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Chemistry
UTME / JAMB 2007
Acids, Bases, pH & Salts
Solution
CH\(_3\)CH\(_2\)Cl + KCN → CH\(_3\)CH\(_2\)CN + KCl
In the reaction above, the cyanide is
A
hydrophobic
B
hydrophilic
C
nucleophilic
D
electrophilic
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A nucleophile is considered an electron donating species, meaning it readily donates an electron pair to form a bond with another molecule, typically an electrophile, in a chemical reaction; essentially acting as a Lewis base.
CN\(^-\) (cyanide ion) is considered a nucleophile. This is because it has a negative charge and a lone pair of electrons that it can donate to form a bond with a positively charged species, making it an electron-rich species characteristic of nucleophile.
Conversely, an electrophile is a chemical species that forms bonds with nucleophiles by accepting an electron pair. Because electrophiles accept electrons, they are Lewis acids.
Source: Myschool Past Questions Archive (Record #3866)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following compounds is the best possible anti-knock agent for petrol?
A
(CH3)2CH - CH(CH3)CH2CH3
B
CH3CH2(CH3)CHCH2CH2CH3
C
CH3CH2(CH3)CHCH2CH2CH3
D
(CH3)3C - CH2CH2CH3
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
An "anti-knock agent" for petrol (or gasoline) is a chemical additive that is added to fuel to prevent engine knocking, which is a knocking sound produced by premature ignition in the combustion chamber, and essentially increases the fuel's octane rating by delaying ignition.
Option A - 2,3- dimethylpentane
Option B - 3-methylhexane
Option C - 3-methylhexane
Option D - 2,2-dimethylpentane
Both 2,3-dimethylpentane and 2,2-dimethylpentane are branched-chain structures. However, 2,2-dimethylpentane has a more compact, highly branched structure, which is generally associated with higher octane ratings and better anti-knock properties.
In contrast, 2,3-dimethylpentane has a slightly less branched structure, which may result in slightly lower octane ratings. So, while both compounds are branched, the degree of branching and the resulting octane rating can differ.
Source: Myschool Past Questions Archive (Record #3869)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The hydrocarbon used in the production of styrene is
A
ethyne
B
propyne
C
ethane
D
ethene
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Styrene is produced from the monomer ethylbenzene through a process called dehydrogenation, where hydrogen is removed from ethylbenzene to create styrene; dehydrogenation of ethylbenzene, a compound obtained by reacting ethylene and benzene. However, ethylene is also known as ethene.
Source: Myschool Past Questions Archive (Record #3870)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
How many structural isomers of chlorobutane are possible?
A
4
B
3
C
2
D
1
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The structural isomers of chlorobutane are: 1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane, and 2-chloro-2-methylpropane; in total, there are four structural isomers of chlorobutane.
Explanation:
1-chlorobutane: Chlorine is attached to the first carbon of a straight carbon chain.
2-chlorobutane: Chlorine is attached to the second carbon of a straight carbon chain.
1-chloro-2-methylpropane: A methyl group is attached to the second carbon of a propane chain, with chlorine on the first carbon.
2-chloro-2-methylpropane: Chlorine is attached to a carbon that is also connected to two methyl groups.
Source: Myschool Past Questions Archive (Record #3980)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The conversion of open chain alkanes into cycloalkanes and aromatic compounds is called
A
cracking
B
reforming
C
isomerization
D
polymerization
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The correct answer is B. Reforming.
Reforming is a process in petroleum refining where low-octane, straight-chain alkanes are converted into higher-octane, branched-chain alkanes, cycloalkanes, and aromatic compounds. This process involves the use of catalysts and high temperatures to break and reform the molecular bonds. Reforming is an important process in the production of high-octane gasoline and other petroleum products.
Source: Myschool Past Questions Archive (Record #3981)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following alkanes has the highest boiling point?
A
Pentane
B
Ethane
C
Propane
D
Methane
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The correct answer is A. Pentane.
Boiling point increases with molecular weight and size in alkanes, due to increased London dispersion forces (also known as van der Waals forces).The order of boiling points for the given options is:
Methane (boiling point: -161.5^\circC) < Ethane (boiling point: -88.5^\circC) < Propane (boiling point: -42.2^\circC) < Pentane (boiling point: 36.1^\circC). Therefore, Pentane has the highest boiling point among the given options.
Source: Myschool Past Questions Archive (Record #3982)
Chemistry
UTME / JAMB 2007
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
Certain useful waxes are composed mainly of
A
amino acids
B
glycerols
C
alkanols
D
alkanoates
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
Waxes are esters of higher fatty acids with long chain of monohydric alcohols. It is a simple lipid that is an ester of a long-chain alcohol and a fatty acid. The alcohol may contain around 12-32 carbon atoms. Waxes are found in nature as coatings on leaves and stems. The wax prevents the plant from losing excessive amounts of water.
Source: Myschool Past Questions Archive (Record #3983)
Chemistry
UTME / JAMB 2007
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The IUPAC nomenclature of compound CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) is
A
propyl ethanoate
B
ethyl butanoate
C
ethyl propanoate
D
methyl butanoate
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
While trying to name the compound CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) , we must realize that this ester or alkanoate was derived from two reactants; alkanol and alkanoic acid. Therefore, we'll try to split the compound into two for easier naming.
CH\(_3\)CH\(_2\)COO - CH\(_2\)CH\(_3\).
Secondly, start the naming from the right hand side i.e CH\(_2\)CH\(_3\), which is ethyl
Thirdly, name the compound from the left hand side i.e CH\(_3\)CH\(_2\)COO,which is propanoate (because there are 3 carbon atoms and the functional group RCOO-).
Finally, join the two names together i.e ethyl propanoate.
Source: Myschool Past Questions Archive (Record #3985)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
When temporary hard water is boiled for sometime in a kettle, the inner surface of the kettle becomes coated with a deposit of
A
calcium tetraoxosulphate(VI)
B
calcium trioxocarbonate (IV)
C
calcium hydrogentrioxocarbonate (IV)
D
aluminium trioxocarbonate (IV)
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
When temporary hard water is boiled for some time in a kettle, the inner surface of the kettle becomes coated with a deposit of Calcium trioxocarbonate(IV), CaCO\(_3\), which originated from Calcium hydrogen trioxocarbonate(IV), Ca(HCO\(_3\))\(_2\).
Ca(HCO\(_3\))\(_2\) → CaCO\(_3\) + H\(_2\)O + CO\(_2\)
Source: Myschool Past Questions Archive (Record #3987)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
A supersaturated solution is said to contain
A
more solute than it can dissolve at that temperature in the presence of undissolved solute
B
as much solute as it can dissolve at that temperature in the presence of undissolved solute
C
as much solute as it can dissolve at that temperature
D
more solute than it can dissolve at that temperature
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
The correct answer is D. More solute than it can dissolve at that temperature.
A supersaturated solution is a solution that contains more dissolved solute than it can hold at equilibrium at a given temperature. This means that the solution is unstable and can precipitate out the excess solute at any moment.
In contrast, a saturated solution (option C) contains as much dissolved solute as it can hold at equilibrium at a given temperature, while an unsaturated solution contains less dissolved solute than it can hold.
Source: Myschool Past Questions Archive (Record #3991)
Chemistry
UTME / JAMB 2007
Periodic Table & Periodicity
Solution
The presence of nitrogen in air is to slow down
A
respiration and combustion
B
combustion and corrosion
C
corrosion and respiration
D
respiration and transpiration
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Nitrogen in the air slows down the burning process of materials, essentially acting as a fire suppressant by diluting the oxygen concentration needed for combustion to occur rapidly; making up the majority of air, it prevents flames from spreading too quickly.
Also,nitrogen in the air does slow down corrosion because it is an inert gas, meaning it doesn't readily react with metals, while the primary contributor to corrosion, oxygen, is displaced by the presence of nitrogen in the atmosphere; essentially, by taking up space, nitrogen limits the amount of oxygen that can come into contact with a metal surface, thus slowing down the corrosion process.
Conversely, nitrogen in the air does not slow down respiration because it is not used in respiration, just as the nitrogen in the soil can affect transpiration rates, but the relationship depends on soil moisture and other factors.
Source: Myschool Past Questions Archive (Record #3994)
Chemistry
UTME / JAMB 2007
Water, Solutions & Solubility
Solution
A good drying agent should be
A
deliquescent
B
effervescent
C
hygroscopic
D
efflorescent
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
A good drying agent should be hygroscopic because this property means it readily absorbs moisture from the surrounding environment, making it effective at drying substances; while efflorescence is the opposite, where a substance releases water, making it unsuitable for drying purposes. Examples of hygroscopic drying agents: Silica gel, calcium oxide, concentrated sulphuric acid.
Source: Myschool Past Questions Archive (Record #3997)
Chemistry
UTME / JAMB 2007
Air & Environmental Chemistry
Solution
Smog usually occurs over cities which
A
burn a lot of fossil fuels
B
have very few plants
C
are surrounded by water
D
are overpopulated
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The correct answer is A. Burn a lot of fossil fuels.
Smog, a type of air pollution, is often associated with urban areas that burn large amounts of fossil fuels, such as coal, oil, and gasoline. These fuels release pollutants like nitrogen oxides, sulphur dioxide, and particulate matter into the atmosphere, which can react with sunlight and other chemicals to form ground-level ozone and smog.
While options B, C, and D may be related to urban areas, they are not the primary cause of smog. Burning fossil fuels is the main culprit!
Source: Myschool Past Questions Archive (Record #4000)
Chemistry
UTME / JAMB 2007
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
What weight of NaCl is needed to make 2.0 dm3 of a 1.5M solution?
[Na = 23, Cl = 35.5]
A
116 g
B
175 g
C
87 g
D
58 g
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
Molar mass of Nacl = 23 + 35.5 = 58.5 g/mol
Number of moles of Nacl = conc. in mol/dm3
x vol. in dm3
= 1.5 * 2.0 = 3.0 moles
1 mole of NaCl has a weight of 58.5 * 3
= 175.5g
Source: Myschool Past Questions Archive (Record #4002)
Chemistry
UTME / JAMB 2007
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Use the diagram above to answer the question below:
The alternative raw material labelled M is
A
carbon
B
steam
C
oxygen
D
natural gas
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The alternative raw material labelled M is steam
Source: Official Exam / Past Question Archive