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Physics
UTME / JAMB 2019
Equilibrium of Forces, Moments & Flotation
Solution
A cone is in unstable equilibrium, has its potential energy
A
decreased
B
increased
C
unchanged
D
oscillating
medium Difficulty
Verified Correct Answer: Option B
Physical Principles & Numerical Solution
In unstable equilibrium, when the cone is disturbed, it tends to fall further from its equilibrium position, leading to a decrease in height and thus an increase in potential energy.
Source: Myschool Past Questions Archive (Record #55826)
Physics
UTME / JAMB 2019
Circular Motion, Gravitation & Simple Harmonic Motion
Solution
A mass of 0.5kg is whirled in a vertical circle of radius 2m at a steady rate of 2 rev/s. Calculate the centripetal force
A
164N
B
160N
C
158N
D
172N
medium Difficulty
Verified Correct Answer: Option C
Physical Principles & Numerical Solution
\omega = 2\piF = 2\pi \times 2 = 4\pirad\(^{-1}\)
Centripetal force = mr\omega\(^2\)
⇒ 0.5 \times 2 \times (4\pi)\(^2\)
⇒ 157.75N
Approximately = 158N.
Source: Myschool Past Questions Archive (Record #55827)
Physics
UTME / JAMB 2019
Work, Energy, Power & Simple Machines
Solution
A body was slightly displaced from its equilibrium position. Which one of the following is a condition for its stable equilibrium
A
an increase in the kinetic energy of the body
B
an increase in the potential energy of the body
C
a decrease in the kinetic energy of the body
D
an increase in the height of the body
medium Difficulty
Verified Correct Answer: Option B
Physical Principles & Numerical Solution
Stable equilibrium brings about increase in potential energy as the height rises after displacement.
Source: Myschool Past Questions Archive (Record #55829)
Physics
UTME / JAMB 2019
Current Electricity & Electric Circuits
Solution
Which of the following readings cannot be determined with a meter rule?
A
2.56cm
B
2.25cm
C
2.50cm
D
2.05cm
medium Difficulty
Verified Correct Answer: Option A
Physical Principles & Numerical Solution
Meter rule has a reading accuracy of 0.5mm or 0.05cm, thus measurement is M \pm 0.05cm i.e 2.00, 2.05, 2.50, 2.55 etc.
The reading that cannot be read is 2.56cm.
Source: Myschool Past Questions Archive (Record #55831)
Physics
UTME / JAMB 2019
Gas Laws & Heat Transfer
Diagram
Solution
Which of the following is consistent with Charles' law?
Attached Figure / Diagram
A
I
B
II
C
III
D
IV
medium Difficulty
Verified Correct Answer: Option A
Physical Principles & Numerical Solution
This is the correct graph. The graph is volume against temperature where temperature is in Celsius.
Source: Myschool Past Questions Archive (Record #56103)
Physics
UTME / JAMB 2019
Gas Laws & Heat Transfer
Solution
Which of the following is consistent with Charles' law?
A
I
B
II
C
III
D
IV
medium Difficulty
Verified Correct Answer: Option A
Physical Principles & Numerical Solution
This is the correct graph. The graph is volume against temperature where temperature is in Celsius.
Source: Official Exam / Past Question Archive
Chemistry
UTME / JAMB 2019
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
A secondary alkanol can be oxidized to give an?
A
alkanone
B
alkyne
C
alkanoic acid
D
alkanal
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
secondary alkanols (alcohols) can be oxidised to alkanones (ketones)
Source: Myschool Past Questions Archive (Record #55517)
Chemistry
UTME / JAMB 2019
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Which of the following will give a precipitate with an aqueous solution of copper (I) chloride?
A
But-2-ene
B
But-1-ene
C
But-2-yne
D
But-1-yne
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
A hydrocarbon that will produce a red precipitate when reacted with an aqueous solution of copper(I) chloride is an alkyne. More specifically, an alkyne with a terminal triple bond, like ethyne (acetylene), will react to form a red precipitate of copper(I) acetylide. The most reactive alkynes are those where the triple bond is at the end of the carbon chain (terminal triple bond).
Source: Myschool Past Questions Archive (Record #55519)
Chemistry
UTME / JAMB 2019
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
Solution
The IUPAC name for CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) is
A
methylpropanoate
B
ethylethanoate
C
ethylpropanoate
D
methylethanoate
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
While naming the IUPAC nomenclature of hydrocarbon compounds, we usually start with the naming from the rare i.e the functional group from the right hand side.
Consider CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\), this is an ester obtained from two compounds propanoic acid and ethanol.
On splitting CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\), we have CH\(_3\)CH\(_2\)COO / CH\(_2\)CH\(_3\) dividing the compound into two; CH\(_3\)CH\(_2\)COO - Propanoate and CH\(_2\)CH\(_3\) - ethyl
So while naming as mentioned earlier on, we start the naming from the rare(RHS), and then the other(LHS). Thus, the name of the compound is; ethylpropanoate.
Source: Myschool Past Questions Archive (Record #55520)
Chemistry
UTME / JAMB 2019
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
Hydrocarbons which will react with Tollen's reagent conform to the general formula
A
C\(_n\)H\(_{2n}\)
B
C\(_n\)H\(_{2n + 2}\)
C
C\(_n\)H\(_{2n - 2}\)
D
C\(_n\)H\(_{2n + 1}\)OH
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
Only hydrocarbons containing an aldehyde group (RCHO) or a terminal alkyne (R-C≡C-H) will react with Tollens' reagent, leading to a silver mirror formation or a white precipitate, respectively. Aldehydes are oxidized by Tollens' reagent (ammoniacal silver nitrate solution) to form carboxylic acids, while the silver ions (Ag+) are reduced to metallic silver (Ag), which deposits as a silver mirror on the walls of the test tube.
Terminal alkynes react with Tollens' reagent, producing a white precipitate of silver acetylide.
Source: Myschool Past Questions Archive (Record #55523)
Chemistry
UTME / JAMB 2019
Organic Chemistry I: Hydrocarbons & Crude Oil
Solution
The IUPAC name of the compound CF\(_3\)CHBrCl is
A
2-chloro-2-bromo-1,1,1-trifluoroethane
B
2-bromo-2-chloro-1,1,1-trifluoroethane
C
1-bromo-1-chloro-2,2,2-trifluoroethane
D
1,1,1-trifluoro-2-bromo-2-chloroethane
medium Difficulty
Verified Correct Answer: Option B
Chemical Principles & Mechanism
The IUPAC name of the compound CF\(_3\)CHBrCl is 2-bromo-2-chloro-1,1,1-trifluoroethane.
This compound is famously known by its non-proprietary name, Halothane, and was widely used as an inhalation anesthetic.
Breakdown of the Name
To arrive at the correct IUPAC name, we follow standard nomenclature rules:
Identify the Parent Chain: The longest carbon chain contains two carbons, making the parent alkane ethane.
Numbering the Chain: We number the carbons to give the substituents the lowest possible locants.
If we start from the carbon with the three fluorine atoms, the locants are (1,1,1,2,2).
If we start from the carbon with bromine and chlorine, the locants are (1,1,2,2,2).
In this case, both directions yield the same set of locants. However, IUPAC rules state that if numbering is equivalent from both ends, we give the lower number to the substituent that comes first alphabetically.
Since Bromo and Chloro come before Fluoro, the carbon attached to Br and Cl is designated as Carbon-2 (wait, let me re-check that logic).
Actually, per the lowest locant set rule, we prioritize the side with more substituents to keep the numbers lower. The carbon with three fluorines gets "1" so the set is (1,1,1,2,2) rather than (1,2,2,2,2).
Correction: In the specific case of Halothane, the standard IUPAC assignment labels the carbon with the three fluorines as C1, resulting in 2-bromo-2-chloro-1,1,1-trifluoroethane
Source: Myschool Past Questions Archive (Record #55524)
Chemistry
UTME / JAMB 2019
Organic Chemistry II: Functional Groups, Polymers & Biomolecules
A synthetic rubber is not obtained from the polymerization of?
A
neoprene
B
isoprene
C
butandiene
D
hexane
medium Difficulty
Verified Correct Answer: Option D
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option D.
Source: Myschool Past Questions Archive (Record #55525)
Chemistry
UTME / JAMB 2019
Stoichiometry, Mole Concept & Volumetric Analysis
Solution
Burning magnesium ribbon in air removes which of the following
(i) oxygen (ii) nitrogen (iii) argon and (iv) carbon(iv)oxide?
A
i and iv only
B
i, ii, iii and iv only
C
i only
D
i and ii only
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
The chemical reaction between magnesium ribbon and oxygen is a combustion reaction that produces magnesium oxide (MgO). Burning Magnesium ribbon in air removes oxygen, because as Magnesium burns in air, it reacts with oxygen in the air to form Magnesium oxide.
The chemical equation for this reaction is 2Mg(s)+O\(_2\)(g) → 2MgO(s)
Source: Myschool Past Questions Archive (Record #55526)
Chemistry
UTME / JAMB 2019
Non-Metals & Their Compounds
Solution
Which of the following is the best starting material for the preparation of oxygen? Heating of trioxonitrate (v) with
A
Pb
B
Zn
C
Ca
D
Na
medium Difficulty
Verified Correct Answer: Option A
Chemical Principles & Mechanism
The best starting material for the preparation of oxygen through heating trioxonitrate(V) (nitrates) would involve a metal that facilitates the decomposition of the nitrate to produce oxygen, coincidentally, Pb (Lead) falls into that category.
Lead(II) nitrate (Pb(NO\(_3\))\(_2\)) decomposes upon heating to produce oxygen, nitrogen dioxide, and lead(II) oxide. This reaction is often used in laboratory settings to generate oxygen.
2Pb(NO\(_3\))\(_2\) → 2PbO + 4NO\(_2\) + O\(_2\)
This makes lead (Pb) a suitable choice for generating oxygen from nitrates.
Source: Myschool Past Questions Archive (Record #55528)
Chemistry
UTME / JAMB 2019
Stoichiometry, Mole Concept & Volumetric Analysis
Which of the following metals is the most essential in the regulation of blood volume, blood pressure and osmotic equilibrium?
A
Zinc
B
Manganese
C
Sodium
D
Iron
medium Difficulty
Verified Correct Answer: Option C
Chemical Principles & Mechanism
No expanded working has been attached for this question yet. The verified answer is Option C.
Source: Myschool Past Questions Archive (Record #55529)