sulphur dioxide, and elemental sulphur, thus failing to serve its purpose of drying.
Ammonia cannot be dried using concentrated sulfuric acid (tetraoxosulphate(VI) acid) because they react to form ammonium sulfate, a solid, rather than drying the ammonia.
Source: Myschool Past Questions Archive (Record #3232)
Chemistry
UTME / JAMB 2005
Reaction Rates & Chemical Equilibrium
Solution
NH\(_4\)Cl(s) ⇌ NH\(_3\)(g) + HCl(g)
The reaction above can only attain equilibrium if
A
a gaseous reactant is added
B
one of the products is removed
C
it is in a closed system
D
it is an open system
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
In a closed system, as a reaction proceeds, the concentrations of reactants and products change until the system reaches a state where the forward and reverse reactions are occurring at the same rate.
Reactions in a closed system naturally tend towards a state of equilibrium, where the rates of the forward and reverse reactions are equal, and the net change in concentrations of reactants and products is zero.
Source: Myschool Past Questions Archive (Record #3234)