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Chemistry
UTME / JAMB 2005
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
What will happen if an aluminium spoon is used to stir a solution of iron (II) trioxonitrates (V)?
A
The spoon will be oxidized while the iron (II) ions will be reduced to the metal
B
The spoon will increase in size
C
The spoon will be reduced while the iron (II) ions will be oxidized
D
The spoon will be reduced
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
When an aluminum spoon reacts with a solution of iron(II) trioxonitrate(V) (Fe(NO3)2), aluminum, being more reactive than iron, displaces iron from its compound, resulting in the formation of solid iron and aluminum nitrate solution.
The chemical reaction can be represented as: 2Al(s) + 3Fe(NO\(_3\))\(_2\)(aq) → 3Fe(s) + 2Al(NO\(_3\))\(_3\)(aq)
Source: Myschool Past Questions Archive (Record #2962)
Chemistry
UTME / JAMB 2005
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The enzymes responsible for converting sucrose into two simple isomeric sugars is
A
maltase
B
amylase
C
invertase
D
lactase
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The enzyme that converts sucrose into two simple sugars, glucose and fructose, is called sucrase (also known as invertase).
Sucrase is a specific enzyme that catalyzes the hydrolysis (breaking down with water) of sucrose, a disaccharide (a sugar made of two monosaccharides), into its two constituent monosaccharides (simple sugars): glucose and fructose. Invertase is another name for sucrase, and it is important in plants for metabolizing sucrose into simpler sugars for growth and energy.
Source: Myschool Past Questions Archive (Record #2963)
Chemistry
UTME / JAMB 2005
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The decolourization of purple colour of tetraoxomanganate (VII) ion is a test for
A
alkenes
B
alkanols
C
alkanals
D
alkanes
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Alkenes decolourize potassium permanganate (KMnO\(_4\)) solution, a reaction used as a test for unsaturation, with the purple color of KMnO\(_4\) changing to a brown precipitate or a colorless solution depending on reaction conditions.
Source: Myschool Past Questions Archive (Record #2964)
Chemistry
UTME / JAMB 2005
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following are structural isomers?
A
propanoic acid and propan-1, 2-diol
B
Propanal and propanone
C
Ethanoic acid and propanoic acid
D
Ethan-1, 2-diol and ethanoic acid
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Isomers are two or more compounds having the same molecular formula but different structural formula.
Among the options given, only propanal and propanone have the same number of C atoms, Hydrogen atoms and Oxygen atoms even though they have different structural formulas, their molecular formulas are the same, hence they are Isomers.
Propanal - CH\(_3\)CH\(_2\)CHO ⇒ C\(_3\)H\(_6\)O
Propanone - CH\(_3\)COCH\(_3\) ⇒ C\(_3\)H\(_6\)O
Source: Myschool Past Questions Archive (Record #2965)
Chemistry
UTME / JAMB 2005
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
In the purification of impure samples of ethyl ethanoate synthesized by esterification, concentrated sodium trioxocarbonate (IV) solution is used to remove
A
water
B
basic impurities
C
acidic impurities
D
ethoxyethane
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
In the purification of ethyl ethanoate (ethyl acetate), Na₂CO₃ (sodium carbonate) solution is used to neutralize any residual acidic impurities, such as ethanoic acid, that may be present in the crude ester product.
During the esterification reaction (the process of making ethyl ethanoate), some ethanoic acid (acetic acid) might remain unreacted or be formed as a byproduct.
Sodium carbonate is a base, and it reacts with acids. When Na₂CO₃ solution is added to the ethyl ethanoate, it neutralizes the ethanoic acid, forming sodium ethanoate (a salt) and carbon dioxide (CO₂).
Source: Myschool Past Questions Archive (Record #2966)
Chemistry
UTME / JAMB 2005
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
How many hydrogen atoms does a single ring cycloalkane have less than the corresponding open-chain alkane?
A
Two
B
Three
C
Four
D
One
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Let's consider an example:
Cycloalkane → Cyclopropane has the formula CH\(_2\)-CH\(_2\)-CH\(_2\) (when drawn in a cyclic form) = C\(_3\)H\(_6\)
Open chain alkane → Propane has the formula CH\(_3\)CH\(_2\)CH\(_3\) (when drawn on a straight chain) = C\(_3\)H\(_8\)
Comparing the two formulas; C\(_3\)H\(_6\) and C\(_3\)H\(_8\), the difference in the hydrogen atoms is two.
Source: Myschool Past Questions Archive (Record #2968)
Chemistry
UTME / JAMB 2005
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Equal moles of ethyne and hydrogen iodide react to give
A
CH2 = CH2
B
CH2 - CHI
C
CH3 - CI
D
CH2 = CHI
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Whenever equal moles of ethyne and hydrogen iodide react, the triple bond in ethyne is broken down to double bond in order to accommodate the hydrogen iodide coming in because it is an addition reaction.
Let's consider the reaction below:
H - C ≡ C - H + HI → H\(_2\)-C = CHI
Source: Myschool Past Questions Archive (Record #2969)
Chemistry
UTME / JAMB 2005
Metals, Transition Elements & Extraction
Solution
When water boilers are used for long period of time, the solid substances left behind as scale are
A
magnesium trioxosilicate (IV) and rust
B
magnesium trioxosilicate (IV) and calcium tetraoxosulphate (VI)
C
clay and magnesium troxosulphate (IV)
D
clay and rust
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The solid substances left behind as scale when water boilers are used in boiling water for a long period of time will contain Magnesium trioxosilicate(IV) and rust which is an indication that the water is hard water(temporary hardness of water, which upon boiling, Calcium and magnesium trioxocarbonate(IV) are formed on the ring ). The rust can occur because of the presence of oxygen and water.
Source: Myschool Past Questions Archive (Record #2971)
Chemistry
UTME / JAMB 2005
Periodic Table & Periodicity
Solution
25cm\(^3\) of a mixture of noble gases was obtained from air after the removal of other constituents. What was the original volume of air?
A
2,500 cm3
B
1250 cm3
C
125 cm3
D
80 cm3
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Noble gases, primarily argon, make up about 1% of Earth's atmosphere, with argon being the most abundant at 0.934%.
Volume of noble gases in air mixture = % composition of noble gas X Total volume of air mixture
25cm\(^3\) = 1% X V\(_T\)
25cm\(^3\) = \(\frac{1}{100}\times {V_T}\)
25cm\(^3\) = \(\frac{V_T}{100}\)
V\(_T\) = 25 X 100
∴ V\(_T\) = 2,500cm\(^3\)
Source: Myschool Past Questions Archive (Record #2972)
Chemistry
UTME / JAMB 2005
Water, Solutions & Solubility
Solution
The solubility curve shows the variation of solute concentration with
A
volume
B
temperature
C
vapour density
D
pressure
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
A solubility curve graphically represents how the solubility of a solute (a substance that dissolves in a solvent) changes with temperature, showing the maximum amount of solute that can dissolve at a given temperature.
Source: Myschool Past Questions Archive (Record #2973)
Chemistry
UTME / JAMB 2005
Metals, Transition Elements & Extraction
Solution
The air around smelting industries is likely to contain
A
H2S, CO and N2
B
CO2, SO3 and H2
C
H2, SO2 and CO2
D
SO2, N2 and CO2
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Smelting is a process of applying heat and a chemical reducing agents to an ore to extract a desired product.
The reducing agent is commonly a fossil-fuel source of carbon, such as carbon monoxide from incomplete combustion of coke. The oxygen in the ore binds to carbon at high temperatures, as the chemical potential energy of the bonds in carbon dioxide (CO\(_2\)) is lower than that of the bonds in the ore. The main industrial uses include fossil fuel processing and ammonia production. Emerging uses for hydrogen include the use of fuel cells to generate electricity
Sulphide ores such as those commonly used to obtain copper, zinc or lead, are roasted before smelting in order to convert the sulphides to oxides, which are more readily reduced to the metal. Roasting heats the ore in the presence of oxygen from air, oxidizing the ore and liberating the sulphur as SO\(_2\) gas.
Source: Myschool Past Questions Archive (Record #2974)
Chemistry
UTME / JAMB 2005
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Kerosene is commonly used to remove the red colour stain of palm oil from cloths because it
A
helps to spread the oil over a larger surface area
B
react with the oil to form an odourless compound
C
makes the oil evaporate easily by dissolving it
D
helps to dilute the oil and reduce its colour
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
kerosene can be used to dissolve oil stains on fabric, especially old or stubborn ones, as it acts as a solvent to lift the oil from the fabric. It is a petroleum-based product that has solvent properties, meaning it can dissolve or break down oil and grease.
Source: Myschool Past Questions Archive (Record #2975)
Chemistry
UTME / JAMB 2005
Non-Metals & Their Compounds
Solution
The gas that is the most dangerous pollutant to human is
A
sulphur (IV) oxide
B
carbon (IV) oxide
C
nitrogen (II) oxide
D
hydrogen sulphide
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
While both SO\(_2\) and H\(_2\)S are dangerous pollutants, H\(_2\)S (hydrogen sulphide) is generally considered more dangerous to humans, especially at high concentrations, due to its rapid and potentially lethal effects on the respiratory system and central nervous system.
Source: Myschool Past Questions Archive (Record #2976)
Chemistry
UTME / JAMB 2005
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Natural water collected from rivers and ponds contain oxygen, carbon (IV) oxide and
A
nitrogen
B
hydrogen
C
chlorine
D
sulphur
E
oxide
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
Pond water does contain nitrogen, in various forms like ammonia, nitrite, and nitrate, which are essential nutrients for aquatic life and play a crucial role in the pond's ecosystem.
Nitrogen enters ponds through various sources, including rainfall, wind, run-off from land, and the decomposition of organic matter like leaves, twigs, and fish waste.
Source: Myschool Past Questions Archive (Record #2977)
Chemistry
UTME / JAMB 2005
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
How many moles of limestone will be required to produce 5.6g of CaO?
[Ca = 40, C = 12, O= 16]
A
0.20 mol
B
0.10 mol
C
1.12 mol
D
0.56 mol
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
CaCO\(_3\) → CaO + CO\(_2\)
CaCO\(_3\) = 40 + 12 + (16 x 3) = 100,
CaO = 40 + 16 = 56
56g of CaO was produced by 100g of CaCO\(_3\)
∴ 5.6g of CaO will be produced by
(5.6 x 100)/56 = 10g of CaCO\(_3\)
Recall that Number of moles = \(\frac{mass}{molar mass}\)
= \(\frac{10}{100}\)
= 0.10mole
Alternatively,
CaCO\(_3\) → CaO + CO\(_2\)
n = \(\frac{m}{M}\)
n = \(\frac{5.6}{56}\)
n = 0.10 mole
Since the ratio of the reactant to product is 1 : 1, and the number of mole of CaO is 0.10mole, therefore, the number of mole of CaCO\(_3\) will also be 0.10 mole, according to Avogadro's law.
Source: Myschool Past Questions Archive (Record #2978)